ASTM D800-05(2014)
(Test Method)Standard Test Methods of Chemical Analysis of Industrial Metal Cleaning Compositions (Withdrawn 2023)
Standard Test Methods of Chemical Analysis of Industrial Metal Cleaning Compositions (Withdrawn 2023)
ABSTRACT
These test methods describe the procedures for the chemical analysis of industrial metal cleaning compositions in solid, paste, or liquid form. These cleaning compositions may contain caustic alkalies, silicates, phosphates, chromates, carbonates, bicarbonates, borates, sulfates, sulfites, nitrates, chlorides, soaps, rosin, sulfonated wetting agents, anti-foaming agents, organic bases, organic solvents, organic coupling agents, and sometimes inorganic acid salts or organic acids. Percentage of total sodium oxide, percentage of potassium oxide, percentage of free sodium hydroxide, percentage of water, percentage of losses, percentage of matter insoluble in alcohol, percentage of fatty acids, percentage of rosin, percentage of synthetic detergent or wetting agent, percentage of silica, percentage of phosphorus pentoxide, percentage of carbon dioxide, percentage of sodium chloride, percentage of sodium sulfate, and percentage of volatile hydrocarbons test methods shall be performed to conform with the specified requirements.
SCOPE
1.1 These test methods describe the procedures for the chemical analysis of industrial metal cleaning compositions in solid, paste, or liquid form. These cleaning compositions may contain caustic alkalies, silicates, phosphates, chromates, carbonates, bicarbonates, borates, sulfates, sulfites, nitrates, chlorides, soaps, rosin, sulfonated wetting agents, anti-foaming agents, organic bases, organic solvents, organic coupling agents, and sometimes inorganic acid salts or organic acids. Occasionally, such cleaning compositions may contain sulfonated oils; in such cases, reference should be made to Method D500. The examination under a low power microscope or magnifying glass, supplemented by a few qualitative tests, will often indicate the number of components and their identity.
1.2 The analytical methods appear in the following order:
Section
Preparation of Sample
4
Total Alkalinity as Na2O
5 – 8
Total Fatty Acids (and Rosin)
9 and 10
Na2O Combined with Fatty Acids (and Rosin)
11 and 12
Anhydrous Soap
13
—Rosin (McNicoll Test Method):
Qualitative
14 and 15
Quantitative
16 – 19
Total Silica Calculated as SiO2
20 – 23
Phosphates:
Qualitative
24 and 25
Quantitative
26 – 18
Combined Sodium and Potassium Oxides
34 – 37
Chlorides
38 – 40
Sulfates
41 – 43
Water, Distillation Test Method
44 – 47
Carbon Dioxide by Evolution-Absorption Test Method
48 – 52
Loss at 105°C
53 and 54
Total Matter Insoluble in Alcohol
55 – 57
Free Alkali
58 – 60
Synthetic Detergent or Wetting Agent
61 and 62
Volatile Hydrocarbons
63 – 67
Loss on Ignition
68 and 69
Report
70 and 71
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Material Safety Data Sheets are available for reagents and materials. Review them for hazards prior to usage. See 6.1 for a specific hazards statement.
WITHDRAWN RATIONALE
These test methods describe the procedures for the chemical analysis of industrial metal cleaning compositions in solid, paste, or liquid form.
Formerly under the jurisdiction of Committee D12 on Soaps and Other Detergents, this test method was withdrawn in January 2023 in accordance with section 10.6.3 of the Regulations Governing ASTM Technical Committees, which requires that standards shall be updated by the end of the eighth year since the last approval date.
General Information
Standards Content (Sample)
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D800 − 05 (Reapproved 2014)
Standard Test Methods of
Chemical Analysis of Industrial Metal Cleaning
1
Compositions
This standard is issued under the fixed designation D800; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope
Volatile Hydrocarbons 63–67
Loss on Ignition 68 and 69
1.1 These test methods describe the procedures for the
Report 70 and 71
chemical analysis of industrial metal cleaning compositions in
1.3 The values stated in SI units are to be regarded as
solid, paste, or liquid form. These cleaning compositions may
standard. No other units of measurement are included in this
contain caustic alkalies, silicates, phosphates, chromates,
standard.
carbonates, bicarbonates, borates, sulfates, sulfites, nitrates,
1.4 This standard does not purport to address all of the
chlorides, soaps, rosin, sulfonated wetting agents, anti-foaming
safety concerns, if any, associated with its use. It is the
agents, organic bases, organic solvents, organic coupling
responsibility of the user of this standard to establish appro-
agents, and sometimes inorganic acid salts or organic acids.
priate safety and health practices and determine the applica-
Occasionally, such cleaning compositions may contain sul-
bility of regulatory limitations prior to use. Material Safety
fonated oils; in such cases, reference should be made to
Data Sheets are available for reagents and materials. Review
MethodD500.Theexaminationunderalowpowermicroscope
them for hazards prior to usage. See 6.1 for a specific hazards
or magnifying glass, supplemented by a few qualitative tests,
statement.
will often indicate the number of components and their
identity.
2. Referenced Documents
1.2 The analytical methods appear in the following order: 2
2.1 ASTM Standards:
Section
D500 Test Methods of ChemicalAnalysis of Sulfonated and
Sulfated Oils
Preparation of Sample 4
Total Alkalinity as Na O 5–8 D841 Specification for Nitration Grade Toluene
2
Total Fatty Acids (and Rosin) 9 and 10
D843 Specification for Nitration Grade Xylene
Na O Combined with Fatty Acids (and Rosin) 11 and 12
2
D1193 Specification for Reagent Water
Anhydrous Soap 13
—Rosin (McNicoll Test Method):
Qualitative 14 and 15 3. Purity of Reagents and Materials
Quantitative 16–19
3.1 Purity of Reagents—Reagent grade chemicals shall be
Total Silica Calculated as SiO 20–23
2
Phosphates:
used in all tests. Unless otherwise indicated, it is intended that
Qualitative 24 and 25
all reagents shall conform to the specifications of the Commit-
Quantitative 26–18
tee onAnalytical Reagents of theAmerican Chemical Society,
Combined Sodium and Potassium Oxides 34–37
3
Chlorides 38–40
where such specifications are available. Other grades may be
Sulfates 41–43
used, provided it is first ascertained that the reagent is of
Water, Distillation Test Method 44–47
sufficiently high purity to permit its use without lessening the
Carbon Dioxide by Evolution-Absorption Test Method 48–52
Loss at 105°C 53 and 54
accuracy of the determination.
Total Matter Insoluble in Alcohol 55–57
Free Alkali 58–60
Synthetic Detergent or Wetting Agent 61 and 62
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
1
These test methods are under the jurisdiction of ASTM Committee D12 on the ASTM website.
3
Soaps and Other Detergents and are the direct responsibility of Subcommittee Reagent Chemicals, American Chemical Society Specifications, American
D12.12 on Analysis and Specifications of Soaps, Synthetics, Detergents and their Chemical Society, Washington, DC. For suggestions on the testing of reagents not
Components. listed by the American Chemical Society, see Analar Standards for Laboratory
Current edition approved Jan. 1, 2014. Published February 2014. Originally Chemicals, BDH Ltd., Poole, Dorset, U.K., and the United States Pharmacopeia
approved in 1944. Last previous edition approved in 2005 as D800 – 05. DOI: and National Formulary, U.S. Pharmacopeial Convention, Inc. (USPC), Rockville,
10.1520/D0800-05R14. MD.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
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D800 − 05 (2014)
3.2 Unless otherwise indicated, references to water shall be where:
understood to mean reagent water conforming to Specification
A = millilitres of 0.5 N
...
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