EN ISO 16558-1:2015

Soil quality - Risk-based petroleum hydrocarbons - Part 1: Determination of aliphatic and aromatic fractions of volatile petroleum hydrocarbons using gas chromatography (static headspace method) (ISO 16558-1:2015)

ISO 16558-1:2015 specifies a method for the quantitative determination of the total extractable volatile, the volatile aliphatic, and aromatic fractions of petroleum hydrocarbon content in field moist soil samples by gas chromatography with mass spectrometric detection. The aromatic fractions are determined by the sum of individual aromatic compounds.
The sum of the volatile aliphatic (C5 to C10) and aromatic (C6 to C10) fractions can be referred to as "volatile oil".
The results of the test carried out can be used for risk assessment studies related to contaminations with petroleum hydrocarbons.
ISO 16558-1:2015 provides a method applicable to petroleum hydrocarbon contents from about 5 mg/kg soil expressed as dry matter for the whole aliphatic fraction C5 to C10 and about 5 mg/kg soil expressed as dry matter for the aromatic fraction in the boiling range of C6 to C10.
With this method, all hydrocarbons with a boiling range of 36 °C to 184 °C, n-alkanes between C5H12 to C10H22, isoalkanes, cycloalkanes, BTEX, and di- and tri-alkyl benzenes compounds are determined as total volatile petroleum hydrocarbons C5 to C10. In addition, volatile aliphatic and aromatic fractions are specified.
For the determination of semi-volatile aliphatic and aromatic fractions of petroleum hydrocarbons in soil samples, see ISO/TS 16558-2.
NOTE          The sub-fractions proposed in this part of ISO 16558 have shown to be suitable for risk assessment studies. However, other sub-fractions between C5H12 to C10H22 can be determined in conformity with this part of ISO 16558.
On the basis of the peak pattern of the gas chromatogram and of the boiling points of the individual n-alkanes listed in Annex A, the approximate boiling range of the mineral oil and some qualitative information on the composition of the contamination can be achieved.

Bodenbeschaffenheit - Mineralölkohlenwasserstoffe für die Risikobeurteilung - Teil 1: Bestimmung aliphatischer und aromatischer Fraktionen leicht flüchtiger Mineralölkohlenwasserstoffe mittels Gaschromatographie (statisches Headspace-Verfahren) (ISO 16558-1:2015)

Dieser Teil von ISO 16558 legt ein Verfahren zur quantitative Bestimmung der gesamten extrahierbaren flüchtigen Bestandteile, der leicht flüchtigen aliphatischen und aromatischen Fraktionen des Mineralölkohlen-wasserstoff-Gehalts in feldfrischen Bodenproben mittels Gaschromatographie mit massen¬spektrometrischem Nachweis (GC MS, en: gas chromatography with mass spectrometric detection) fest. Die aromatischen Fraktionen werden durch die Summe der einzelnen aromatischen Verbindungen bestimmt.
Die Ergebnisse der durchgeführten Prüfung können für Studien zur Risikobeurteilung hinsichtlich der Kontaminationen mit Mineralölkohlenwasserstoffen angewendet werden.
Das Verfahren ist für Mineralölkohlenwasserstoff-Gehalte zwischen XXXX mg/kg und XXXX mg/kg Boden, angegeben als Trockensubstanz für die gesamte aliphatische Fraktion C5 bis C10 sowie für die aromatischen Verbindungen im Siedebereich von C6 bis C10 geeignet. Bei Teilfraktionen können niedrigere Bestimmungsgrenzen erreicht werden.
Mit diesem Verfahren werden alle Kohlenwasserstoffe mit einem Siedebereich von 36 °C bis 175 °C, n Alkane zwischen C5H12 und C10H22, Isoalkane, Cycloalkane, BTEX, Di- und Trialkylbenzol-Verbindungen als leicht flüchtige Gesamt-Mineralölkohlenwasserstoffe C5 bis C10 bestimmt. Zusätzlich werden die leicht flüchtigen aliphatischen und aromatischen Fraktionen festgelegt.
Hinsichtlich der Bestimmung von schwerflüchtigen aliphatischen und aromatischen Fraktionen von Mineralölkohlenwasserstoffen in Bodenproben siehe Teil 2 dieser Internationalen Norm.
ANMERKUNG   Die in diesem Teil der ISO 16558 vorgeschlagenen Teilfraktionen haben gezeigt, dass sie für Studien zur Risikobeurteilung geeignet sind. Jedoch können weitere Teilfraktionen zwischen C5H12 und C10H22 in Übereinstimmung mit dieser Internationalen Norm bestimmt werden.
Auf der Grundlage der Peakfolge des Gaschromatogramms und der Siedepunkte der einzelnen im Anhang A angeführten n Alkane können der näherungsweise Siedebereich des Mineralöls und einige qualitative Hinweise zur Zusammensetzung der Kontamination erhalten werden.

Qualité du sol - Hydrocarbures de pétrole à risque - Partie 1: Détermination des fractions aliphatiques et aromatiques des hydrocarbures de pétrole volatils par chromatographie en phase gazeuse (méthode par espace de tête statique) (ISO 16558-1:2015)

ISO 16558-1:2015 spécifie une méthode de dosage quantitatif des fractions aliphatiques et aromatiques volatiles extractibles totales des hydrocarbures de pétrole dans des échantillons humides par chromatographie en phase gazeuse avec détection spectrométrique de masse. Les fractions aromatiques sont dosées par l'ensemble des composés aromatiques individuels.
L'ensemble des fractions aliphatiques (C5 à C10) et aromatiques (C6 to C10) volatiles peut être désigné par l'expression «huile volatile».
Les résultats de l'essai effectué peuvent être utilisés pour les études d'évaluation des risques liées aux contaminations par les hydrocarbures de pétrole.
ISO 16558-1:2015 propose une méthode applicable aux teneurs en hydrocarbures de pétrole d'environ 5 mg/kg de sol, exprimées sous forme de matière sèche pour la fraction aliphatique totale C5 à C10 et d'environ 5 mg/kg de sol, exprimées sous forme de matière sèche pour la fraction aromatique dans le domaine d'ébullition de C6 à C10.
Grace à cette méthode, tous les hydrocarbures ayant une température d'ébullition comprise entre 36 °C et 184 °C, les n-alcanes de C5H12 à C10H22, les isoalcanes, les cycloalcanes, les BTEX et les composés de di- et trialkylbenzène sont dosés sous forme d'hydrocarbures de pétrole volatils totaux C5 à C10. De plus, les fractions aliphatiques et aromatiques volatiles sont spécifiées.
Pour le dosage des fractions aliphatiques et aromatiques semi-volatiles des hydrocarbures de pétrole dans les échantillons de sol, voir l'ISO/TS 16558-2.
NOTE          Les sous-fractions proposées dans la présente partie de l'ISO 16558 se sont révélées adaptées aux études d'évaluation des risques. Cependant, d'autres sous-fractions entre C5H12 et C10H22 peuvent être dosées conformément à la présente partie de l'ISO 16558.
Compte tenu de la forme des pics du chromatogramme en phase gazeuse et du point d'ébullition des différents alcanes indiqués à l'Annexe A, il est possible de déterminer le domaine d'ébullition approximatif des huiles minérales et de recueillir quelques informations qualitatives sur la composition des polluants.

Kakovost tal - Naftni ogljikovodiki, ki predstavljajo tveganje - 1. del: Določevanje alifatskih in aromatskih frakcij hlapnih naftnih ogljikovodikov s plinsko kromatografijo (metoda s statičnim vzorčevalnikom iz plinske faze - headspace) (ISO 16558-1:2015)

Ta del standarda ISO 16558-1 določa metodo za količinsko določevanje skupnih hlapnih snovi, ki jih je mogoče ekstrahirati, hlapnih alifatskih in aromatskih frakcij naftnih ogljikovodikov na terenskih vzorcih vlažnih tal s plinsko kromatografijo. Rezultate izvedenega preskusa je mogoče uporabiti za študije ocene tveganja v zvezi z onesnaženjem z naftnimi ogljikovodiki. Metoda se lahko uporablja za vsebnost naftnih ogljikovodikov med XXXX mg/kg in XXXX mg/kg tal, izraženo kot suha snov, za celotno alifatsko frakcijo C5 do C10 in aromatske spojine v območju vrelišča C6 do C10. Za podfrakcije je mogoče doseči nižje mejne vrednosti določevanja. S to metodo so vsi ogljikovodiki z območjem vrelišča 36 °C do 175 °C, n-alkani med C5H12 in C10H22, izoalkani, cikloalkani, BTEX, dialkil in trialkil benzenske spojine določeni kot skupni hlapni naftni ogljikovodiki C5 do C10; poleg tega se določijo hlapne alifatske in aromatske frakcije. Za podfrakcije, predlagane v tem delu standarda ISO xxxxx, se je izkazalo, da so primerne za študije ocene tveganja. Druge podfrakcije med C5H12 in C10H22 pa je mogoče določiti v skladu s tem standardom.

General Information

• Status: Published
• Publication Date: 08-Sep-2015
• Withdrawal Date: 30-Mar-2016
• ICS: 13.080.10 - Chemical characteristics of soils
• Technical Committee: CEN/TC 444 - Environmental characterization
• Drafting Committee: CEN/TC 444/WG 2 - Organic analysis
• Current Stage: 6060 - Definitive text made available (DAV) - Publishing
• Start Date: 09-Sep-2015
• Completion Date: 09-Sep-2015
• Ref Project: SIST EN ISO 16558-1:2015 - Soil quality - Risk based petroleum hydrocarbons - Part 1: Determination of aliphatic and aromatic fractions of volatile petroleum hydrocarbons using gas chromatography (static headspace method) (ISO 16558-1:2015)

Relations

• Amended By: EN ISO 16558-1:2015/A1:2020 - Soil quality - Risk-based petroleum hydrocarbons - Part 1: Determination of aliphatic and aromatic fractions of volatile petroleum hydrocarbons using gas chromatography (static headspace method) - Amendment 1 (ISO 16558-1:2015/Amd 1:2020)
• Effective Date: 06-Dec-2017

Standards Content (Sample)

SLOVENSKI STANDARD
01-november-2015
.DNRYRVWWDO1DIWQLRJOMLNRYRGLNLNLSUHGVWDYOMDMRWYHJDQMHGHO'RORþHYDQMH
DOLIDWVNLKLQDURPDWVNLKIUDNFLMKODSQLKQDIWQLKRJOMLNRYRGLNRYVSOLQVNR
NURPDWRJUDILMRPHWRGDVVWDWLþQLPY]RUþHYDOQLNRPL]SOLQVNHID]HKHDGVSDFH
,62
Soil quality - Risk based petroleum hydrocarbons - Part 1: Determination of aliphatic and
aromatic fractions of volatile petroleum hydrocarbons using gas chromatography (static
headspace method) (ISO 16558-1:2015)
Bodenbeschaffenheit - Mineralölkohlenwasserstoffe für die Risikobeurteilung - Teil 1:
Bestimmung aliphatischer und aromatischer Fraktionen leicht flüchtiger
Mineralölkohlenwasserstoffe mittels Gaschromatographie (statisches Headspace-
Verfahren) (ISO 16558-1:2015)
Qualité du sol - Hydrocarbures de pétrole à risque - Partie 1: Détermination des fractions
aliphatiques et aromatiques des hydrocarbures de pétrole volatiles par chromatographie
en phase gazeuse (méthode par espace de tête statique) (ISO 16558-1:2015)
Ta slovenski standard je istoveten z: EN ISO 16558-1:2015
ICS:
13.080.10 .HPLMVNH]QDþLOQRVWLWDO Chemical characteristics of
soils
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 16558-1
EUROPEAN STANDARD
NORME EUROPÉENNE
September 2015
EUROPÄISCHE NORM
ICS 13.080.10
English Version
Soil quality - Risk-based petroleum hydrocarbons - Part 1:
Determination of aliphatic and aromatic fractions of
volatile petroleum hydrocarbons using gas
chromatography (static headspace method) (ISO 16558-
1:2015)
Qualité du sol - Hydrocarbures de pétrole à risque - Bodenbeschaffenheit - Mineralölkohlenwasserstoffe
Partie 1: Détermination des fractions aliphatiques et für die Risikobeurteilung - Teil 1: Bestimmung
aromatiques des hydrocarbures de pétrole volatiles aliphatischer und aromatischer Fraktionen leicht
par chromatographie en phase gazeuse (méthode par flüchtiger Mineralölkohlenwasserstoffe mittels
espace de tête statique) (ISO 16558-1:2015) Gaschromatographie (statisches Headspace-Verfahren)
(ISO 16558-1:2015)
This European Standard was approved by CEN on 13 June 2015.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2015 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 16558-1:2015 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 16558-1:2015) has been prepared by Technical Committee ISO/TC 190 “Soil
quality” in collaboration with Technical Committee CEN/TC 345 “Characterization of soils” the
secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by March 2016, and conflicting national standards shall
be withdrawn at the latest by March 2016.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent
rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Endorsement notice
The text of ISO 16558-1:2015 has been approved by CEN as EN ISO 16558-1:2015 without any
modification.
INTERNATIONAL ISO
STANDARD 16558-1
First edition
2015-08-15
Soil quality — Risk-based petroleum
hydrocarbons —
Part 1:
Determination of aliphatic and
aromatic fractions of volatile
petroleum hydrocarbons using gas
chromatography (static headspace
method)
Qualité du sol — Hydrocarbures de pétrole à risque —
Partie 1: Détermination des fractions aliphatiques et aromatiques
des hydrocarbures de pétrole volatiles par chromatographie en phase
gazeuse (méthode par espace de tête statique)
Reference number
ISO 16558-1:2015(E)
©
ISO 2015
ISO 16558-1:2015(E)
© ISO 2015, Published in Switzerland
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
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ii © ISO 2015 – All rights reserved

ISO 16558-1:2015(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 2
4 Interferences . 3
5 Principle . 3
6 Reagents . 3
7 Apparatus . 7
8 Sampling, preservation, and sample pretreatment . 8
8.1 General . 8
8.2 Sampling using vials pre-filled with methanol . 8
8.3 Sampling using coring tube method . 9
9 Procedure. 9
9.1 Blank determination . 9
9.2 Extraction . 9
9.3 Headspace-analysis . 9
9.4 Gas chromatographic analysis .10
9.4.1 General.10
9.4.2 Calibration .10
9.4.3 Measurement .12
10 Calculation .12
10.1 Calculation of the concentration in the spiked water sample .12
10.1.1 Volatile aromatic hydrocarbon compounds with internal standard method .12
10.1.2 Volatile aliphatic fractions .12
10.2 Calculation of the concentration of a volatile compound or fraction in the soil sample .13
10.3 Calculation of the concentration of volatile oil in the soil sample .13
11 Expression of results .13
12 Precision .13
13 Test report .13
Annex A (informative) Examples of GC-MS chromatograms of fuels .14
Bibliography .16
ISO 16558-1:2015(E)
Foreword
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bodies (ISO member bodies). The work of preparing International Standards is normally carried out
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The procedures used to develop this document and those intended for its further maintenance are
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Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of
...