Standard Specification for and Basis for Specifications for Styrene-Acrylonitrile (SAN) Injection and Extrusion Materials

ABSTRACT
This specification covers unfilled, filled, and reinforced styrene acrylonitrile (SAN) materials suitable for injection molding and extrusion. SAN compounds are typically general-purpose materials used in either molding or extrusion processes or applications. There are currently no group, class, or grade distinctions and no basic property table given. The SAN compounds are produced by the polymerization of the monomers acrylonitrile and styrene. The melt-flow rate, Vicat softening point, heat-deflection temperature, tensile strength at yield, flexural modulus, and glass content shall be tested to meet the requirements prescribed.
SCOPE
1.1 This specification covers unfilled, filled, and reinforced styrene acrylonitrile (SAN) materials suitable for injection molding and extrusion.  
1.2 This classification system and subsequent line callout (specification) are intended to provide a means of calling out plastic materials used in the fabrication of end items or parts. It is not intended for the selection of materials. Material selection can be made by those having expertise in the plastic field only after careful consideration of the design and the performance required of the part, the environment to which it will be exposed, the fabrication process to be employed, the costs involved, and the inherent properties of the material other than those covered by this standard.  
1.3 The properties included in this standard are those required to identify the compositions covered. Other requirements necessary to identify particular characteristics important to specialized applications are to be specified using the suffixes specified in Section 5.  
1.4 The values stated in SI units are to be regarded as the standard. The values in parentheses are given for information only.  
1.5 The following precautionary caveat pertains only to the test methods portion, Section 11, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.  
Note 1: This standard and ISO 19064-1 and ISO 4894-2 address the same subject matter, but differ in technical content. Although this standard and ISO 19064-1 and ISO 4894-2 differ in approach or detail, data obtained using either are technically equivalent.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM D4203-17 - Standard Specification for and Basis for Specifications for Styrene-Acrylonitrile (SAN) Injection and Extrusion Materials
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation:D4203 −17
Standard Specification for and Basis for Specifications for
Styrene-Acrylonitrile (SAN) Injection and Extrusion
1
Materials
This standard is issued under the fixed designation D4203; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope* 1.6 This international standard was developed in accor-
dance with internationally recognized principles on standard-
1.1 This specification covers unfilled, filled, and reinforced
ization established in the Decision on Principles for the
styrene acrylonitrile (SAN) materials suitable for injection
Development of International Standards, Guides and Recom-
molding and extrusion.
mendations issued by the World Trade Organization Technical
1.2 This classification system and subsequent line callout
Barriers to Trade (TBT) Committee.
(specification) are intended to provide a means of calling out
plastic materials used in the fabrication of end items or parts.
2. Referenced Documents
It is not intended for the selection of materials. Material
2
2.1 ASTM Standards:
selection can be made by those having expertise in the plastic
D256 Test Methods for Determining the Izod Pendulum
field only after careful consideration of the design and the
Impact Resistance of Plastics
performance required of the part, the environment to which it
D618 Practice for Conditioning Plastics for Testing
will be exposed, the fabrication process to be employed, the
D638 Test Method for Tensile Properties of Plastics
costsinvolved,andtheinherentpropertiesofthematerialother
D648 Test Method for Deflection Temperature of Plastics
than those covered by this standard.
Under Flexural Load in the Edgewise Position
1.3 The properties included in this standard are those
D790 Test Methods for Flexural Properties of Unreinforced
required to identify the compositions covered. Other require-
and Reinforced Plastics and Electrical Insulating Materi-
ments necessary to identify particular characteristics important
als
to specialized applications are to be specified using the suffixes
D792 Test Methods for Density and Specific Gravity (Rela-
5.
specified in Section
tive Density) of Plastics by Displacement
D883 Terminology Relating to Plastics
1.4 The values stated in SI units are to be regarded as the
D1238 Test Method for Melt Flow Rates of Thermoplastics
standard. The values in parentheses are given for information
by Extrusion Plastometer
only.
D1525 Test Method for Vicat Softening Temperature of
1.5 The following precautionary caveat pertains only to the
Plastics
test methods portion, Section 11, of this specification: This
D1600 Terminology forAbbreviatedTerms Relating to Plas-
standarddoesnotpurporttoaddressallofthesafetyconcerns,
tics
ifany,associatedwithitsuse.Itistheresponsibilityoftheuser
D2584 Test Method for Ignition Loss of Cured Reinforced
of this standard to establish appropriate safety and health
Resins
practices and determine the applicability of regulatory limita-
D3641 Practice for Injection Molding Test Specimens of
tions prior to use.
Thermoplastic Molding and Extrusion Materials
NOTE 1—This standard and ISO 19064-1 and ISO 4894-2 address the
D3892 Practice for Packaging/Packing of Plastics
same subject matter, but differ in technical content.Although this standard
D4000 Classification System for Specifying Plastic Materi-
and ISO 19064-1 and ISO 4894-2 differ in approach or detail, data
als
obtained using either are technically equivalent.
E29 Practice for Using Significant Digits in Test Data to
Determine Conformance with Specifications
1
This specification is under the jurisdiction of ASTM Committee D20 on
Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic
2
Materials.15.03). For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved Aug. 1, 2017. Published August 2017. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 1989. Last previous edition approved in 2012 as D4203 - 12. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D4203-17. the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ------------------
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D4203 − 12 D4203 − 17
Standard Specification for and Basis for Specifications for
Styrene-Acrylonitrile (SAN) Injection and Extrusion
1
Materials
This standard is issued under the fixed designation D4203; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope*
1.1 This specification covers unfilled, filled, and reinforced styrene acrylonitrile (SAN) materials suitable for injection molding
and extrusion.
1.2 This classification system and subsequent line callout (specification) are intended to provide a means of calling out plastic
materials used in the fabrication of end items or parts. It is not intended for the selection of materials. Material selection can be
made by those having expertise in the plastic field only after careful consideration of the design and the performance required of
the part, the environment to which it will be exposed, the fabrication process to be employed, the costs involved, and the inherent
properties of the material other than those covered by this standard.
1.3 The properties included in this standard are those required to identify the compositions covered. Other requirements
necessary to identify particular characteristics important to specialized applications are to be specified using the suffixes specified
in Section 5.
1.4 The values stated in SI units are to be regarded as the standard. The values in parentheses are given for information only.
1.5 The following precautionary caveat pertains only to the test methods portion, Section 11, of this specification:This standard
does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this
standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
NOTE 1—This standard and ISO 4894-119064-1 and ISO 4894-2 address the same subject matter, but differ in technical content. Although this standard
and ISO 4894-119064-1 and ISO 4894-2 differ in approach or detail, data obtained using either are technically equivalent.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D256 Test Methods for Determining the Izod Pendulum Impact Resistance of Plastics
D618 Practice for Conditioning Plastics for Testing
D638 Test Method for Tensile Properties of Plastics
D648 Test Method for Deflection Temperature of Plastics Under Flexural Load in the Edgewise Position
D790 Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Electrical Insulating Materials
D792 Test Methods for Density and Specific Gravity (Relative Density) of Plastics by Displacement
D883 Terminology Relating to Plastics
D1238 Test Method for Melt Flow Rates of Thermoplastics by Extrusion Plastometer
D1525 Test Method for Vicat Softening Temperature of Plastics
D1600 Terminology for Abbreviated Terms Relating to Plastics
D2584 Test Method for Ignition Loss of Cured Reinforced Resins
1
This specification is under the jurisdiction of ASTM Committee D20 on Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic
Materials.15.03).
Current edition approved Nov. 15, 2012Aug. 1, 2017. Published November 2012August 2017. Originally approved in 1989. Last previous edition approved in 20072012
as D4203 - 07.D4203 - 12. DOI: 10.1520/D4203-12.10.1520/D4203-17.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D4203 − 17
D3641 Practice for Injection Molding Test Specimens of Thermoplastic Mo
...

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