Standard Test Method for Portland-Cement Content of Hardened Hydraulic-Cement Concrete

SIGNIFICANCE AND USE
This test method consists of two independent procedures: an oxide-analysis procedure that consists of two sub-procedures and an extraction procedure. Each procedure requires a substantial degree of chemical skill and relatively elaborate chemical instrumentation. Except for the influence of known interferences, determined cement contents are normally equal to, or slightly greater than, actual values except for the Maleic Acid procedure where results can also be significantly low when the paste is carbonated (Note 1).
Note 1—With certain limitations, the procedure is also applicable for estimating the combined content of portland cement and pozzolan or slag in concretes made with blended hydraulic cement and blends of portland cement with pozzolans or slags. The results of this test method when applied to concretes made with blended cements or pozzolans depend on the composition of the pozzolan, the age of the concrete, the extent of reaction of the pozzolan and the fact that this test method may determine only the portland-cement component of a blended cement. The test method should be applied to determination of the blended cement content or the pozzolanic content only by use of calibration concrete samples or other information. Earlier versions of this test method can provide useful information as detailed by Hime6 and Minnick.7
SCOPE
1.1 This test method covers the determination of portland-cement content of a sample of hardened hydraulic-cement concrete.
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are provided for information purposes only.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Disposal of some or all of the chemicals used in this method may require adherence to EPA or other regulatory guidelines.

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Publication Date
09-Jan-2002
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ASTM C1084-02 - Standard Test Method for Portland-Cement Content of Hardened Hydraulic-Cement Concrete
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information.
Designation:C1084–02
Standard Test Method for
Portland-Cement Content of Hardened Hydraulic-Cement
1
Concrete
This standard is issued under the fixed designation C1084; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 3. Significance and Use
1.1 This test method covers the determination of portland- 3.1 This test method consists of two independent proce-
cement content of a sample of hardened hydraulic-cement dures: an oxide-analysis procedure that consists of two sub-
concrete. procedures and an extraction procedure. Each procedure re-
1.2 The values stated in SI units are to be regarded as the quires a substantial degree of chemical skill and relatively
standard. The values given in parentheses are provided for elaboratechemicalinstrumentation.Exceptfortheinfluenceof
information purposes only. knowninterferences,determinedcementcontentsarenormally
1.3 This standard does not purport to address all of the equal to, or slightly greater than, actual values except for the
safety concerns, if any, associated with its use. It is the Maleic Acid procedure where results can also be significantly
responsibility of the user of this standard to establish appro- low when the paste is carbonated (Note 1).
priate safety and health practices and determine the applica-
NOTE 1—With certain limitations, the procedure is also applicable for
bility of regulatory limitations prior to use.Disposalofsomeor
estimating the combined content of portland cement and pozzolan or slag
allofthechemicalsusedinthismethodmayrequireadherence
in concretes made with blended hydraulic cement and blends of portland
to EPA or other regulatory guidelines.
cement with pozzolans or slags. The results of this test method when
applied to concretes made with blended cements or pozzolans depend on
2. Referenced Documents
the composition of the pozzolan, the age of the concrete, the extent of
2
reaction of the pozzolan and the fact that this test method may determine
2.1 ASTM Standards:
only the portland-cement component of a blended cement. The test
C42/C42M Test Method for Obtaining and Testing Drilled
method should be applied to determination of the blended cement content
Cores and Sawed Beams of Concrete
or the pozzolanic content only by use of calibration concrete samples or
C114 Test Methods for Chemical Analysis of Hydraulic
other information. Earlier versions of this test method can provide useful
3 4
Cement
information as detailed by Hime and Minnick.
C670 Practice for Preparing Precision and Bias Statements
4. Interferences
for Test Methods for Construction Materials
C702 Practice for Reducing Samples of Aggregate to Test- 4.1 Many constituents of concrete may interfere with the
analysis of the concrete for portland-cement content. The
ing Size
C823 Practice for Examination and Sampling of Hardened following limited lists of materials have been provided as a
guide. The rocks, minerals or mineral admixtures listed will
Concrete in Constructions
C856 Practice for Petrographic Examination of Hardened interferewiththecementcontentdeterminationtotheextentof
their solubility during the dissolution procedure used. The
Concrete
D1193 Specification for Reagent Water solubilityofrocks,mineralsormineraladmixturesmaydepend
onthefinenessofthetestsample,thewater-cementratioofthe
E11 SpecificationforWovenWireTestSieveClothandTest
Sieves concrete, the extent of hydration, and the age of the concrete
(extended exposure to the high pH of the concrete may affect
E832 Specification for Laboratory Filter Papers
the solubility of some minerals).
4.2 Substances Affecting Calcium Oxide Sub-procedure:
1
This method is under the jurisdiction of ASTM Committee C09 on Concrete
andConcreteAggregatesandisthedirectresponsibilityofSubcommitteeC09.69on
3
Miscellaneous Tests. Hime, W. G., “Cement Content,” Significance of Tests and Properties of
Current edition approved Jan. 10, 2002. Published March 1997. Originally Concrete and Concrete-Making Materials, ASTM STP 169B, ASTM, 1978, pp.
published as C1084–87. Last previous edition C1084–97. DOI: 10.1520/C1084- 462–470, and “Analyses for Cement and Other Materials in Hardened Concrete,”
02. Chapter 29, Significant of Tests and Properties of Concrete and Concrete-Making
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or Materials, ASTM STP 169C, 1994, pp. 315–319.
4
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Minnick, L. J., “Cement-Content, Hardened Concrete,” Significance of Tests
Standards volume information, refer to the standard’s Document Summary page on and Propert
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