ASTM D740-11

Standard Specification for Methyl Ethyl Ketone

ABSTRACT
This specification covers two types of methyl ethyl ketone (or 2-butanone), namely: Type I (regular grade) and Type II (urethane grade), that are used primarily as solvents in lacquers and industrial coatings, but also in adhesives, printing inks, lube oil dewaxing, and as chemical intermediates. The physical and chemical properties of methyl ethyl ketone shall conform to the requirements specified for the following: (1) acidity, (2) weight percentage of alcohol, (3) color (Pt-Co scale), (4) distillation range defined by the initial boiling point and dry point, (5) nonvolatile matter content, (6) purity, (7) apparent specific gravity, and (8) weight percentage of water. The sampling and test methods for determining conformance to the specified physical and chemical properties are given.
SCOPE
1.1 This specification covers two types of methyl ethyl ketone that are used primarily as solvents in lacquers and industrial coatings, but also in adhesives, printing inks, lube oil dewaxing, and as chemical intermediates.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off "to the nearest unit" in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for materials listed in this specification.

General Information

• Status: Historical
• Publication Date: 31-Oct-2011
• ICS: 71.080.80 - Aldehydes and ketones
• ICS: 87.060.30 - Solvents
• Technical Committee: D01 - Paint and Related Coatings, Materials, and Applications
• Drafting Committee: D01.35 - Solvents, Plasticizers, and Chemical Intermediates

Relations

• Replaces: ASTM D740-05 - Standard Specification for Methyl Ethyl Ketone
• Effective Date: 01-Nov-2011
• Replaced By: ASTM D740-11(2019) - Standard Specification for Methyl Ethyl Ketone^,
• Effective Date: 01-Apr-2019
• Referred By: ASTM F945-22 - Standard Test Method for Stress-Corrosion of Titanium Alloys by Aircraft Engine Cleaning Materials
• Effective Date: 01-Nov-2011
• Referred By: ASTM D2235-22 - Standard Specification for Solvent Cement for Acrylonitrile-Butadiene-Styrene (ABS) Plastic Pipe and Fittings
• Effective Date: 01-Nov-2011
• Referred By: ASTM D7835/D7835M-19 - Standard Test Method for Determining the Solvent Resistance of an Organic Coating Using a Mechanical Rubbing Machine
• Effective Date: 01-Nov-2011
• Referred By: ASTM D4752-20 - Standard Practice for Measuring MEK Resistance of Ethyl Silicate (Inorganic) Zinc-Rich Primers by Solvent Rub
• Effective Date: 01-Nov-2011
• Referred By: ASTM D5402-19 - Standard Practice for Assessing the Solvent Resistance of Organic Coatings Using Solvent Rubs
• Effective Date: 01-Nov-2011

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D740 −11
Standard Specification for
1,2
Methyl Ethyl Ketone
This standard is issued under the fixed designation D740; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope* Fischer Reagent Titration Method)
D1613 Test Method for Acidity in Volatile Solvents and
1.1 This specification covers two types of methyl ethyl
Chemical Intermediates Used in Paint, Varnish, Lacquer,
ketone that are used primarily as solvents in lacquers and
and Related Products
industrial coatings, but also in adhesives, printing inks, lube oil
D2804 Test Method for Purity of Methyl Ethyl Ketone By
dewaxing, and as chemical intermediates.
Gas Chromatography
1.2 The values stated in SI units are to be regarded as
D4052 Test Method for Density, Relative Density, and API
standard. No other units of measurement are included in this
Gravity of Liquids by Digital Density Meter
standard.
D5386 Test Method for Color of Liquids Using Tristimulus
Colorimetry
1.3 The following applies to all specified limits in this
standard; for purposes of determining conformance with this E29 Practice for Using Significant Digits in Test Data to
Determine Conformance with Specifications
standard, an observed value or a calculated value shall be
rounded off “to the nearest unit” in the last right-hand digit E300 Practice for Sampling Industrial Chemicals
used in expressing the specification limit, in accordance with 2.2 U.S. Federal Specification:
the rounding-off method of Practice E29.
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
4
of
1.4 For specific hazard information and guidance, see the
supplier’sMaterialSafetyDataSheetformaterialslistedinthis
3. Classification
specification.
3.1 Methyl ethyl ketone shall be of the following types, as
2. Referenced Documents
specified:
3
3.1.1 Type I—regular, and
2.1 ASTM Standards:
3.1.2 Type II—urethane grade. This type may be suited for
D268 Guide for Sampling and Testing Volatile Solvents and
use in urethane coatings, provided that the water content and
Chemical Intermediates for Use in Paint and Related
alcohol content are acceptable.
Coatings and Material
D1078 Test Method for Distillation Range of Volatile Or-
4. Properties
ganic Liquids
4.1 The physical and chemical properties of methyl ethyl
D1209 Test Method for Color of Clear Liquids (Platinum-
ketone shall conform to the requirements specified in Table 1.
Cobalt Scale)
D1353 Test Method for Nonvolatile Matter in Volatile Sol-
5. Sampling
vents for Use in Paint, Varnish, Lacquer, and Related
Products
5.1 The material shall be sampled in accordance with
D1364 Test Method for Water in Volatile Solvents (Karl Practice E300.
6. Test Methods
1
This specification is under the jurisdiction of ASTM Committee D01 on Paint
6.1 The properties enumerated in this specification shall be
and Related Coatings, Materials, andApplications and is the direct responsibility of
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates. determined in accordance with the following ASTM test
Current edition approved Nov. 1, 2011. Published December 2011. Originally
methods:
approved in 1943. Last previous edition approved in 2005 as D740 – 05. DOI:
6.1.1 Acidity—Test Method D1613.
10.1520/D0740-11.
2
Also known as butanone and 2–butanone.
3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
4
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM Available from Standardization Documents Order Desk, DODSSP, Bldg. 4,
Standards volume information, refer to the standard’s Document Summary page on Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098, http://
the ASTM website. dodssp.daps.dla.mil.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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D740−11
TABLE 1 Physical and Chemical Properties of Methyl Ethyl
6.1.4 Distillation Range—Test Method D1078, using a tem-
Ketone
perature measuring device having a range of 48 to 102°C and
Type I Type II
a resolution of 0.1°C.
Commercial reference regular urethane-grade
6.1.5 Nonvolatile Matter—Test Method D1353.
A
Acidity , weight %, max 0.005 0.003
B
6.1.6 Purity—Test Method D2804.
Alcohol , weight %, max . 0.5
C
Color, Pt-Co scale, max 10 10
6.1.7 Apparent Specific Gravity—Determine the apparent
Distillation range, 760 mm Hg,°C
specific gravity by any method that is accurate to the third
Initial
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D740–05 Designation: D740 – 11
Standard Specification for
,
1 2
Methyl Ethyl Ketone
This standard is issued under the fixed designation D740; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope*
1.1 This specification covers two types of methyl ethyl ketone that are used primarily as solvents in lacquers and industrial
coatings, but also in adhesives, printing inks, lube oil dewaxing, and as chemical intermediates.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard,
an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing
the specification limit, in accordance with the rounding-off method of Practice E29.
1.4 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet for materials listed in this
specification.
2. Referenced Documents
3
2.1 ASTM Standards:
D268 Guide for Sampling and Testing Volatile Solvents and Chemical Intermediates for Use in Paint and Related Coatings and
Material
D1078 Test Method for Distillation Range of Volatile Organic Liquids
D1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D1353 Test Method for Nonvolatile Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related Products
D1364 Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration Method)
D1613 Test Method for Acidity in Volatile Solvents and Chemical Intermediates Used in Paint, Varnish, Lacquer, and Related
Products
D2804 Test Method for Purity of Methyl Ethyl Ketone By Gas Chromatography
D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
D5386 Test Method for Color of Liquids Using Tristimulus Colorimetry E1Specification for ASTM Liquid-in-Glass
Thermometers
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E300 Practice for Sampling Industrial Chemicals
2.2 U.S. Federal Specification:
4
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging of
3. Classification
3.1 Methyl ethyl ketone shall be of the following types, as specified:
3.1.1 Type I—regular, and
3.1.2 Type II—urethane grade.This type may be suited for use in urethane coatings, provided that the water content and alcohol
content are acceptable.
1
This specification is under the jurisdiction of ASTM Committee D01 on Paint and Related Coatings, Materials, and Applications and is the direct responsibility of
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates.
Current edition approved May 15, 2005. Published May 2005. Originally approved in 1943. Last previous edition approved in 2001 as D740–94(2001). DOI:
10.1520/D0740-05.
Current edition approved Nov. 1, 2011. Published December 2011. Originally approved in 1943. Last previous edition approved in 2005 as D740 – 05. DOI:
10.1520/D0740-11.
2
Also known as butanone and 2–butanone.
3
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at [e-mail]. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
4
Available from Standardization Documents Order Desk, DODSSP, Bldg. 4, Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098, http://dodssp.daps.dla.mil.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D740 – 11
4. Properties
4.1 The physical and chemical properties of methyl ethyl ketone shall conform to the requirements specified in Table 1.
5. Sampling
5.1 The material shall be sampled in accordance with Practice E300.
6. Test Methods
6.1 The properties enumerated in this specification shall be determined in accordance with the following ASTM test methods:
6.1.1 Acidity—Test Method D1613.
6.1.2 Alcohol—Test Method D2804.
6.1.3 Color—Test Method D1209 (see Fo
...