Textiles and textile products - Determination of dimethylformamide (DMF), method using gas chromatography

This document specifies a method to determine the amounts of extractable dimethylformamide (DMF) in components of textile products containing polyurethane or acrylic.
NOTE   Further information can be found in CEN/TR 16741:2015, Tables 1 and 3 that define which materials are applicable to this determination.

Textilien und textile Erzeugnisse - Bestimmung von Dimethylformamid (DMF), Verfahren mittels Gaschromatographie

Dieses Dokument legt ein Verfahren zur quantitativen Bestimmung von extrahierbarem Dimethylformamid (DMF) in Bestandteilen textiler Erzeugnisse fest, die Polyurethan oder Acryl enthalten.
ANMERKUNG Weitere Informationen können CEN/TR 16741:2015, Tabelle 1 und Tabelle 3 entnommen werden, in denen festgelegt ist, welche Werkstoffe für diese Bestimmung anwendbar sind.

Textiles et produits textiles - Détermination du diméthylformamide (DMF), méthode par chromatographie en phase gazeuse

Le présent document spécifie une méthode permettant de déterminer la quantité de diméthylformamide (DMF) extractible dans les composants de produits textiles contenant du polyuréthane ou de l’acrylique.
NOTE Pour plus d’informations, se reporter au CEN/TR 16741:2015, Tableaux 1 et 3, qui définit à quels matériaux s’applique cette détermination.

Tekstilije in tekstilni izdelki - Določevanje dimetilformamida (DMF), metoda z uporabo plinske kromatografije

Ta dokument določa metodo za določanje količine dimetilformamida (DMF) v sestavnih delih tekstilnih izdelkov, ki vsebujejo poliuretan ali akril.
OPOMBA: Dodatne informacije so na voljo v tabeli 1 standarda CEN/TR 16741:2015, ki določa, katere materiale zadeva ta določitev.

General Information

Status
Published
Publication Date
09-Jul-2019
Current Stage
6060 - Definitive text made available (DAV) - Publishing
Due Date
10-Jul-2019
Completion Date
10-Jul-2019

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SLOVENSKI STANDARD
SIST EN 17131:2019
01-september-2019
Tekstilije in tekstilni izdelki - Določevanje dimetilformamida (DMF), metoda z
uporabo plinske kromatografije

Textiles and textile products - Determination of dimethylformamide (DMF), method using

gas chromatography

Textilien und textile Erzeugnisse - Bestimmung von Dimethylformamid (DMF), Verfahren

mittels Gaschromatographie

Textiles et produits textiles - Détermination du diméthylformamide (DMF), méthode par

chromatographie en phase gazeuse
Ta slovenski standard je istoveten z: EN 17131:2019
ICS:
59.080.01 Tekstilije na splošno Textiles in general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN 17131:2019 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN 17131:2019
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SIST EN 17131:2019
EN 17131
EUROPEAN STANDARD
NORME EUROPÉENNE
July 2019
EUROPÄISCHE NORM
ICS 59.080.01
English Version
Textiles and textile products - Determination of
dimethylformamide (DMF), method using gas
chromatography

Textiles et produits textiles - Détermination du Textilien und textile Erzeugnisse - Kritische Stoffe, die

diméthylformamide (DMF), méthode par in Bestandteilen von Materialien textiler Erzeugnisse

chromatographie en phase gazeuse vorhanden sein können - Bestimmung von
Dimethlyformamid (DMF), gaschromatographisches
Verfahren
This European Standard was approved by CEN on 26 May 2019.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this

European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references

concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN

member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by

translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management

Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,

Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and

United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17131:2019 E

worldwide for CEN national Members.
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SIST EN 17131:2019
EN 17131:2019 (E)
Contents Page

European foreword ....................................................................................................................................................... 3

Introduction .................................................................................................................................................................... 4

1 Scope .................................................................................................................................................................... 5

2 Normative references .................................................................................................................................... 5

3 Terms and definitions ................................................................................................................................... 5

4 Principle of method ........................................................................................................................................ 5

5 Reagents ............................................................................................................................................................. 5

6 Equipment ......................................................................................................................................................... 6

7 Sampling ............................................................................................................................................................. 6

8 Procedure........................................................................................................................................................... 7

9 Expression of results ...................................................................................................................................... 7

10 Test report ......................................................................................................................................................... 7

Annex A (informative) Suggested parameters for GC-MS determination of DMF —

Measuring method .......................................................................................................................................... 8

A.1 Measuring parameter .................................................................................................................................... 8

A.2 Chromatographic conditions ...................................................................................................................... 8

A.3 Detection conditions ...................................................................................................................................... 8

Table A.1 — Quantifier ions ....................................................................................................................................... 8

Bibliography .................................................................................................................................................................... 9

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SIST EN 17131:2019
EN 17131:2019 (E)
European foreword

This document (EN 17131:2019) has been prepared by Technical Committee CEN/TC 248 “Textiles and

textile products”, the secretariat of which is held by BSI.

This European Standard shall be given the status of a national standard, either by publication of an

identical text or by endorsement, at the latest by January 2020, and conflicting national standards shall

be withdrawn at the latest by January 2020.

Attention is drawn to the possibility that some of the elements of this document may be the subject of

patent rights. CEN shall not be held responsible for identifying any or all such patent rights.

This document is adapted from CEN ISO/TS 16189, it was prepared by Technical Committee

CEN/TC 309 “Footwear”, in collaboration with Technical Committee ISO/TC 216 “Footwear”, in

accordance with the agreement on technical cooperation between ISO and CEN (Vienna Agreement).

The adaptation is based on the extension of the scope to textile products.

According to the CEN-CENELEC Internal Regulations, the national standards organisations of the

following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,

Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,

Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of

North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the

United Kingdom.
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SIST EN 17131:2019
EN 17131:2019 (E)
Introduction

In Europe according to Regulation (EU) 2018/1513 amending Annex XVII to Regulation (EC) No

1907/2006 (REACH) by Entry 72, (a) clothing or related accessories; (b) textiles other than clothing

which, under normal or reasonably foreseeable conditions of use, come into contact with human skin to

an extent similar to clothing; (c) footwear are not to be placed on the market after 1 November 2020, if

they contain more than 3 000 mg/kg of dimethylformamide (DMF).

This restriction does not apply to: (a) clothing, related accessories or footwear, or parts of clothing,

related accessories or footwear, made exclusively of natural leather, fur or hide; (b) non-textile

fasteners and non-textile decorative attachments; (c) second-hand clothing, related accessories, textiles

other than clothing or footwear; (d) wall-to-wall carpets and textile floor coverings for indoor use, ru

...

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