ASTM D1319-20
(Test Method)Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
SIGNIFICANCE AND USE
5.1 The determination of the total volume percent of saturates, olefins, and aromatics in petroleum fractions is important in characterizing the quality of petroleum fractions as gasoline blending components and as feeds to catalytic reforming processes. This information is also important in characterizing petroleum fractions and products from catalytic reforming and from thermal and catalytic cracking as blending components for motor and aviation fuels. This information is also important as a measure of the quality of fuels, such as specified in Specification D1655.
SCOPE
1.1 This test method covers the determination of hydrocarbon types of total aromatics, total olefins, and total saturates in petroleum fractions that distill below 315 °C. Samples containing dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.
Note 1: For the determination of olefins below 0.3 % by volume, other test methods are available, such as Test Method D2710.
1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision statement does not apply to narrow boiling petroleum fractions near the 315 °C limit. Such samples are not eluted properly, and results are erratic.
1.3 This test method is also applicable to automotive spark-ignition engine fuels which are gasolines with and without blended oxygenates, such as alcohols and ethers (for example MTBE, ethanol) and where gasoline is the primary component by volume in the blend.
1.4 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar sands, has not been determined, and the precision statement may or may not apply to such products.
1.5 This test method has two precision statements depicted in Table 3 and Table 4.
1.5.1 Table 3 is applicable to fuels that do not contain oxygenated blending components over the test method concentration working ranges from 5 % to 99 % by volume aromatics, 1 % to 55 % by volume olefins, and 1 % to 95 % by volume saturates in petroleum fractions and with a final boiling point of
1.5.2 Table 4 precision was derived from an ILS containing only blended oxygenated (for example, MTBE, ethanol) and non-oxygenated automotive spark-ignition engine fuels (gasolines) and is applicable only in the test method concentration working range of 13 % to 40 % by volume aromatics, 4 % to 33 % by volume olefins, and 45 % to 68 % by volume saturates.
1.5.3 Non-oxygenated automotive spark-ignition engine fuels (gasolines) outside the inclusive valid test result reporting concentration ranges of Table 4 may use the precision in Table 3 and its applicable concentration ranges.
1.6 The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether (TAME), and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed, correct the results to a total-sample basis.
1.7 This test method includes a relative bias section based on Practice D6708 accuracy assessment between Test Method D1319 and Test Method D5769 for total aromatics in spark-ignition engine fuels as a possible Test Method D1319 alternative to Test Method D5769 for U.S. EPA spark-ignition engine fuel regulations reporting. The Practice D6708 derived correlation equation is only applicable for fuels in the total aromatic concentration range from 3.3 % to 34.4 % by volume as measured by Test Method D1319 and the distillation temperature T95, at which 95 % of the sample has evaporated, ranges from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F) when tested according to ...
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Designation: D1319 − 20
Standard Test Method for
Hydrocarbon Types in Liquid Petroleum Products by
1
Fluorescent Indicator Adsorption
This standard is issued under the fixed designation D1319; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope* non-oxygenated automotive spark-ignition engine fuels (gaso-
lines) and is applicable only in the test method concentration
1.1 This test method covers the determination of hydrocar-
working range of 13 % to 40 % by volume aromatics, 4 % to
bon types of total aromatics, total olefins, and total saturates in
33 % by volume olefins, and 45 % to 68 % by volume
petroleum fractions that distill below 315 °C. Samples contain-
saturates.
ing dark-colored components that interfere in reading the
1.5.3 Non-oxygenated automotive spark-ignition engine fu-
chromatographic bands cannot be analyzed.
els (gasolines) outside the inclusive valid test result reporting
NOTE1—Forthedeterminationofolefinsbelow0.3 %byvolume,other
concentration ranges of Table 4 may use the precision in Table
test methods are available, such as Test Method D2710.
3 and its applicable concentration ranges.
1.2 This test method is intended for use with full boiling
1.6 The oxygenated blending components, methanol,
range products. Cooperative data have established that the
ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether
precisionstatementdoesnotapplytonarrowboilingpetroleum
(TAME), and ethyl-tert-butylether (ETBE), do not interfere
fractions near the 315 °C limit. Such samples are not eluted
with the determination of hydrocarbon types at concentrations
properly, and results are erratic.
normally found in commercial blends. These oxygenated
1.3 This test method is also applicable to automotive spark-
components are not detected since they elute with the alcohol
ignition engine fuels which are gasolines with and without
desorbent. Other oxygenated compounds shall be individually
blended oxygenates, such as alcohols and ethers (for example
verified. When samples containing oxygenated blending com-
MTBE, ethanol) and where gasoline is the primary component
ponentsareanalyzed,correcttheresultstoatotal-samplebasis.
by volume in the blend.
1.7 This test method includes a relative bias section based
1.4 The applicability of this test method to products derived
on Practice D6708 accuracy assessment between Test Method
from fossil fuels other than petroleum, such as coal, shale, or
D1319 and Test Method D5769 for total aromatics in spark-
tar sands, has not been determined, and the precision statement
ignition engine fuels as a possible Test Method D1319 alter-
may or may not apply to such products.
native to Test Method D5769 for U.S. EPA spark-ignition
1.5 This test method has two precision statements depicted
engine fuel regulations reporting. The Practice D6708 derived
in Table 3 and Table 4.
correlation equation is only applicable for fuels in the total
1.5.1 Table 3 is applicable to fuels that do not contain
aromatic concentration range from 3.3 % to 34.4 % by volume
oxygenated blending components over the test method concen-
as measured by Test Method D1319 and the distillation
trationworkingrangesfrom5 %to99 %byvolumearomatics,
temperature T , at which 95 % of the sample has evaporated,
95
1 % to 55 % by volume olefins, and 1 % to 95 % by volume
ranges from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F) when
saturatesinpetroleumfractionsandwithafinalboilingpointof
tested according to Test Method D86.
<315 °C. It may or may not apply to automotive gasolines
1.7.1 The applicable Test Method D5769 range for total
containing lead antiknock mixtures.
aromatics is 3.7 % to 29.4 % by volume as reported by Test
1.5.2 Table 4 precision was derived from an ILS containing
Method D5769 and the distillation temperature T values, at
95
only blended oxygenated (for example, MTBE, ethanol) and
which 95 % of the sample has evaporated, when tested
according to Test Method D86 is from 149.1 °C to 196.6 °C
(300.3 °F to 385.8 °F).
1
This test method is under the jurisdiction of ASTM Committee D02 on
1.7.2 Regulations may change over time and the user is
Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of
advised to verify current regulatory requirements.
Subcommittee D02.04.0C on Liquid Chromatography.
Current edition approved July 15, 2020. Published September 2020. Originally
1.8 WARNING—Mercury has been designated by many
approved in 1954. Last previous edition approved in 2019 as D1319 – 19.
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D1319 − 19 D1319 − 20
Standard Test Method for
Hydrocarbon Types in Liquid Petroleum Products by
1
Fluorescent Indicator Adsorption
This standard is issued under the fixed designation D1319; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope*
1.1 This test method covers the determination of hydrocarbon types over the concentration ranges from 5 % to 99 % by volume
aromatics, 0.3 % to 55 % by volume olefins, and 1 % to 95 % by volume of total aromatics, total olefins, and total saturates in
petroleum fractions that distill below 315 °C. This test method may apply to concentrations outside these ranges, but the precision
has not been determined. Samples containing dark-colored components that interfere in reading the chromatographic bands cannot
be analyzed.
NOTE 1—For the determination of olefins below 0.3 % by volume, other test methods are available, such as Test Method D2710.
1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision
statement does not apply to narrow boiling petroleum fractions near the 315 °C limit. Such samples are not eluted properly, and
results are erratic.
1.3 This test method includes a relative bias section based on Practice is also applicable to automotive D6708 accuracy assessment
between Test Method D1319 and Test Method D5769 for total aromatics in spark-ignition engine fuels as a possible Test
Methodwhich are gasolines with and without blended oxygenates, such as alcohols and ethers (for D1319 alternative to Test
Methodexample MTBE, ethanol) and where D5769 for U.S. EPA spark-ignition engine fuel regulations reporting. The Practice
gasoline D6708 derived correlation equation is only applicable for fuels in the total aromatic concentration range from 3.3 % to
34.4 % by volume as measured by Test Method is the primary component by volume in D1319 and the distillation temperature
Tthe blend. , at which 95 % of the sample has evaporated, ranges from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F) when tested
95
according to Test Method D86.
1.3.1 The applicable Test Method D5769 range for total aromatics is 3.7 % to 29.4 % by volume as reported by Test Method
D5769 and the distillation temperature T values, at which 95 % of the sample has evaporated, when tested according to Test
95
Method D86 is from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F).
1.4 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar sands,
has not been determined, and the precision statement may or may not apply to such products.
1.5 This test method has two precision statements depicted in tables. The first table is applicable to unleaded fuels that do not
1
This test method is under the jurisdiction of ASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcommittee
D02.04.0C on Liquid Chromatography.
Current edition approved Aug. 1, 2019July 15, 2020. Published September 2019September 2020. Originally approved in 1954. Last previous edition approved in 20182019
as D1319 – 18.D1319 – 19. DOI: 10.1520/D1319-19. 10.1520/D1319-20.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
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D1319 − 20
contain oxygenated blending components. It may or may not apply to automotive gasolines containing lead antiknock mixtures.
The second table is applicable to oxygenate blended (for example, MTBE, ethanol) automotive spark ignition fuel samples with
a concentration range of 13 % to 40 % by volume aromatics, 4 % to 33 % by volume olefins, and 45 % to 68 % by volume
saturates.Table 3 and Table 4.
1.5.1 Table 3 is applicable to fuels that do not contain oxygenated blending components over the test method concentration
working ranges from 5 % to 99 % by volume aromatics, 1 % to 55 % by volume olefins, and 1 % to 95 % by volume saturates
in petroleum fractions and with a final boiling point of <315 °C. It may or may not apply to automotive gasolines containing lead
antiknoc
...
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