Standard Test Method for Determining Chemical Emissions from Spray Polyurethane Foam (SPF) Insulation using Micro-Scale Environmental Test Chambers

SIGNIFICANCE AND USE
6.1 SPF insulation is applied and formed onsite, which creates unique challenges for measuring product emissions. This test method provides a way to measure post-application chemical emissions from SPF insulation.  
6.2 This test method can be used to identify compounds that emit from SPF insulation products, and the emission factors may be used to compare emissions at the specified sampling times and test conditions.  
6.3 Emission data may be used in product development, manufacturing quality control and comparison of field samples.  
6.4 This test method is used to determine chemical emissions from freshly applied SPF insulation samples. The utility of this test method for investigation of odors in building scale environments has not been demonstrated at this time.
SCOPE
1.1 This test method is used to identify and to measure the emissions of volatile organic compounds (VOCs) emitted from samples of cured spray polyurethane foam (SPF) insulation using micro-scale environmental test chambers combined with specific air sampling and analytical methods for VOCs.  
1.2 Specimens prepared from product samples are maintained at specified conditions of temperature, humidity, airflow rate, and elapsed time in micro-scale chambers that are described in Practice D7706. Air samples are collected periodically at the chamber exhaust at the flow rate of the micro-scale chambers.  
1.2.1 Samples for formaldehyde and other low-molecular weight carbonyl compounds are collected on treated silica gel cartridges and are analyzed by high performance liquid chromatography (HPLC) as described in Test Method D5197 and ISO 16000-3.  
1.2.2 Samples for other VOCs are collected on multi-sorbent samplers and are analyzed by thermal-desorption gas chromatography / mass spectrometry (TD-GC/MS) as described in U.S. EPA Compendium Method TO-17 and ISO 16000-6.  
1.3 This test method is intended specifically for SPF insulation products. Compatible product types include two component, high pressure and two-component, low pressure formulations of open-cell and closed-cell SPF insulation.  
1.4 VOCs that can be sampled and analyzed by this test method generally include organic blowing agents such as 1,1,1,3,3-pentafluoropropane, formaldehyde and other carbonyl compounds, residual solvents, and some amine catalysts. Emissions of some organic flame retardants can be measured after 24 h with this method, such as tris (chloroisopropyl) phosphate (TCPP).  
1.5 This test method does not cover the sampling and analysis of methylene diphenyl diisocyanate (MDI) or other isocyanates.  
1.6 Area-specific and mass-specific emission rates are quantified at the elapsed times and chamber conditions as specified in 13.2 and 13.3 of this test method.  
1.7 This test method is used to identify emitted compounds and to estimate their emission factors at specific times. The emission factors are based on specified conditions, therefore, use of the data to predict emissions in other environments may not be appropriate and is beyond the scope of this test method. The results may not be representative of other test conditions or comparable with other test methods.  
1.8 This test method is primarily intended for freshly applied, SPF insulation samples that are sprayed and packaged as described in Practice D7859. The measurement of emissions during spray application and within the first hour following application is outside of the scope of this test method.  
1.9 This test method can also be used to measure the emissions from SPF insulation samples that are collected from building sites where the insulation has already been applied. Potential uses of such measurements include investigations of odor complaints after product application. However, the specific details of odor investigations and other indoor air quality (IAQ) investigations are outside of the scope of this test method.  
1.10 The values stated in SI units are to be regarde...

General Information

Status
Published
Publication Date
31-Aug-2023
Technical Committee
Drafting Committee
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ASTM D8142-23 - Standard Test Method for Determining Chemical Emissions from Spray Polyurethane Foam (SPF) Insulation using Micro-Scale Environmental Test Chambers
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Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D8142 − 23
Standard Test Method for
Determining Chemical Emissions from Spray Polyurethane
Foam (SPF) Insulation using Micro-Scale Environmental
1
Test Chambers
This standard is issued under the fixed designation D8142; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 1.5 This test method does not cover the sampling and
analysis of methylene diphenyl diisocyanate (MDI) or other
1.1 This test method is used to identify and to measure the
isocyanates.
emissions of volatile organic compounds (VOCs) emitted from
1.6 Area-specific and mass-specific emission rates are quan-
samples of cured spray polyurethane foam (SPF) insulation
tified at the elapsed times and chamber conditions as specified
using micro-scale environmental test chambers combined with
in 13.2 and 13.3 of this test method.
specific air sampling and analytical methods for VOCs.
1.7 This test method is used to identify emitted compounds
1.2 Specimens prepared from product samples are main-
and to estimate their emission factors at specific times. The
tained at specified conditions of temperature, humidity, airflow
emission factors are based on specified conditions, therefore,
rate, and elapsed time in micro-scale chambers that are
use of the data to predict emissions in other environments may
described in Practice D7706. Air samples are collected peri-
not be appropriate and is beyond the scope of this test method.
odically at the chamber exhaust at the flow rate of the
The results may not be representative of other test conditions or
micro-scale chambers.
comparable with other test methods.
1.2.1 Samples for formaldehyde and other low-molecular
1.8 This test method is primarily intended for freshly
weight carbonyl compounds are collected on treated silica gel
applied, SPF insulation samples that are sprayed and packaged
cartridges and are analyzed by high performance liquid chro-
as described in Practice D7859. The measurement of emissions
matography (HPLC) as described in Test Method D5197 and
during spray application and within the first hour following
ISO 16000-3.
application is outside of the scope of this test method.
1.2.2 Samples for other VOCs are collected on multi-
sorbent samplers and are analyzed by thermal-desorption gas 1.9 This test method can also be used to measure the
emissions from SPF insulation samples that are collected from
chromatography / mass spectrometry (TD-GC/MS) as de-
scribed in U.S. EPA Compendium Method TO-17 and ISO building sites where the insulation has already been applied.
Potential uses of such measurements include investigations of
16000-6.
odor complaints after product application. However, the spe-
1.3 This test method is intended specifically for SPF insu-
cific details of odor investigations and other indoor air quality
lation products. Compatible product types include two
(IAQ) investigations are outside of the scope of this test
component, high pressure and two-component, low pressure
method.
formulations of open-cell and closed-cell SPF insulation.
1.10 The values stated in SI units are to be regarded as
1.4 VOCs that can be sampled and analyzed by this test
standard. No other units of measurement are included in this
method generally include organic blowing agents such as
standard.
1,1,1,3,3-pentafluoropropane, formaldehyde and other carbo-
1.11 This standard does not purport to address all of the
nyl compounds, residual solvents, and some amine catalysts.
safety concerns, if any, associated with its use. It is the
Emissions of some organic flame retardants can be measured
responsibility of the user of this standard to establish appro-
after 24 h with this method, such as tris (chloroisopropyl)
priate safety, health, and environmental practices and deter-
phosphate (TCPP).
mine the applicability of regulatory limitations prior to use.
1.12 This international standard was developed in accor-
dance with internationally recognized principles on standard-
1
This test method is under the jurisdiction of ASTM Committee D22 on Air
ization established in the Decision on Principles for the
Quality and is the direct responsibility of Subcommittee D22.05 on Indoor Air.
Development of International Standards, Guides and Recom-
Current edition approved Sept. 1, 2023. Published October 2023. Originally
ɛ1
mendations issued by the World Trade Organization Technical
approved in 2017. Last previous edition approved in 2017 as D8142 – 17 . DOI:
10.1
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
´1
Designation: D8142 − 17 D8142 − 23
Standard Test Method for
Determining Chemical Emissions from Spray Polyurethane
Foam (SPF) Insulation using Micro-Scale Environmental
1
Test Chambers
This standard is issued under the fixed designation D8142; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1
ε NOTE—Editorially added research report information to Section 16 and Appendix X1 in February 2020.
1. Scope
1.1 This test method is used to identify and to measure the emissions of volatile organic compounds (VOCs) emitted from samples
of cured spray polyurethane foam (SPF) insulation using micro-scale environmental test chambers combined with specific air
sampling and analytical methods for VOCs.
1.2 Specimens prepared from product samples are maintained at specified conditions of temperature, humidity, airflow rate, and
elapsed time in micro-scale chambers that are described in Practice D7706. Air samples are collected periodically at the chamber
exhaust at the flow rate of the micro-scale chambers.
1.2.1 Samples for formaldehyde and other low-molecular weight carbonyl compounds are collected on treated silica gel cartridges
and are analyzed by high performance liquid chromatography (HPLC) as described in Test Method D5197 and ISO 16000-3.
1.2.2 Samples for other VOCs are collected on multi-sorbent samplers and are analyzed by thermal-desorption gas chromatog-
raphy / mass spectrometry (TD-GC/MS) as described in U.S. EPA Compendium Method TO-17 and ISO 16000-6.
1.3 This test method is intended specifically for SPF insulation products. Compatible product types include two component, high
pressure and two-component, low pressure formulations of open-cell and closed-cell SPF insulation.
1.4 VOCs that can be sampled and analyzed by this test method generally include organic blowing agents such as
1,1,1,3,3-pentafluoropropane, formaldehyde and other carbonyl compounds, residual solvents, and some amine catalysts.
Emissions of some organic flame retardants can be measured after 24 h with this method, such as tris (chloroisopropyl) phosphate
(TCPP).
1.5 This test method does not cover the sampling and analysis of methylene diphenyl diisocyanate (MDI) or other isocyanates.
1.6 Area-specific and mass-specific emission rates are quantified at the elapsed times and chamber conditions as specified in 13.2
and 13.3 of this test method.
1.7 This test method is used to identify emitted compounds and to estimate their emission factors at specific times. The emission
1
This test method is under the jurisdiction of ASTM Committee D22 on Air Quality and is the direct responsibility of Subcommittee D22.05 on Indoor Air.
Current edition approved Oct. 1, 2017Sept. 1, 2023. Published October 2017October 2023. Originally approved in 2017. Last previous edition approved in 2017 as
ɛ1
D8142 – 17 . DOI: 10.1520/D8142-17E01.10.1520/D8142-23.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D8142 − 23
factors are based on specified conditions, therefore, use of the data to predict emissions in other environments may not be
appropriate and is beyond the scope of this test method. The results may not be representative of other test conditions or
comparable with other test methods.
1.8 This test method is primarily intended for freshly applied, SPF insulation samples that are sprayed and packaged as described
in Practice D7859. The measurement of emissions during spray application and within the first hour following application is
outside of the scope of this test method.
1.9 This test method can also be used to measure the emissions from SPF insulation samples that are collected from building sites
where the insulation has already been applied. Potential uses of such measurements include investigations of odor complaints after
product application. However, the specific details of odor investigations and other indoor air quality (IAQ) investigations are
outside of the scope of this test method.
1.10 The values stated in SI units are to be regarded as standard. No other units of measure are used.measurement are included
in this standard.
1.11 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is th
...

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