prEN ISO 13144
(Main)Textiles - Determination of quinoline, isoquinoline and certain derivatives (ISO/DIS 13144:2025)
Textiles - Determination of quinoline, isoquinoline and certain derivatives (ISO/DIS 13144:2025)
This document specifies a method for the qualification and quantification of certain quinoline derivatives in textile products by means of extraction with methanol and gas chromatography with mass selective detector or liquid chromatography with mass selective detector. The method is applicable to all kinds of textile products consisting of natural or artificially dyed textile fibres and fabrics.
It is further applicable to dyestuff powder used as textile auxiliary for dyeing and printing.
Textilien - Bestimmung von Chinolin, Isochinolin und bestimmten Derivaten (ISO/DIS 13144:2025)
Textiles - Détermination de la quinoléine, de l’isoquinoléine et de certains dérivés (ISO/DIS 13144:2025)
Tekstilije - Ugotavljanje kvinolina, izokvinolina in nekaterih derivatov (ISO/DIS 13144:2025)
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
01-april-2025
Tekstilije - Ugotavljanje kvinolina, izokvinolina in nekaterih derivatov (ISO/DIS
13144:2025)
Textiles - Determination of quinoline, isoquinoline and certain derivatives (ISO/DIS
13144:2025)
Textilien - Bestimmung von Chinolin, Isochinolin und bestimmten Derivaten (ISO/DIS
13144:2025)
Textiles - Détermination de la quinoléine, de l’isoquinoléine et de certains dérivés
(ISO/DIS 13144:2025)
Ta slovenski standard je istoveten z: prEN ISO 13144
ICS:
59.080.01 Tekstilije na splošno Textiles in general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
DRAFT
International
Standard
ISO/DIS 13144
ISO/TC 38
Textiles — Determination of
Secretariat: JISC
quinoline, isoquinoline and certain
Voting begins on:
derivatives
2025-02-12
Textiles — Dosage de quinoléine, d'isoquinoléine et de certains
Voting terminates on:
dérivés
2025-05-07
ICS: 59.080.01
THIS DOCUMENT IS A DRAFT CIRCULATED
FOR COMMENTS AND APPROVAL. IT
IS THEREFORE SUBJECT TO CHANGE
AND MAY NOT BE REFERRED TO AS AN
INTERNATIONAL STANDARD UNTIL
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This document is circulated as received from the committee secretariat.
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NATIONAL REGULATIONS.
RECIPIENTS OF THIS DRAFT ARE INVITED
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NOTIFICATION OF ANY RELEVANT PATENT
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PROVIDE SUPPORTING DOCUMENTATION.
Reference number
ISO/DIS 13144:2025(en)
DRAFT
ISO/DIS 13144:2025(en)
International
Standard
ISO/DIS 13144
ISO/TC 38
Textiles — Determination of
Secretariat: JISC
quinoline, isoquinoline and certain
Voting begins on:
derivatives
Textiles — Dosage de quinoléine, d'isoquinoléine et de certains
Voting terminates on:
dérivés
ICS: 59.080.01
THIS DOCUMENT IS A DRAFT CIRCULATED
FOR COMMENTS AND APPROVAL. IT
IS THEREFORE SUBJECT TO CHANGE
AND MAY NOT BE REFERRED TO AS AN
INTERNATIONAL STANDARD UNTIL
PUBLISHED AS SUCH.
This document is circulated as received from the committee secretariat.
IN ADDITION TO THEIR EVALUATION AS
BEING ACCEPTABLE FOR INDUSTRIAL,
© ISO 2025
TECHNOLOGICAL, COMMERCIAL AND
USER PURPOSES, DRAFT INTERNATIONAL
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
STANDARDS MAY ON OCCASION HAVE TO
ISO/CEN PARALLEL PROCESSING
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
BE CONSIDERED IN THE LIGHT OF THEIR
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NATIONAL REGULATIONS.
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TO SUBMIT, WITH THEIR COMMENTS,
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NOTIFICATION OF ANY RELEVANT PATENT
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Published in Switzerland Reference number
ISO/DIS 13144:2025(en)
ii
ISO/DIS 13144:2025(en)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 2
6 Apparatus . 2
7 Preparation of test specimens . 3
7.1 Fibre and fabric test specimens.3
7.2 Dyestuff test specimens .3
8 Procedure . 3
8.1 Preparation of standard solutions .3
8.1.1 Preparation of stock standard solutions .3
8.1.2 Preparation of calibration solutions .3
8.2 Extraction procedure .4
8.2.1 Extraction procedure for textile specimens .4
8.2.2 Extraction procedure for dyestuff specimens .4
8.3 Sample analysis . .4
9 Expression of results . 4
9.1 Calibration curve .4
9.2 Calculation of quinoline derivatives .4
9.3 Reliability of the test method .5
9.4 Limit of quantification of the test method .5
10 Test report . 5
Annex A (informative) Examples of chromatographic method – GC-MS and GC-MS/MS . 6
Annex B (informative) Examples of chromatographic method – LC-MS .10
Annex C (informative) Reliability of the method . 14
iii
ISO/DIS 13144:2025(en)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out through
ISO technical committees. Each member body interested in a subject for which a technical committee
has been established has the right to be represented on that committee. International organizations,
governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely
with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are described
in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types
of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the
ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent
rights identified during the development of the document will be in the Introduction and/or on the ISO list of
patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment,
as well as information about ISO's adherence to the World Trade Organization (WTO) principles in the
Technical Barriers to Trade (TBT) see the following URL: www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 38, Textiles.
A list of all parts in the ISO series can be found on the ISO website.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.
iv
ISO/DIS 13144:2025(en)
Introduction
Quinoline, which is used in certain dyes, is classified as a carcinogenic substance. It has a high solubility in
water and this tendency makes it of concern in manufacturing processes where the dyed textiles are washed.
It can also be found as residue in textiles and textile products where it can easily come into skin contact. A
series of studies have shown the potential harm to humans as well as downstream aquatic life. Quinoline is
thus restricted in the European Union in (a) clothing or related accessories; (b) textiles other than clothing
which, under normal or reasonably foreseeable conditions of use, come into contact with human skin to an
extent similar to clothing; (c) footwear [1].
Quinoline derivatives are compounds that can be synthesized from a quinoline compound by replacement
of one atom with another atom or group of atoms. Considering their toxicity on several animal species, it is
important to set up an effective and precise test method to determine the content of them.
The test method described in this document is based on the use of gas chromatography with mass
spectrometry (GC-MS) or liquid chromatography with mass spectrometry (LC-MS).
v
DRAFT International Standard ISO/DIS 13144:2025(en)
Textiles — Determination of quinoline, isoquinoline and
certain derivatives
1 Scope
WARNING — The use of this document involves hazardous substances, operations and equipment.
It does not purport to address all of the safety or environmental problems associated with its use.
It refers only to technical suitability and does not absolve the user from legal obligations relating to
health and safety/environment at any stage.
This document specifies a method for the qualification and quantification of certain quinoline derivatives
in textile products by means of extraction with methanol and gas chromatography with mass selective
detector or liquid chromatography with mass selective detector. The method is applicable to all kinds of
textile products consisting of natural or artificially dyed textile fibres and fabrics.
It is further applicable to dyestuff powder used as textile auxiliary for dyeing and printing.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content constitutes
requirements of this document. For dated references, only the edition cited applies. For undated references,
the latest edition of the referenced document (including any amendments) applies.
ISO 3696, Water for analytical laboratory use — Specification and test methods
ISO 4787, Labora
...
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