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ASTM D803-02

(Test Method)

Standard Test Methods for Testing Tall Oil

Standard Test Methods for Testing Tall Oil

SCOPE
1.1 These test methods cover the test procedures to be applied to whole tall oils or refined tall oils. Previous editions of these test methods have described test procedures that are used to test tall oil fatty acid, rosin, and other tall oil-derived products as well as test crude and refined tall oil. Consequently, these test methods are widely cited in reference books and industry literature for the testing of tall oil-derived products.
1.1.1 In this current revision, procedural details of some of the often-cited test methods have been removed and the test methods consolidated with other existing test methods. In such cases the consolidated methods, applicable to all tall oil-derived products, are referenced.
1.2 The procedures appear in the following order:Physical TestsSectionsViscosity:Brookfield Method (Preferred Method)7Bubble Time Method8Pour Point9Flash Point10Color11Moisture:12Insoluble Matter13Ash14Chemical AnalysisAcid Number17Saponification Number18Rosin Acids19Unsaponifiable Matter20Fatty Acids21
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
09-May-2002
ICS
87.060.20 - Binders
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.34 - Pine Chemicals and Hydrocarbon Resins
Current Stage
Ref Project

Relations

Replaces
ASTM D803-97 - Standard Test Methods for Testing Tall Oil
Effective Date
10-May-2002
Replaced By
ASTM D803-03 - Standard Test Methods for Testing Tall Oil
Effective Date
10-May-2003
Referred By
ASTM D890-12(2022) - Standard Test Method for Water in Liquid Pine Chemicals
Effective Date
10-May-2002
Referred By
ASTM D802-02(2022) - Standard Test Methods for Sampling and Testing Pine Oils
Effective Date
10-May-2002
Referred By
ASTM D1585-15(2020) - Standard Test Methods for Fatty Acids Content of Pine Chemicals, Including Rosin, Tall Oil, and Related Products
Effective Date
10-May-2002
Referred By
ASTM D465-15(2020) - Standard Test Methods for Acid Number of Pine Chemical Products Including Tall Oil and Other Related Products
Effective Date
10-May-2002
Referred By
ASTM D464-15(2020) - Standard Test Methods for Saponification Number of Pine Chemical Products Including Tall Oil and Other Related Products
Effective Date
10-May-2002
Referred By
ASTM D1065-18(2022) - Standard Test Method for Unsaponifiable Matter in Pine Chemicals, Including Rosin, Tall Oil, and Related Products
Effective Date
10-May-2002
Referred By
ASTM E203-23 - Standard Test Method for Water Using Volumetric Karl Fischer Titration
Effective Date
10-May-2002

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ASTM D803-02 - Standard Test Methods for Testing Tall Oil
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Standards Content (Sample)

NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 803 – 02
Standard Test Methods for
1
Testing Tall Oil
This standard is issued under the fixed designation D 803; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
2
1. Scope D 97 Test Method for Pour Point of Petroleum Products
D 269 Test Method for Insoluble Matter in Rosin and Rosin
1.1 These test methods cover the test procedures to be
3
Derivatives
applied to whole tall oils or refined tall oils. Previous editions
D 464 Test Methods for Saponification Number of Naval
of these test methods have described test procedures that are
Store Products Including Tall Oil and Other Related
used to test tall oil fatty acid, rosin, and other tall oil-derived
3
Products
products as well as test crude and refined tall oil. Consequently,
D 465 Test Methods for Acid Number of Naval Store
these test methods are widely cited in reference books and
3
Products Including Tall Oil and Other Related Products
industry literature for the testing of tall oil-derived products.
3
D 890 Test Method for Water in Liquid Naval Stores
1.1.1 In this current revision, procedural details of some of
D 1065 Test Method for Unsaponifiable Matter in Naval
the often-cited test methods have been removed and the test
3
Stores, Including Rosin, Tall Oil, and Related Products
methods consolidated with other existing test methods. In such
D 1240 Test Methods for Rosin Acids Content of Naval
cases the consolidated methods, applicable to all tall oil-
3
Stores, Including Rosin, Tall Oil, and Related Products
derived products, are referenced.
D 1466 Test Method for Sampling Liquid Oils and Fatty
1.2 The procedures appear in the following order:
Acids Commonly Used in Paints, Varnishes, and Related
Physical Tests Sections
3
Materials
Viscosity:
Brookfield Method (Preferred Method) 7
D 1544 Test Method for Color of Transparent Liquids
Bubble Time Method 8
4
(Gardner Color Scale)
Pour Point 9
D 1545 Test Method for Viscosity of Transparent Liquids
Flash Point 10
3
Color 11
by Bubble Time Method
Moisture: 12
D 1585 Test Methods for Fatty Acids Content of Naval
Insoluble Matter 13
3
Ash 14 Stores Including Rosin, Tall Oil, and Related Products
Chemical Analysis
D 2196 Test Methods for Rheological Properties of Non-
Acid Number 17
Newtonian Materials by Rotational (Brookfield) Viscom-
Saponification Number 18
4
eter
Rosin Acids 19
Unsaponifiable Matter 20
D 3278 Test Methods for Flash Point of Liquids by Small
Fatty Acids 21
4
Scale Closed-Cup Apparatus
1.3 This standard does not purport to address all of the
D 5974 Test Methods for Fatty and Rosin Acids in Tall Oil
safety concerns, if any, associated with its use. It is the
Fractionation Products By Capillary Gas Chromatogra-
3
responsibility of the user of this standard to establish appro-
phy
priate safety and health practices and determine the applica-
D 6166 Test Method for Color of Naval Stores and Related
3
bility of regulatory limitations prior to use.
Products (Instrumental Determination of Gardner Color)
5
E 300 Practice for Sampling Industrial Chemicals
2. Referenced Documents
3. Significance and Use
2.1 ASTM Standards:
D 92 Test Method for Flash and Fire Points by Cleveland
3.1 Tall oil, both crude and refined, is an important by-
2
Open Cup
product of the alkaline (kraft) pulping of pine wood. It consists
D 93 Test Methods for Flash Point by Pensky-Martens
primarily of fatty acids, resin acids, and neutral materials; the
2
Closed Tester
levels of these various components depend on factors such as
the species of pine tree, geographic location, climate, etc.
1
3.1.1 Tall oil is used primarily as a commercial source of
These test methods are under the jurisdiction of ASTM Committee D01 on
Paint and Related Coatings, Materials, and Applications and are the direct
responsibility of Subcommittee D01.34 on Naval Stores.
3
Current edition approved May 10, 2002. Published July 2002. Originally Annual Book of ASTM Standards, Vol 06.03.
4
published as D 803 – 44 T. Last previous edition D 803 – 97. Annual Book of ASTM Standards, Vol 06.01.
2 5
Annual Book of ASTM Standards, Vol 05.01. Annual Book of ASTM Standards, Vol 15.05.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D 803
fatty acids and rosin, and, therefore, reliable methods for the D 1545. The testing temperature shall be 210°F (99°C) un
...

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