EN ISO 22036:2024
(Main)Environmental solid matrices - Determination of elements using inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 22036:2024)
Environmental solid matrices - Determination of elements using inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 22036:2024)
This document specifies a method for the determination of the following elements in aqua regia, nitric acid or mixture of hydrochloric (HCl), nitric (HNO3) and tetrafluoroboric (HBF4)/hydrofluoric (HF) acid digests of soil, treated biowaste, waste, sludge and sediment:
Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), chromium (Cr), cobalt (Co), copper (Cu), dysprosium (Dy), erbium (Er), europium (Eu), gallium (Ga), gadolinium (Gd), germanium (Ge), gold (Au), hafnium (Hf), holmium (Ho), indium (In), iridium (Ir), iron (Fe), lanthanum (La), lead (Pb), lithium (Li), lutetium (Lu) magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium (Nd), nickel (Ni), palladium (Pd), phosphorus (P), platinum (Pt), potassium (K), praseodymium (Pr), rhodium (Rh), ruthenium (Ru), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulfur (S), tantalum (Ta), tellurium (Te), terbium (Tb), thallium (Tl), thulium (Tm), thorium (Th), tin (Sn), titanium (Ti), tungsten (W), vanadium (V), yttrium (Y), ytterbium (Yb), zinc (Zn) and zirconium (Zr).
The method is also applicable to other extracts or digests originating from, for example, DTPA extraction, fusion methods or total digestion methods, provided the user has verified the applicability.
The method has been validated for the elements given in Table A.1 (sludge), Table A.2 (compost) and Table A.3 (soil). The method is applicable for other solid matrices and other elements as listed above, provided the user has verified the applicability.
This method is also applicable for the determination of major, minor and trace elements in aqua regia and nitric acid digests and in eluates of construction products (EN 17200[22]).
NOTE Construction products include e.g. mineral-based products; bituminous products; metals; wood-based products; plastics and rubbers; sealants and adhesives; paints and coatings.
Feste Umweltmatrizes - Bestimmung von Elementen mittels optischer Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-OES) (ISO 22036:2024)
Dieses Dokument legt ein Verfahren zur Bestimmung der folgenden Elemente in Königswasser, Salpetersäure oder einer Mischung aus Salzsäure (HCl), Salpetersäure (HNO3) und Tetrafluoroborsäure (HBF4)/Flusssäure (HF) in Aufschlüssen von Böden, behandelten Bioabfällen, Abfällen, Schlämmen und Sedimenten fest:
Aluminium (Al), Antimon (Sb), Arsen (As), Barium (Ba), Beryllium (Be), Bismut (Bi), Blei (Pb), Bor (B), Cadmium (Cd), Calcium (Ca), Cer (Ce), Chrom (Cr), Cobalt (Co), Eisen (Fe), Dysprosium (Dy), Erbium (Er), Europium (Eu), Gallium (Ga), Gadolinium (Gd), Germanium (Ge), Gold (Au), Hafnium (Hf), Holmium (Ho),Indium (In), Iridium (Ir), Kalium (K), Kupfer (Cu), Lanthan (La), Lithium (Li), Lutetium (Lu), Magnesium (Mg), Mangan (Mn), Molybdän (Mo), Natrium (Na), Neodym (Nd), Nickel (Ni), Palladium (Pd), Phosphor (P), Platin (Pt), Praseodym (Pr), Rhodium (Rh), Ruthenium (Ru), Quecksilber (Hg), Samarium (Sm), Scandium (Sc), Schwefel (S), Selen (Se), Silber (Ag), Silicium (Si), Strontium (Sr), Tantal (Ta), Tellur (Te), Terbium (Tb), Thallium (Tl),Thorium (Th), Thulium (Tm), Titan (Ti), Uran (U), Vanadium (V), Wolfram (W), Yttrium (Y), Ytterbium (Yb), Zink (Zn), Zinn (Sn) und Zirconium (Zr).
Dieses Verfahren ist auch für andere Extraktions- oder Aufschluss¬lösungen anwendbar, z. B. die DTPA-Extraktion (en: diethylenetriaminepentaacetic acid, Diethylentriamin¬pentaessigsäure), Lösungen, die mit einem Schmelzaufschlussverfahren oder mit einem Aufschlussverfahren zur Bestimmung von Element-Gesamtgehalten hergestellt wurden, sofern der Anwender die Anwendbarkeit überprüft hat.
Das Verfahren wurde für die in Tabelle A.1 (Schlämme), Tabelle A.2 (Kompost) und Tabelle A.3 (Böden) aufgeführten Elemente validiert. Das Verfahren ist für andere feste Matrices und andere als die oben aufgeführten Elemente anwendbar, sofern der Anwender die Anwendbarkeit überprüft hat.
Diese Methode ist auch für die Bestimmung von Haupt-, Neben- und Spurenelementen in Königswasser- und Salpetersäureaufschlüssen und in Eluaten von Bauprodukten anwendbar (EN 17200 [22]).
ANMERKUNG Bauprodukte umfassen z. B. Produkte auf Mineralbasis, bituminöse Produkte, Metalle, Produkte auf Holzbasis, Kunststoffe und Kautschuk, Dichtstoffe und Klebstoffe, Farben und Beschichtungen.
WARNUNG — Anwender dieses Dokuments sollten mit der üblichen Laborpraxis vertraut sein. Dieses Dokument gibt nicht vor, alle unter Umständen mit der Anwendung des Verfahrens verbundenen Sicherheitsaspekte anzusprechen. Es liegt in der Verantwortung des Anwenders, angemessene Sicherheits- und Schutzmaßnahmen zu treffen sowie die Einhaltung von nationalen Vorschriften sicherzustellen.
WICHTIG — Es ist unbedingt notwendig, dass Untersuchungen nach diesem Dokument von entsprechend ausgebildetem Personal durchgeführt werden.
Matrices solides environnementales - Dosage d’éléments par spectroscopie d’émission optique avec plasma induit par haute fréquence (ICP-OES) (ISO 22036:2024)
Le présent document spécifie une méthode de dosage des éléments suivants dans des digestats d’eau régale, d’acide nitrique ou de mélange d’acides chlorhydrique (HCl), nitrique (HNO3) et tétrafluoroborique (HBF4)/fluorhydrique (HF) de sols, de biodéchets traités, de déchets, de boues et de sédiment:
Aluminium (Al), antimoine (Sb), arsenic (As), baryum (Ba), béryllium (Be), bismuth (Bi), bore (B), cadmium (Cd), calcium (Ca), cérium (Ce), chrome (Cr), cobalt (Co), cuivre (Cu), dysprosium (Dy), erbium (Er), europium (Eu), gallium (Ga), gadolinium (Gd), germanium (Ge), or (Au), hafnium (Hf), holmium (Ho), indium (In), iridium (Ir), fer (Fe), lanthane (La), plomb (Pb), lithium (Li), lutécium (Lu) magnésium (Mg), manganèse (Mn), mercure (Hg), molybdène (Mo), néodyme (Nd), nickel (Ni), palladium (Pd), phosphore (P), platine (Pt), potassium (K), praséodyme (Pr), rhodium (Rh), ruthénium (Ru), samarium (Sm), scandium (Sc), sélénium (Se), silicium (Si), argent (Ag), sodium (Na), strontium (Sr), soufre (S), tantale (Ta), tellure (Te), terbium (Tb), thallium (Tl), thulium (Tm), thorium (Th), étain (Sn), titane (Ti), tungstène (W), vanadium (V), yttrium (Y), ytterbium (Yb), zinc (Zn) et zirconium (Zr).
Cette méthode s’applique également à d’autres extraits ou digestats issus, par exemple, de l’extraction au DTPA, de méthodes de fusion ou de méthodes de digestion totale, sous réserve que l’utilisateur ait vérifié l’applicabilité.
Cette méthode a été validée pour les éléments indiqués dans le Tableau A.1 (boues), le Tableau A.2 (compost) et le Tableau A.3 (sols). Elle est applicable à d’autres matrices solides et aux autres éléments énumérés ci-dessus, à condition que l’utilisateur ait vérifié l’applicabilité.
Cette méthode est également applicable au dosage des éléments majeurs, mineurs et à l’état de trace dans des digestats d’eau régale et d’acide nitrique ainsi que dans des éluats de produits de construction (EN 17200[22]).
NOTE Les produits de construction comprennent par exemple les produits minéraux; les produits bitumineux; les métaux; les produits ligneux; les matières plastiques et les caoutchoucs; les mastics et les adhésifs; les peintures et les revêtements.
Trdni matriksi v okolju - Določanje elementov z optično emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP/OES) (ISO 22036:2024)
ICS: 71.040.50, 13.080.10
Ta evropski standard določa metodo za določevanje naslednjih elementov v zlatotopki, raztopini izvlečka dušikove kisline blata, obdelanih bioloških odpadkov in tal: aluminij (Al), antimon (Sb), arzen (As), barij (Ba), berilij (Be), bizmut (Bi), bor (B), kadmij (Cd), kalcij (Ca), krom (Cr), kobalt (Co), baker (Cu), galij (Ga), indij (In), železo (Fe), svinec (Pb), litij (Li), magnezij (Mg), mangan (Mn), živo srebro (Hg), molibden (Mo), nikelj (Ni), fosfor (P), kalij (K), selen (Se), silicij (Si), srebro (Ag), natrij (Na), stroncij (Sr), žveplo (S), talij (Tl), kositer (Sn), titan (Ti), volfram (W), uran (U), vanadij (V), cink (Zn) in cirkonij (Zr).
Metoda je bila potrjena za elemente v preglednici A.1. Metoda se uporablja za druge zgoraj navedene elemente, če uporabnik preveri uporabnost.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-junij-2024
Nadomešča:
SIST EN 16170:2017
SIST ISO 22036:2019
Trdni matriksi v okolju - Določanje elementov z optično emisijsko spektrometrijo z
induktivno sklopljeno plazmo (ICP/OES) (ISO 22036:2024)
Environmental solid matrices - Determination of elements using inductively coupled
plasma optical emission spectrometry (ICP-OES) (ISO 22036:2024)
Feste Umweltmatrizes - Bestimmung von Elementen mittels optischer
Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-OES) (ISO 22036:2024)
Matrices solides environnementales - Dosage d’éléments par spectroscopie d’émission
optique avec plasma induit par haute fréquence (ICP-OES) (ISO 22036:2024)
Ta slovenski standard je istoveten z: EN ISO 22036:2024
ICS:
13.080.10 Kemijske značilnosti tal Chemical characteristics of
soils
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN ISO 22036
EUROPEAN STANDARD
NORME EUROPÉENNE
January 2024
EUROPÄISCHE NORM
ICS 13.080.10 Supersedes EN 16170:2016
English Version
Environmental solid matrices - Determination of elements
using inductively coupled plasma optical emission
spectrometry (ICP-OES) (ISO 22036:2024)
Matrices solides environnementales - Dosage Feste Umweltmatrizes - Bestimmung von Elementen
d'éléments par spectroscopie d'émission optique avec mittels optischer Emissionsspektrometrie mit induktiv
plasma induit par haute fréquence (ICP-OES) (ISO gekoppeltem Plasma (ICP-OES) (ISO 22036:2024)
22036:2024)
This European Standard was approved by CEN on 2 January 2024.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2024 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 22036:2024 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
European foreword
This document (EN ISO 22036:2024) has been prepared by Technical Committee ISO/TC 190 "Soil
quality" in collaboration with Technical Committee CEN/TC 444 “Environmental characterization of
solid matrices” the secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by July 2024, and conflicting national standards shall be
withdrawn at the latest by July 2024.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN 16170:2016.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
Endorsement notice
The text of ISO 22036:2024 has been approved by CEN as EN ISO 22036:2024 without any modification.
International
Standard
ISO 22036
Second edition
Environmental solid matrices —
2024-01
Determination of elements using
inductively coupled plasma optical
emission spectrometry (ICP-OES)
Matrices solides environnementales — Dosage d’éléments par
spectroscopie d’émission optique avec plasma induit par haute
fréquence (ICP-OES)
Reference number
ISO 22036:2024(en) © ISO 2024
ISO 22036:2024(en)
© ISO 2024
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
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Published in Switzerland
ii
ISO 22036:2024(en)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 2
5 Interferences . 3
5.1 General .3
5.2 Spectral interferences .3
5.3 Non-spectral interferences .4
6 Reagents . 5
7 Apparatus . 7
8 Procedure . 8
8.1 Cleaning of glassware.8
8.2 Instrument performance parameters .8
8.3 Instrument optimization .9
8.4 Instrument set-up .9
8.4.1 General requirements .9
8.4.2 Software method development, wavelength selection .9
8.4.3 Inter-element correction .9
8.4.4 Reference element .9
8.4.5 Long-term stability .10
8.4.6 Preliminary instrument check .10
8.5 Calibration .10
8.5.1 Linear calibration function .10
8.5.2 Standard addition calibration .11
8.6 Solutions to be prepared . . .11
8.6.1 General .11
8.6.2 Blank calibration solution .11
8.6.3 Blank test solution .11
8.6.4 Calibration solutions .11
8.6.5 Test sample solutions . 12
8.6.6 Test solutions . 12
8.7 Measurement procedure . 12
9 Calculation .12
10 Expression of results .13
11 Performance characteristics .13
11.1 Calibration check . 13
11.2 Interference . 13
11.3 Recovery .
...
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