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ASTM D5517-00

(Test Method)

Standard Test Method for Determining Extractability of Metals from Art Materials

Standard Test Method for Determining Extractability of Metals from Art Materials

SCOPE
1.1 This test method covers the extraction of metals from art materials using an extractant that simulates the acid potential of gastric juice. This test method is similar to the extraction method noted in Specification F963 but involves conducting extraction steps at body temperature instead of at room temperature. The extraction procedure specified in this test method is more rigorous than that noted in Specification F963.
1.2 This test method is adapted from the European Toy Safety Standard, EN 71-3:1988.
1.3 This test method differs from EN 71-3:1988 in that a solvent extraction step is not required for processing waxes or oil-based products. The rationale for this test method is discussed in Appendix X1.
1.4 This test method does not specify any specific acceptable metal level.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
09-Nov-2000
ICS
97.195 - Items of art and handicrafts. Cultural property and heritage
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.57 - Artist Paints and Related Materials
Current Stage
Ref Project

Relations

Replaces
ASTM D5517-96 - Standard Test Method for Determining Extractability of Metals from Art Materials
Effective Date
10-Nov-2000
Replaced By
ASTM D5517-03 - Standard Test Method for Determining Extractability of Metals from Art Materials
Effective Date
10-Jan-2003

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ASTM D5517-00 - Standard Test Method for Determining Extractability of Metals from Art Materials
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Standards Content (Sample)

NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 5517 – 00
Standard Test Method for
1
Determining Extractability of Metals from Art Materials
This standard is issued under the fixed designation D 5517; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope Content—Flame Atomic Absorption Spectrometric
Method and Dithiazone Spectrophotometric Method
1.1 This test method covers the extraction of metals from art
Part 2: Determination of Antimony Content—Flame Atomic
materials using an extractant that simulates the acid potential of
Absorption Spectrophotometric Method and Rhodamine
gastric juice. This test method is similar to the extraction
B Spectrophotometric Method
method noted in Specification F 963 but involves conducting
Part 3: Determination of Barium Content—Flame Atomic
extraction steps at body temperature instead of at room
Emission Spectrometric Method
temperature. The extraction procedure specified in this test
Part 4: Determination of Cadmium Content—Flame Atomic
method is more rigorous than that noted in Specification F 963.
Absorption Spectrometric Method and Polarographic
1.2 This test method is adapted from the European Toy
Method
Safety Standard, EN 71-3:1988.
Part 5: Determination of Hexavalent Chromium Content of
1.3 This test method differs from EN 71-3:1988 in that a
the Pigment Portion of the Liquid Paint or the Paint in
solvent extraction step is not required for processing waxes or
Powder Form—Diphenylcarbazide Spectrophotometric
oil-based products. The rationale for this test method is
Method
discussed in Appendix X1.
Part 6: Determination of Total Chromium Content of the
1.4 This test method does not specify any specific accept-
Liquid Portion of Paint—Flame Atomic Absorption Spec-
able metal level.
trometric Method
1.5 This standard does not purport to address all of the
7
2.3 USEPA Standards:
safety concerns, if any, associated with its use. It is the
USEPA Test Method SW-846
responsibility of the user of this standard to establish appro-
6010 Test Method for antimony, arsenic, barium, beryllium,
priate safety and health practices and determine the applica-
cadmium, chromium, cobalt, copper, lead, manganese,
bility of regulatory limitations prior to use.
molybdenum, nickel, selenium, silver, thallium, vana-
2. Referenced Documents
dium, and zinc
6020 Test Method for aluminum, antimony, arsenic, barium,
2.1 ASTM Standards:
beryllium, cadmium, chromium, cobalt, copper, lead,
D 4236 Practice for Labeling Art Materials for Chronic
2
manganese, nickel, silver, thallium, and zinc
Health Hazards
7040 Test Method for antimony
E 180 Practice for Determining the Precision of ASTM
3
7041 Test Method for antimony
Methods for Analysis and Testing of Industrial Chemicals
4
7060 Test Method for arsenic
E 456 Terminology Relating to Quality and Statistics
5
7061 Test Method for arsenic
F 963 Consumer Safety Specification on Toy Safety
6
7080 Test Method for barium
2.2 International Standards:
7090 Test Method for beryllium
EN 71-3:1988 Safety of Toys
7091 Test Method for beryllium
ISO 3696 Water for Laboratory Use—Specifications
7130 Test Method for cadmium
ISO 3856 Paints and Varnishes—Determination of
7131 Test Method for cadmium
“Soluble” Metal Content Part 1: Determination of Lead
7190 Test Method for chromium
7191 Test Method for chromium
1
This test method is under the jurisdiction of ASTM Committee D01 on Paint 7200 Test Method for cobalt
and Related Coatings, Materials, and Applications and is the direct responsibility of
7201 Test Method for cobalt
Subcommittee D01.57 on Artist Paints and Related Materials.
7210 Test Method for copper
Current edition approved Nov. 10, 2000. Published January 2001. Originally
7420 Test Method for lead
published as D 5517 – 94. Last previous edition D 5517 – 96.
2
Annual Book of ASTM Standards, Vol 06.02.
7421 Test Method for lead
3
Annual Book of ASTM Standards, Vol 15.05.
4
Annual Book of ASTM Standards, Vol 14.02.
5
Annual Book of ASTM Standards, Vol 15.07.
6 7
Available from the Comite European de Normalisation, Central Secretariat, Available from USEPA, Environmental Protection Agency, Alexander Drive,
Rue Brederode 2, B–100 Brussels. Research Triangle Park, NC 27709.
Copyright © ASTM, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D 5517
7460 Test Method for manganese 6. Apparatus
7470 Test Method for mercury
6.1 Metal Sieve
...

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4.1 This specification establishes quality requirements and provides a basis for common understanding among producers, distributors, and users.  
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SCOPE
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1.2 This specification includes requirements for identification and lightfastness.  
1.3 Pastel specimens are exposed to both natural daylight through window glass and window glass-filtered simulated daylight radiation to determine the lightfastness category for each pastel.  
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ABSTRACT
This practice describes a procedure for developing precautionary labels for ceramic art materials and provides hazard and precautionary statements concerning chronic adverse health hazards known to be associated with a product or product component(s), when the component(s) is present in a physical form, volume, or concentration that in the opinion of a toxicologist has the potential to produce a chronic adverse health effect(s). Precautionary labels covered by this practice are intended for adult usage and does not assure completely the safe use of an art product. This practice does not specify test methods for determining whether a substance or product presents chronic adverse health hazards and does not apply to products appropriately labeled for known chronic adverse health hazards according to chemical substances labeling standards and practices, such as another national consensus standard, existing labeling statutes, regulations, or guidelines. Requirements for the conformance to this practice are given. Determination of labeling and labeling practices such as, signal word, list of potential chronic hazards, name of chronic hazard components, safe handling, instructions, list of sensitizing components, combined statements, information sources, and supplement information are detailed.
SCOPE
1.1 This practice describes a procedure for developing precautionary labels for ceramic art materials and provides hazard and precautionary statements based upon knowledge that exists in the scientific and medical communities. This practice concerns those chronic adverse health hazards known to be associated with a product or product component(s), when the component(s) is present in a physical form, volume, or concentration that in the opinion of a toxicologist has the potential to produce a chronic adverse health effect(s).  
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1.5 This practice does not apply to products appropriately labeled for known chronic adverse health hazards according to chemical substances labeling standards and practices, such as another national consensus standard, existing labeling statutes, regulations, or guidelines.  
1.6 Since knowledge about chronic adverse health hazards is incomplete and warning cannot cover all uses of any product, it is not possible for precautionary labeling to assure completely safe use of an art product.  
1.7 Manufacturers or repackagers may wish to determine individually or collectively precautionary labeling for ceramic art materials in accordance with this practice. Compliance may be certified by a certifying organization. Guidelines for a certifying organization are given in Appendix X1.  
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ASTM D5724-16(2021)(Specification)
Standard Specification for Gouache Paints

ABSTRACT
This specification establishes the requirements for composition, physical properties, performance, and labeling of gouache paints. Covered here are pigments, vehicles, and additives, wherein the requirements for which are included for pigment identification, lightfastness, and consistency. Some pigments meeting the lightfastness requirements in this specification are listed herein. Also, in order to identify other pigments that meet these requirements, instructions are given for test specimen preparation and the respective test methods for determining relative lightfastness. The conditions not covered in this specification that affect gouache paints are substrate, environmental conditions, storage, vehicles, pigments, additives, inerts, preparation of samples, coarse particles, fineness of dispersions, consistency, freeze-thaw stability, opacity (hiding power), bleeding, and color specification.
SIGNIFICANCE AND USE
4.1 This specification establishes quality requirements and provides a basis for common understanding among producers, distributors, and users.  
4.2 It is not intended that all paints meeting the requirements be identical nor of uniform excellence in all respects. Variations in manufacture, not covered by this specification, may cause some artists to prefer one brand over another, either of which may be acceptable under this specification.
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1.1 This specification establishes requirements for composition, physical properties, performance, and labeling of gouache paints.  
1.2 This specification covers pigments, vehicles, and additives. Requirements are included for pigment identification, lightfastness, and consistency.  
1.3 Table 1 lists some pigments meeting the lightfastness requirements in this specification. In order to identify other pigments that meet these requirements, instructions are given for test specimen preparation. Test methods for determining relative lightfastness are referenced.  
1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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