iTeh StandardsiTeh Standards
EURUSD
Your shopping cart is empty.
ASTM

ASTM E698-05

(Test Method)

Standard Test Method for Arrhenius Kinetic Constants for Thermally Unstable Materials

Standard Test Method for Arrhenius Kinetic Constants for Thermally Unstable Materials

SIGNIFICANCE AND USE
The Arrhenius parameters combined with the general rate law and the reaction enthalpy can be used for the determination of thermal explosion hazards (1).3
SCOPE
1.1 This method covers the determination of the overall kinetic parameters for exothermic reactions using the Flynn/Wall/Ozawa method and differential scanning calorimetry.
1.2 This technique is applicable to reactions whose behavior can be described by the Arrhenius equation and the general rate law.
1.3 LimitationsThere are cases where this technique is not applicable. Limitations may be indicated by curves departing from a straight line (see ) or the isothermal aging test not closely agreeing with the results predicted by the calculated kinetic values. In particular, this method is not applicable to reactions that are partially inhibited. The technique may not work with reactions that include simultaneous or consecutive reaction steps. This method may not apply to materials that undergo phase transitions if the reaction rate is significant at the transition temperature.
1.4 SI units are the standard.
This standard may involve hazardous materials, operations, and equipment. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
28-Feb-2005
ICS
19.040 - Environmental testing
Technical Committee
E27 - Hazard Potential of Chemicals
Drafting Committee
E27.02 - Thermal Stability and Condensed Phases
Current Stage
Ref Project

Relations

Replaces
ASTM E698-04 - Standard Test Method for Arrhenius Kinetic Constants for Thermally Unstable Materials
Effective Date
01-Mar-2005
Replaced By
ASTM E698-11 - Standard Test Method for Arrhenius Kinetic Constants for Thermally Unstable Materials Using Differential Scanning Calorimetry and the Flynn/Wall/Ozawa Method
Effective Date
01-Mar-2011
Referred By
ASTM E2254-23 - Standard Test Method for Storage Modulus Calibration of Dynamic Mechanical Analyzers
Effective Date
01-Mar-2005
Referred By
ASTM E1231-19 - Standard Practice for Calculation of Hazard Potential Figures of Merit for Thermally Unstable Materials
Effective Date
01-Mar-2005
Referred By
ASTM E2781-16 - Standard Practice for Evaluation of Methods for Determination of Kinetic Parameters by Calorimetry and Differential Scanning Calorimetry
Effective Date
01-Mar-2005
Referred By
ASTM E2070-13(2018) - Standard Test Methods for Kinetic Parameters by Differential Scanning Calorimetry Using Isothermal Methods
Effective Date
01-Mar-2005
Referred By
ASTM E1445-08(2015) - Standard Terminology Relating to Hazard Potential of Chemicals
Effective Date
01-Mar-2005
Referred By
ASTM E3174-22 - Standard Practice for Determination of Kinetic Reaction Model Using Differential Scanning Calorimetry
Effective Date
01-Mar-2005
Referred By
ASTM E2012-06(2020) - Standard Guide for the Preparation of a Binary Chemical Compatibility Chart
Effective Date
01-Mar-2005
Referred By
ASTM E1232-07(2019) - Standard Test Method for Temperature Limit of Flammability of Chemicals
Effective Date
01-Mar-2005
Referred By
ASTM E3142-18a(2023) - Standard Test Method for Thermal Lag of Thermal Analysis Apparatus
Effective Date
01-Mar-2005
Referred By
ASTM E2041-23 - Standard Test Method for Estimating Kinetic Parameters by Differential Scanning Calorimeter Using the Borchardt and Daniels Method
Effective Date
01-Mar-2005
Referred By
ASTM E2890-21 - Standard Test Method for Determination of Kinetic Parameters and Reaction Order for Thermally Unstable Materials by Differential Scanning Calorimetry Using the Kissinger and Farjas Methods
Effective Date
01-Mar-2005
Referred By
ASTM E1981-22 - Standard Guide for Assessing Thermal Stability of Materials by Methods of Accelerating Rate Calorimetry
Effective Date
01-Mar-2005

Buy Standard

ASTM E698-05 - Standard Test Method for Arrhenius Kinetic Constants for Thermally Unstable MaterialsASTM E698-05 - Standard Test Method for Arrhenius Kinetic Constants for Thermally Unstable Materials
PreviousNext
Standard
ASTM E698-05 - Standard Test Method for Arrhenius Kinetic Constants for Thermally Unstable Materials
English language
8 pages
sale 15% off
Preview
sale 15% off
Preview

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:E698–05
Standard Test Method for
Arrhenius Kinetic Constants for Thermally Unstable
Materials Using Differential Scanning Calorimetry and the
1
Flynn/Wall/Ozawa Method
This standard is issued under the fixed designation E698; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
INTRODUCTION
The kinetics of exothermic reactions are important in assessing the potential of materials and
systems for thermal explosion. This test method provides a means for determining Arrhenius
activationenergiesandpre-exponentialfactorsusingdifferentialthermalmethods.Thistestmethodis
one of several test methods being developed byASTM Committee E27 for chemical reactions. This
test method is to be used in conjunction with other tests to characterize the hazard potential of
chemicals.
1. Scope 2. Referenced Documents
2
1.1 This test method covers the determination of the overall 2.1 ASTM Standards:
kinetic parameters for exothermic reactions using the Flynn/ E473 Terminology Relating to Thermal Analysis and Rhe-
Wall/Ozawa method and differential scanning calorimetry. ology
1.2 Thistechniqueisapplicabletoreactionswhosebehavior E691 Practice for Conducting an Interlaboratory Study to
canbedescribedbytheArrheniusequationandthegeneralrate Determine the Precision of a Test Method
law. E968 Practice for Heat Flow Calibration of Differential
1.3 Limitations—Therearecaseswherethistechniqueisnot Scanning Calorimeters
applicable. Limitations may be indicated by curves departing E1142 Terminology Relating to Thermophysical Properties
from a straight line (see 11.2) or the isothermal aging test not E1445 TerminologyRelatingtoHazardPotentialofChemi-
closely agreeing with the results predicted by the calculated cals
kinetic values. In particular, this test method is not applicable E1860 Test Method for Elapsed Time Calibration of Ther-
to reactions that are partially inhibited. The technique may not mal Analyzers
work with reactions that include simultaneous or consecutive E1970 Practice for Statistical Treatment of Thermoanalyti-
reactionsteps.Thistestmethodmaynotapplytomaterialsthat cal Data
undergo phase transitions if the reaction rate is significant at
3. Terminology
the transition temperature.
3.1 Technical terms used in this test method are defined in
1.4 SI units are the standard.
1.5 This standard may involve hazardous materials, opera- Terminologies E473, E1142, and E1445.
tions, and equipment. This standard does not purport to
4. Summary of Test Method
address all of the safety concerns, if any, associated with its
4.1 Asampleisplacedinasuitablecontainerandpositioned
use. It is the responsibility of the user of this standard to
in a differential scanning calorimeter (DSC).
establish appropriate safety and health practices and deter-
4.2 The sample equipment temperature is increased at a
mine the applicability of regulatory limitations prior to use.
linear rate and any exothermic reaction peaks recorded.
1
This test method is under the jurisdiction ofASTM Committee E27 on Hazard
Potential of Chemicals and is the direct responsibility of Subcommittee E27.02 on
2
Thermal Stability and Condensed Phases. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved March 1, 2005. Published April 2005. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 1979. Last previous edition approved in 2004 as E698–01. DOI: Standards volume information, refer to the standard’s Document Summary page on
the ASTM website.
10.1520/E0698-05.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
E698–05
4.3 Steps 4.1 and 4.2 are repeated for several heating rates 6.3 Containers (pans, crucibles, vials, etc), which are inert
-1
in the range from 1 to 10 K min . to the specimen and reference materials and which are suitable
4.4 Temperatures at which the reaction peak maxima occur structural shape and integrity to contain the specimen and
are plotted as a function of their respective heating rates. reference in accordance with the specific requirements of this
4.5 Kinetic values calculated from the peak temperature- test method.
heating rate relationship are used to predict a reaction half-life 6.4 A balance, with a capacity of at least 100 mg, to weigh
at a selected temperature. specimens and/or containers (pans, crucibles, vials, etc) to
4.6 A sample is aged at the selected temperature for the within 10 µg.
predicted half-life time. 6.5 Auxilia
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.

This May Also Interest You

ASTM
ASTM D6660-01(2023)(Test Method)
Standard Test Method for Freezing Point of Aqueous Ethylene Glycol Base Engine Coolants by Automatic Phase Transition Method

SIGNIFICANCE AND USE
5.1 The freezing point of an engine coolant indicates the coolant freeze protection.  
5.2 The freezing point of an engine coolant may be used to determine the approximate glycol content, provided the glycol type is known.  
5.3 Freezing point as measured by Test Method D1177 or approved alternative method is a requirement in Specifications D3306 and D6210.  
5.4 This test method provides results that are equivalent to Test Method D1177 and expresses results to the nearest 0.1 °C with improved reproducibility over Test Method D1177.  
5.5 This test method determines the freezing point in a shorter period of time than Test Method D1177.  
5.6 This test method removes most of the operator time and judgement required by Test Method D1177.
SCOPE
1.1 This test method covers the determination of the freezing point of an aqueous engine coolant solution.  
1.2 This test method is designed to cover ethylene glycol base coolants up to a maximum concentration of 60 % (v/v) in water; however, the ASTM interlaboratory study mentioned in 12.2 has only demonstrated the test method with samples having a concentration range of 40 % to 60 % (v/v) water.
Note 1: Where solutions of specific concentrations are to be tested, they shall be prepared from representative samples as directed in Practice D1176. Secondary phases separating on dilution need not be separated.
Note 2: The products may also be marketed in a ready-to-use form (prediluted).  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Some specific hazards statements are given in 7.3.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    5 pages
    English language
    sale 15% off
ASTM
ASTM E698-23(Test Method)
Standard Test Method for Kinetic Parameters for Thermally Unstable Materials Using Differential Scanning Calorimetry and the Flynn/Wall/Ozawa Method

SIGNIFICANCE AND USE
5.1 The kinetic parameters combined with the general rate law and the reaction enthalpy can be used for the determination of thermal hazard using Practice E1231  (1).4
SCOPE
1.1 This test method covers the determination of the overall kinetic parameters for exothermic reactions using the Flynn/Wall/Ozawa method and differential scanning calorimetry.  
1.2 This technique is applicable to reactions whose behavior can be described by the Arrhenius equation and the general rate law.  
1.3 Limitations—There are cases where this technique is not applicable. Limitations may be indicated by curves departing from a straight line (see 11.2) or the isothermal aging test not closely agreeing with the results predicted by the calculated kinetic values. In particular, this test method is not applicable to reactions that are partially inhibited. The technique may not work with reactions that include simultaneous or consecutive reaction steps. This test method may not apply to materials that undergo phase transitions if the reaction rate is significant at the transition temperature.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    9 pages
    English language
    sale 15% off
  • Standard
    9 pages
    English language
    sale 15% off
ASTM
ASTM G90-23(Practice)
Standard Practice for Performing Accelerated Outdoor Weathering of Materials Using Concentrated Natural Sunlight

SIGNIFICANCE AND USE
4.1 Results obtained from this practice can be used to compare the relative durability of materials subjected to the specific test cycle used. No accelerated test can be specified as a perfect simulation of natural or field exposures. Results obtained from this practice can be considered as representative of natural weathering only when a sufficient magnitude of mathematical correlation exists between exposures.  
4.2 The acceleration factor relating the rate of degradation in this accelerated exposure to the rate of degradation in a natural weathering exposure varies with the type and formulation of the material. Each material and formulation may respond differently to the increased level of irradiance and differences in temperature and humidity. Thus an acceleration factor determined for one material may not be applicable to other materials. For this reason, the use of a single acceleration factor is not recommended. Also, a different acceleration factor may be obtained by using different mirror types and configurations. Because of variability in test results for both accelerated and natural weathering exposures, results from a sufficient number of tests must be obtained to determine an acceleration factor for a material. Further, the acceleration factor is applicable to only one exposure location because results from natural weathering will vary due to seasonal or annual differences in climatic factors.  
4.3 The relative durability of materials determined by this practice can be used to determine the relative durability of the materials exposed under natural weathering conditions provided the materials have similar acceleration factors. However, even if results from a specific accelerated test condition are found to be useful for comparing the durability of materials exposed in a particular exterior location, it cannot be assumed that they will be useful for determining the relative durability for a different location. The relative durability of materials in n...
SCOPE
1.1 Linear Fresnel reflector concentrators using the sun as source are utilized in the accelerated outdoor exposure testing of materials.  
1.2 This practice covers a procedure for performing accelerated outdoor exposure testing of materials using a linear Fresnel reflector, accelerated outdoor weathering, test machine. The apparatus (see Fig. 1 and Fig. 2) and guidelines are described herein to minimize the variables encountered during outdoor accelerated exposure testing.    
1.3 This practice does not specify the exposure conditions best suited for the materials to be tested but is limited to the method of obtaining, measuring, and controlling the procedures and certain conditions of the exposure. Sample preparation, test conditions, and evaluation of results are covered in existing methods or specifications for specific materials.  
1.4 The linear Fresnel reflector accelerated outdoor exposure test apparatus described may be suitable for the determination of the relative durability of materials when these materials are exposed to concentrated sunlight, heat, and moisture.  
1.5 This practice establishes uniform sample mounting and in-test maintenance procedures. Also included in the practice are standard provisions for maintenance of the machine and linear Fresnel reflector mirrors to ensure cleanliness and durability.  
1.6 This practice shall apply to specimens whose size meets the dimensions of the target board as described in 8.2.  
1.7 For test machines currently in use, this practice is not recommended for specimens exceeding 13 mm (1/2 in.) in thickness because of specimen cooling.  
1.8 Values stated in SI units are to be regarded as the standard. The inch-pound units in parentheses are provided for information only.  
1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate...

  • Standard
    14 pages
    English language
    sale 15% off
  • Standard
    14 pages
    English language
    sale 15% off
ASTM
ASTM E324-23(Test Method)
Standard Test Method for Relative Initial and Final Melting Points and the Melting Range of Organic Chemicals

SIGNIFICANCE AND USE
5.1 It has long been recognized that narrow melting range and high final melting point are good indications of high purity in crystalline organic compounds. Several ASTM test methods use these criteria to assay the purity of organic compounds (Note 1).
Note 1: Other ASTM test methods using melting (or freezing point) data to indicate sample purity are Test Methods D852 and D6875.  
5.2 The relatively simple and rapid test prescribed in this test method shows the sample under test to be either more or less pure than the standard sample. For specification purposes, a minimum allowable purity can be assured by setting limits on the differences in final melting points and the melting ranges between the standard sample and the sample under test.
SCOPE
1.1 This test method covers the determination, by a capillary tube method, of the initial melting point and the final melting point, which define the melting range, of samples of organic chemicals whose melting points without decomposition fall between 30 °C and 250 °C.  
1.2 This test method is applicable only to crystalline materials that are sufficiently stable in storage to met the requirements of a satisfactory standard sample as defined in Section 7.  
1.3 This test method is not directly applicable to opaque materials or to noncrystalline materials such as waxes, fats, and fatty acids.  
1.4 Review the current Safety Data Sheets (SDS) for detailed information concerning toxicity, first aid procedures, handling, and safety precautions.  
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    4 pages
    English language
    sale 15% off
  • Standard
    4 pages
    English language
    sale 15% off
ASTM
ASTM G63-15(2023)(Guide)
Standard Guide for Evaluating Nonmetallic Materials for Oxygen Service

SIGNIFICANCE AND USE
4.1 The purpose of this guide is to furnish qualified technical personnel with pertinent information for use in selecting materials for oxygen service in order to minimize the probability of ignition and the risk of explosion or fire. It is not intended as a specification for approving materials for oxygen service.
SCOPE
1.1 This guide applies to nonmetallic materials, (hereinafter called materials) under consideration for oxygen or oxygen-enriched fluid service, direct or indirect, as defined below. It is intended for use in selecting materials for applications in connection with the production, storage, transportation, distribution, or use of oxygen. It is concerned primarily with the properties of a material associated with its relative susceptibility to ignition and propagation of combustion; it does not involve mechanical properties, potential toxicity, outgassing, reactions between various materials in the system, functional reliability, or performance characteristics such as physical aging, degradation, abrasion, hardening, or embrittlement, except when these might contribute to an ignition.  
1.2 When this document was originally published in 1980, it addressed both metals and nonmetals. Its scope has been narrowed to address only nonmetals and a separate standard Guide G94 has been developed to address metals.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: The American Society for Testing and Materials takes no position respecting the validity of any evaluation methods asserted in connection with any item mentioned in this guide. Users of this guide are expressly advised that determination of the validity of any such evaluation methods and data and the risk of use of such evaluation methods and data are entirely their own responsibility.
Note 2: In evaluating materials, any mixture with oxygen exceeding atmospheric concentration at pressures higher than atmospheric should be evaluated from the hazard point of view for possible significant increase in material combustibility.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Guide
    27 pages
    English language
    sale 15% off
ASTM
ASTM G128/G128M-15(2023)(Guide)
Standard Guide for Control of Hazards and Risks in Oxygen Enriched Systems

SIGNIFICANCE AND USE
4.1 The purpose of this guide is to introduce the hazards and risks associated with oxygen-enriched systems. This guide explains common hazards that often are overlooked. It provides an overview of the standards and documents produced by ASTM Committee G04 and other knowledgable sources as well as their uses. It does not highlight standard test methods that support the use of these practices. Table 1 provides a graphic representation of the relationship of ASTM G04 standards. Table 2 provides a list of standards published by ASTM and other organizations.  
4.2 The standards discussed here focus on reducing the hazards associated with the use of oxygen. In general, they are not directly applicable to process reactors in which the deliberate reaction of materials with oxygen is sought, as in burners, bleachers, or bubblers. Other ASTM Committees and products (such as the CHETAH program5) and other outside groups are more pertinent for these.  
4.3 This guide is not intended as a specification to establish practices for the safe use of oxygen. The documents discussed here do not purport to contain all the information needed to design and operate an oxygen-enriched system safely. The control of oxygen hazards has not been reduced to handbook procedures, and the tactics for using oxygen are not simple. Rather, they require the application of sound technical judgment and experience. Oxygen users should obtain assistance from qualified technical personnel to design systems and operating practices for the safe use of oxygen in their specific applications.
SCOPE
1.1 This guide covers an overview of the work of ASTM Committee G04 on Compatibility and Sensitivity of Materials in Oxygen-Enriched Atmospheres. It is a starting point for those asking the question: “What are the risks associated with my use of oxygen?” This guide is an introduction to the unique concerns that must be addressed in the handling of oxygen. The principal hazard is the prospect of ignition with resultant fire, explosion, or both. All fluid systems require design considerations, such as adequate strength, corrosion resistance, fatigue resistance, and pressure safety relief. In addition to these design considerations, one must also consider the ignition mechanisms that are specific to an oxygen-enriched system. This guide outlines these ignition mechanisms and the approach to reducing the risks.  
1.2 This guide also lists several of the recognized causes of oxygen system fires and describes the methods available to prevent them. Sources of information about the oxygen hazard and its control are listed and summarized. The principal focus is on Guides G63, G88, Practice G93, and Guide G94. Useful documentation from other resources and literature is also cited.  
Note 1: This guide is an outgrowth of an earlier (1988) Committee G04 videotape adjunct entitled Oxygen Safety and a related paper by Koch2 that focused on the recognized ignition source of adiabatic compression as one of the more significant but often overlooked causes of oxygen fires. This guide recapitulates and updates material in the videotape and paper.  
1.3 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements see Sections 8 and 11.  
Note 2: ASTM takes no position respecting the validity of any evaluation methods asserted in connection with any ite...

  • Guide
    16 pages
    English language
    sale 15% off
ASTM
ASTM G154-23(Practice)
Standard Practice for Operating Fluorescent Ultraviolet (UV) Lamp Apparatus for Exposure of Materials

SIGNIFICANCE AND USE
5.1 The use of this apparatus is intended to induce property changes consistent with the end use conditions, including the effects of the UV portion of sunlight, moisture, and heat. Typically, these exposures would include moisture in the form of condensing humidity. Exposures are not intended to simulate the deterioration caused by localized weather phenomena, such as atmospheric pollution, biological attack, and saltwater exposure. Alternatively, the exposure may simulate the effects of sunlight through window glass. (Warning—Refer to Practice G151 for full cautionary guidance applicable to all laboratory weathering devices.)  
5.2 This practice provides general procedures for operating fluorescent UV lamp weathering devices that allow for a wide range of exposure conditions. Therefore, no reference shall be made to results from the use of this practice unless accompanied by a report detailing the specific operating conditions in conformance with Section 10.  
5.2.1 It is recommended that a similar material of known performance (a control) be exposed simultaneously with the test specimen to provide a standard for comparative purposes. Generally, two controls are recommended: one known to have poor durability and one known to have good durability. It is recommended that at least three replicates of each material evaluated be exposed in each test to allow for statistical evaluation of results.  
5.2.2 Comparison of results obtained from specimens exposed in the same model of apparatus should not be made unless reproducibility has been established among devices for the material to be tested.  
5.2.3 Comparison of results obtained from specimens exposed in different models of apparatus should not be made unless correlation has been established among devices for the material to be tested (see Guide D6631 for guidance).
SCOPE
1.1 This practice is limited to the basic principles for operating a fluorescent UV lamp and water apparatus; on its own, it does not deliver a specific result.  
1.2 It is intended to be used in conjunction with a practice or method that defines specific exposure conditions for an application along with a means to evaluate changes in material properties. This practice is intended to reproduce the weathering effects that occur when materials are exposed to sunlight (either direct or through window glass) and moisture as rain or dew in actual usage. This practice is limited to the procedures for obtaining, measuring, and controlling conditions of exposure.
Note 1: Practice G151 describes general procedures to be used when exposing nonmetallic materials in accelerated test devices that use laboratory light sources.
Note 2: A number of exposure procedures are listed in an appendix; however, this practice does not specify the exposure conditions best suited for the material to be tested.  
1.3 Test specimens are exposed to fluorescent UV light under controlled environmental conditions. Different types of fluorescent UV lamp sources are described.
Note 3: In this standard, the terms UV light and UV radiation are used interchangeably.  
1.4 Specimen preparation and evaluation of the results are covered in ASTM methods or specifications for specific materials. General guidance is given in Practice G151 and ISO 4892-1.
Note 4: General information about methods for determining the change in properties after exposure and reporting these results is described in ISO 4582 and Practice D5870.  
1.5 This practice is not intended for corrosion testing of bare metals.  
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.7 This standard is technically similar to ISO 4892-3 and ISO 16474-3.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and...

  • Standard
    12 pages
    English language
    sale 15% off
  • Standard
    12 pages
    English language
    sale 15% off
ASTM
ASTM D6677-18(2022)(Test Method)
Standard Test Method for Evaluating Adhesion by Knife

SIGNIFICANCE AND USE
4.1 Coatings, to perform satisfactorily, must adhere to the substrates on which they are applied. This test method has been found useful as a simple means of assessing the adhesion of coatings. Although this method is a qualitative (subjective) test it has been used in industry for many years and can provide valuable information.  
4.2 Other adhesion test methods may be useful in obtaining quantitative results. See Test Methods D2197, D3359, D4541, and D7234.  
4.3 The Performance Evaluation Scale (see Table 1) is based on both the degree of difficulty to remove the coating from the substrate and the size of removed coating chip.  
4.4 This test method does not have a known correlation to other adhesion test methods (pull-off, tape, etc.).  
4.5 A coating that has a high degree of cohesive strength may appear to have worse adhesion than one that is brittle and hence fractures easily when probed.  
4.6 This method is not to be used on overly thick coatings, that is, those which cannot be cut to the substrate with a utility knife in one stroke.
SCOPE
1.1 This test method covers the procedure for assessing the adhesion of coating films to substrate by using a knife.  
1.2 This test method is used to establish whether the adhesion of a coating to a substrate or to another coating (in multi-coat systems) is at a generally adequate level.
Note 1: The term “substrate” relates to the basic surface on which a coating adheres (may be steel, concrete, etc. or other coating).  
1.3 This method can be used in the laboratory and field.  
1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off
ASTM
ASTM F2111-22(Practice)
Standard Practice for Measuring Intergranular Attack or End Grain Pitting on Metals Caused by Aircraft Chemical Processes

SIGNIFICANCE AND USE
4.1 If not properly qualified, chemicals and chemical processes can attack metals used during aircraft maintenance and production. It is important to qualify only processes and chemical formulas that do not have any deleterious effects on aircraft metallic skins, fittings, components, and structures. This test procedure is used to detect and measure intergranular attack or pitting depth caused by aircraft maintenance chemical processes, hence, this test procedure is useful in selecting a process that will not cause intergranular attack or end grain pitting on aircraft alloys.  
4.2 The purpose of this practice is to aid in the qualification or process conformance testing or production of maintenance chemicals for use on aircraft.  
4.2.1 Actual aircraft processes in the production environment shall give the most representative results; however, the test results cannot be completely evaluated with respect to ambient conditions which normally vary from day to day. Additionally, when testing chemicals requiring dilutions, water quality and composition can play a role in the corrosion rates and mechanism affecting the results.  
4.2.2 Some examples of maintenance and production chemicals include: organic solvents, paint strippers, cleaners, deoxidizers, water-based or semi-aqueous cleaners, or etching solutions and chemical milling solutions.
SCOPE
1.1 This practice covers the procedures for testing and measuring intergranular attack (IGA) and end grain pitting on aircraft metals and alloys caused by maintenance or production chemicals.  
1.2 The standard does not purport to address all qualification testing parameters, methods, critical testing, or criteria for aircraft production or maintenance chemical qualifications. Specific requirements and acceptance testing along with associated acceptance criteria shall be found where applicable in procurement specifications, materials specifications, appropriate process specifications, or previously agreed upon specifications.  
1.3 Units—The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    3 pages
    English language
    sale 15% off
  • Standard
    3 pages
    English language
    sale 15% off
ASTM
ASTM D7560-22(Test Method)
Standard Test Method for Determination of Fiber Length Percentages in Hydraulic Erosion Control Products (HECPs)

SIGNIFICANCE AND USE
5.1 The fiber length of an HECP plays a role in the ability of the HECP to effectively be mixed and applied. This standard can be used by manufacturers to evaluate their manufacturing process (quality assurance/quality control). Laboratories can also use this method for quality assurance/quality control and also conformance to criteria testing.
Note 1: The quality of the result produced by these test methods is dependent on the competence of the personnel performing it, and the suitability of the equipment and facilities used. Agencies that meet the criteria of Practice D3740 are generally considered capable of competent and objective testing/sampling/inspection/etc. Users of these test methods are cautioned that compliance with Practice D3740 does not in itself assure reliable results. Reliable results depend on many factors; Practice D3740 provides a means of evaluating some of those factors.
SCOPE
1.1 Hydraulic erosion control product (HECP) fibers are manufactured and processed to specific length and width dimensions to facilitate the hydraulic application and to prevent clogging of the pump, recirculation pipes, nozzles, and tips. This test method is used to determine the length of the fibers on a percentage basis in an HECP.  
1.2 This test method can be used to evaluate an HECP during and after manufacturing. The results can be used for comparative evaluations of the manufacturing process.  
1.3 Units—The values stated in SI units are to be regarded as the standard. No other units of measurement are included in this standard. Sieve designations are shown in both the standard and alternative designations.  
1.4 All observed and calculated values shall conform to the guidelines for significant digits and rounding established in Practice D6026.  
1.4.1 The procedures used to specify how data are collected/recorded or calculated in the standard are regarded as the industry standard. In addition, they are representative of the significant digits that generally should be retained. The procedures used do not consider material variation, purpose for obtaining the data, special purpose studies, or any considerations for the user’s objectives; and it is common practice to increase or reduce significant digits of reported data to be commensurate with these considerations. It is beyond the scope of this standard to consider significant digits used in analysis methods for engineering design.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    3 pages
    English language
    sale 15% off
  • Standard
    3 pages
    English language
    sale 15% off