Vitreous and porcelain enamels - Determination of resistance to chemical corrosion - Part 4: Determination of resistance to chemical corrosion by alkaline liquids using a cylindrical vessel (ISO 28706-4:2008)

ISO 28706-4:2008 describes a test method for the determination of the resistance of vitreous and porcelain enamelled articles to attack by alkaline liquids at temperatures between 25 °C and 95 °C. The apparatus used is a cylindrical vessel in which only one enamelled specimen is tested.

Emails und Emaillierungen - Bestimmung der Beständigkeit gegen chemische Korrosion - Teil 4: Bestimmung der Beständigkeit gegen chemische Korrosion durch alkalische Flüssigkeiten unter Verwendung eines Gerätes mit zylindrischem Gefäß (ISO 28706-4:2008)

Dieser Teil von ISO 28706 legt ein Prüfverfahren zur Bestimmung der Beständigkeit von emaillierten Gegenständen
gegen den Angriff alkalischer Flüssigkeiten bei Temperaturen zwischen 25 °C und 95 °C fest. Das
verwendete Gerät besteht aus einem zylindrischen Gefäß, in dem nur eine emaillierte Probe geprüft wird.
ANMERKUNG 1 Das Prüfverfahren wurde ursprünglich zur Bestimmung der Beständigkeit von Emails gegen eine
heiße Natronlauge entwickelt. Innerhalb des Anwendungsbereiches dieses Teils von ISO 28706 kann die Beständigkeit
gegen weitere alkalische Flüssigkeiten geprüft werden.
ANMERKUNG 2 Dieser Teil von ISO 28706, in dem ein zylindrisches Gefäß eingesetzt wird, wird im Allgemeinen bei
Prüfungen angewendet, die an Email-Überzügen für die chemische Industrie durchgeführt werden.

Émaux vitrifiés - Détermination de la résistance à la corrosion chimique - Partie 4: Détermination de la résistance à la corrosion chimique par des liquides alcalins dans un récipient cylindrique (ISO 28706-4:2008)

L'ISO 28706-4:2008 spécifie une méthode d'essai permettant de déterminer la résistance d'articles en émail vitrifié à l'attaque par des liquides alcalins à des températures comprises entre 25 °C et 95 °C. L'appareillage utilisé est un récipient cylindrique dans lequel une seule éprouvette émaillée est soumise à essai.

Steklasti in porcelanski emajli - Ugotavljanje odpornosti proti kemični koroziji - 4. del: Ugotavljanje odpornosti proti kemični koroziji z alkalnimi tekočinami in valjasto posodo (ISO 28706-4:2008)

Ta del ISO 28706 opisuje preskusno metodo za ugotavljanje odpornosti steklastih in porcelanskih emajliranih predmetov proti napadu z alkalnimi tekočinami pri temperaturah med 25 °C in 95 °C. Uporabljeni aparat je valjasta posoda, v kateri se preskuša samo en emajliran vzorec.

General Information

Status
Withdrawn
Publication Date
17-May-2011
Withdrawal Date
26-Jan-2016
Current Stage
9960 - Withdrawal effective - Withdrawal
Completion Date
27-Jan-2016

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SLOVENSKI STANDARD
01-januar-2012
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GHO8JRWDYOMDQMHRGSRUQRVWLSURWLNHPLþQLNRUR]LML]DONDOQLPLWHNRþLQDPLLQ
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Vitreous and porcelain enamels - Determination of resistance to chemical corrosion -
Part 4: Determination of resistance to chemical corrosion by alkaline liquids using a
cylindrical vessel (ISO 28706-4:2008)
Emails und Emaillierungen - Bestimmung der Beständigkeit gegen chemische Korrosion
- Teil 4: Bestimmung der Beständigkeit gegen chemische Korrosion durch alkalische
Flüssigkeiten unter Verwendung eines Gerätes mit zylindrischem Gefäß (ISO 28706-
4:2008)
Émaux vitrifiés - Détermination de la résistance à la corrosion chimique - Partie 4:
Détermination de la résistance à la corrosion chimique par des liquides alcalins dans un
récipient cylindrique (ISO 28706-4:2008)
Ta slovenski standard je istoveten z: EN ISO 28706-4:2011
ICS:
25.220.50 Emajlne prevleke Enamels
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
EN ISO 28706-4
NORME EUROPÉENNE
EUROPÄISCHE NORM
May 2011
ICS 25.220.50 Supersedes EN 14483-4:2004
English Version
Vitreous and porcelain enamels - Determination of resistance to
chemical corrosion - Part 4: Determination of resistance to
chemical corrosion by alkaline liquids using a cylindrical vessel
(ISO 28706-4:2008)
Émaux vitrifiés - Détermination de la résistance à la Emails und Emaillierungen - Bestimmung der Beständigkeit
corrosion chimique - Partie 4: Détermination de la gegen chemische Korrosion - Teil 4: Bestimmung der
résistance à la corrosion chimique par des liquides alcalins Beständigkeit gegen chemische Korrosion durch alkalische
dans un récipient cylindrique (ISO 28706-4:2008) Flüssigkeiten unter Verwendung eines Gerätes mit
zylindrischem Gefäß (ISO 28706-4:2008)
This European Standard was approved by CEN on 15 April 2011.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same
status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2011 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 28706-4:2011: E
worldwide for CEN national Members.

Contents Page
Foreword .3

Foreword
The text of ISO 28706-4:2008 has been prepared by Technical Committee ISO/TC 107 “Metallic and other
inorganic coatings” of the International Organization for Standardization (ISO) and has been taken over as EN
ISO 28706-4:2011 by Technical Committee CEN/TC 262 “Metallic and other inorganic coatings” the
secretariat of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by November 2011, and conflicting national standards shall be withdrawn
at the latest by November 2011.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN 14483-4:2004.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech
Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia,
Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain,
Sweden, Switzerland and the United Kingdom.
Endorsement notice
The text of ISO 28706-4:2008 has been approved by CEN as a EN ISO 28706-4:2011 without any
modification.
INTERNATIONAL ISO
STANDARD 28706-4
First edition
2008-12-01
Vitreous and porcelain enamels —
Determination of resistance to chemical
corrosion —
Part 4:
Determination of resistance to chemical
corrosion by alkaline liquids using a
cylindrical vessel
Émaux vitrifiés — Détermination de la résistance à la corrosion
chimique —
Partie 4: Détermination de la résistance à la corrosion chimique par des
liquides alcalins dans un récipient cylindrique

Reference number
ISO 28706-4:2008(E)
©
ISO 2008
ISO 28706-4:2008(E)
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ii © ISO 2008 – All rights reserved

ISO 28706-4:2008(E)
Contents Page
Foreword. iv
Introduction . v
1 Scope. 1
2 Normative references. 1
3 Principle. 1
4 Reagents. 2
5 Apparatus and material. 2
6 Test specimens. 7
7 Procedure. 7
8 Expression of results. 8
8.1 Total loss in mass per unit area . 8
8.2 Corrosion rate . 8
9 Hot sodium hydroxide test . 9
9.1 General. 9
9.2 Test solution, c(NaOH) = 0,1 mol/l. 9
9.3 Test temperature. 9
9.4 Duration of the test. 9
9.5 Test report. 9
10 Other test solutions. 10
10.1 General. 10
10.2 Test solution. 10
10.3 Test temperature. 10
10.4 Duration of the test. 10
10.5 Test report. 10
Bibliography . 11

ISO 28706-4:2008(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 28706-4 was prepared by the European Committee for Standardization (CEN) (as EN 14483-4) and was
adopted, under a special “fast-track procedure”, by Technical Committee ISO/TC 107, Metallic and other
inorganic coatings, in parallel with its approval by the ISO member bodies.
It cancels and replaces ISO 2734:1997 and ISO 2745:1998, which have been technically revised.
ISO 28706 consists of the following parts, under the general title Vitreous and porcelain enamels —
Determination of resistance to chemical corrosion:
⎯ Part 1: Determination of resistance to chemical corrosion by acids at room temperature
⎯ Part 2: Determination of resistance to chemical corrosion by boiling acids, boiling neutral liquids and/or
their vapours
⎯ Part 3: Determination of resistance to chemical corrosion by alkaline liquids using a hexagonal vessel
⎯ Part 4: Determination of resistance to chemical corrosion by alkaline liquids using a cylindrical vessel
⎯ Part 5: Determination of resistance to chemical corrosion in closed systems
iv © ISO 2008 – All rights reserved

ISO 28706-4:2008(E)
Introduction
Corrosion of vitreous and porcelain enamels by aqueous solutions is a dissolution process. The main
component of the enamel, SiO , forms a three-dimensional silica network. After hydrolysis, it decomposes and
forms silicic acid or silicates. These are released into the attacking medium. Other components, mainly metal
oxides, are hydrolysed as well and form the corresponding hydrated metal ions or hydroxides. All corrosion
products are more or less soluble in the attacking medium. The whole process results in a loss in mass per
unit ar
...

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