ISO 16000-38:2019
(Main)Indoor air — Part 38: Determination of amines in indoor and test chamber air — Active sampling on samplers containing phosphoric acid impregnated filters
Indoor air — Part 38: Determination of amines in indoor and test chamber air — Active sampling on samplers containing phosphoric acid impregnated filters
This document specifies a method for the determination of primary, secondary and tertiary aliphatic and aromatic amines in indoor air using accumulated sampling and high-performance liquid-chromatography (HPLC) coupled with tandem mass spectrometry (MS-MS) or high resolution mass spectrometry (HRMS). It specifies the sampling procedure for determining the mass concentration of amines as mean values by sampling the amines on phosphoric acid impregnated filters. The analytical procedure of the measurement method is covered by ISO 16000-39. Measurements, performed with samplers containing phosphoric acid-impregnated inert supporting material and operating at specified flow rates for specified sampling periods are described in this document. Requirements regarding sample volume are also defined. The range of application of this document concerning the concentrations of amines in indoor air depends on the linear range of the calibration line and hence on the gas sample volume (here: from 5 l up to 100 l), the eluate volume (from 1 ml up to 5 ml), the injection volume (from 1 µl up to 10 µl) and the sensitivity of the analytical equipment (e.g. linear range from 2 pg up to 2 ng amine). The range of application can be expected to be from approximately 0,002 µg/m3 (100 l sample) up to 2 000 µg/m3 (5 l sample) for a common analytical equipment[1] for the majority of the amines listed in Annex A. The analysis of derivatives of ethanolamine is usually about 10 times more sensitive and the analysis of short-chained aliphatic amines is usually about 10 times less sensitive than the analysis of an average amine. Although primarily intended for the measurement of amines listed in Annex A, this document can also be used for the measurement of other amines in indoor air. This document describes procedures for the fabrication and gives requirements for the use of glass tubes containing impregnated filters out of phosphoric acid-impregnated glass wool as samplers, but does not exclude other samplers with proven equal or improved properties. This document also gives procedures for the demonstration of equivalence of other sampler types or methods. This document does not cover the determination of amines in other media like water or soil. Furthermore, it does not cover the determination of isocyanates in indoor air as corresponding amines (covered by ISO 17734-1 and ISO 17734-2). Quaternary amines are also not included in this document. [1] Waters "TQ-D" is an example of a suitable product available commercially. This information is given for the convenience of users of this document and does not constitute an endorsement by ISO of this product.
Titre manque — Partie 38:
Notranji zrak - 38. del: Določevanje aminov v notranjem zraku in preskusni komori - Aktivno vzorčenje z vzorčevalniki s filtri, impregniranimi s fosforjevo kislino
Ta dokument določa metodo za določevanje primarnih, sekundarnih in terciarnih alifatskih ter aromatskih aminov v notranjem zraku z uporabo akumuliranega vzorčenja in visokozmogljive tekočinske kromatografije (HPLC) skupaj s tandemsko masno spektrometrijo (MS-MS) ali masno spektrometrijo visoke ločljivosti (HRMS). Določa postopek vzorčenja za določevanje masne koncentracije aminov kot povprečnih vrednosti z vzorčenjem aminov s filtri, impregniranimi s fosforjevo kislino. Analitični postopek metode merjenja je zajet v standardu ISO 16000-39. V tem dokumentu so opisane meritve z vzorčevalniki, ki vsebujejo inertni material, impregniran s fosforno kislino, in delujejo pri določenih pretokih in v določenem času vzorčenja. Opredeljene so tudi zahteve glede volumna vzorca. Področje uporabe tega dokumenta v zvezi s koncentracijami aminov v notranjem zraku je odvisno od linearnega obsega kalibracijske krivulje in s tem od volumna vzorca plina (tukaj: od 5 l do 100 l), volumna eluata (od 1 ml do 5 ml), volumna vbrizgavanja (od 1 μl do 10 μl) in občutljivosti analitične opreme (npr. linearni razpon od 2 pg do 2 ng amina). Obseg uporabe je mogoče pričakovati od približno 0,002 μg/m3 (vzorec 100 l) do 2000 μg/m3 (vzorec 5 l) za skupno analitsko opremo1) za večino aminov, naštetih v dodatku A. Analiza derivatov etanolamina je običajno približno 10-krat občutljivejša, analiza kratko verižnih alifatičnih aminov pa je običajno približno 10-krat manj občutljiva kot analiza povprečnega amina. Čeprav je dokument namenjen predvsem za merjenje aminov, naštetih v dodatku A, ga je mogoče uporabiti tudi za merjenje drugih aminov v notranjem zraku. Ta dokument opisuje postopke izdelave in določa zahteve za uporabo steklenih cevi, ki kot vzorčevalnike vsebujejo filtre iz steklene volne, impregnirane s fosforjevo kislino, ne izključuje pa drugih vzorčevalnikov z dokazano enakimi ali izboljšanimi lastnostmi. Dokument vsebuje tudi postopke za dokazovanje enakovrednosti drugih vrst vzorčevalnikov ali metod. Ta dokument ne obravnava določevanja aminov v drugih medijih, kot sta voda ali zemlja. Poleg tega ne zajema določevanja izocianatov kot ustreznih aminov v notranjem zraku (zajeto v standardih ISO 17734-1 in ISO 17734-2). V tem dokumentu tudi niso vključeni kvarterni amini.
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SLOVENSKI STANDARD
SIST ISO 16000-38:2019
01-december-2019
Notranji zrak - 38. del: Določevanje aminov v notranjem zraku in preskusni komori
- Aktivno vzorčenje z vzorčevalniki s filtri, impregniranimi s fosforjevo kislino
Indoor air - Part 38: Determination of amines in indoor and test chamber air - Active
sampling on samplers containing phosphoric acid impregnated filters
Ta slovenski standard je istoveten z: ISO 16000-38:2019
ICS:
13.040.20 Kakovost okoljskega zraka Ambient atmospheres
SIST ISO 16000-38:2019 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
SIST ISO 16000-38:2019
---------------------- Page: 2 ----------------------
SIST ISO 16000-38:2019
INTERNATIONAL ISO
STANDARD 16000-38
First edition
2019-02
Indoor air —
Part 38:
Determination of amines in indoor
and test chamber air — Active
sampling on samplers containing
phosphoric acid impregnated filters
Reference number
ISO 16000-38:2019(E)
©
ISO 2019
---------------------- Page: 3 ----------------------
SIST ISO 16000-38:2019
ISO 16000-38:2019(E)
COPYRIGHT PROTECTED DOCUMENT
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved
---------------------- Page: 4 ----------------------
SIST ISO 16000-38:2019
ISO 16000-38:2019(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Amines in indoor air . 2
4.1 Properties of amines . 2
4.2 Origin and occurrence of amines in indoor air . 2
5 Sampling strategy — Measurement procedure . 2
5.1 Structure and properties of the samplers . 2
5.2 Manufacturing of the samplers . 3
5.2.1 General. 3
5.2.2 Implementation . 3
5.2.3 Verification . 3
5.3 Selection of the suitable sampling time . 4
5.4 Sampling protocol .
...
INTERNATIONAL ISO
STANDARD 16000-38
First edition
2019-02
Indoor air —
Part 38:
Determination of amines in indoor
and test chamber air — Active
sampling on samplers containing
phosphoric acid impregnated filters
Reference number
ISO 16000-38:2019(E)
©
ISO 2019
---------------------- Page: 1 ----------------------
ISO 16000-38:2019(E)
COPYRIGHT PROTECTED DOCUMENT
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved
---------------------- Page: 2 ----------------------
ISO 16000-38:2019(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Amines in indoor air . 2
4.1 Properties of amines . 2
4.2 Origin and occurrence of amines in indoor air . 2
5 Sampling strategy — Measurement procedure . 2
5.1 Structure and properties of the samplers . 2
5.2 Manufacturing of the samplers . 3
5.2.1 General. 3
5.2.2 Implementation . 3
5.2.3 Verification . 3
5.3 Selection of the suitable sampling time . 4
5.4 Sampling protocol . 4
5.5 Comparative measurements . 4
5.6 Sampling procedure . 5
5.7 Storing of the samples . 5
5.8 Sample preparation and transfer to the analytical procedure .
...
SLOVENSKI STANDARD
oSIST ISO 16000-38:2019
01-september-2019
Notranji zrak - 38. del: Določevanje aminov v notranjem zraku in preskusni komori
- Aktivno vzorčenje z vzorčevalniki s filtri, impregniranimi s fosforjevo kislino
Indoor air - Part 38: Determination of amines in indoor and test chamber air - Active
sampling on samplers containing phosphoric acid impregnated filters
Ta slovenski standard je istoveten z: ISO 16000-38:2019
ICS:
13.040.20 Kakovost okoljskega zraka Ambient atmospheres
oSIST ISO 16000-38:2019 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
oSIST ISO 16000-38:2019
---------------------- Page: 2 ----------------------
oSIST ISO 16000-38:2019
INTERNATIONAL ISO
STANDARD 16000-38
First edition
2019-02
Indoor air —
Part 38:
Determination of amines in indoor
and test chamber air — Active
sampling on samplers containing
phosphoric acid impregnated filters
Reference number
ISO 16000-38:2019(E)
©
ISO 2019
---------------------- Page: 3 ----------------------
oSIST ISO 16000-38:2019
ISO 16000-38:2019(E)
COPYRIGHT PROTECTED DOCUMENT
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved
---------------------- Page: 4 ----------------------
oSIST ISO 16000-38:2019
ISO 16000-38:2019(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Amines in indoor air . 2
4.1 Properties of amines . 2
4.2 Origin and occurrence of amines in indoor air . 2
5 Sampling strategy — Measurement procedure . 2
5.1 Structure and properties of the samplers . 2
5.2 Manufacturing of the samplers . 3
5.2.1 General. 3
5.2.2 Implementation . 3
5.2.3 Verification . 3
5.3 Selection of the suitable sampling time . 4
5.4 Sampling protocol .
...
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