Inorganic fertilizers - Determination of specific contaminants

This document specifies references to methods for the determination of the biuret, mercury, cadmium, nickel, copper, zinc, arsenic, lead, perchlorate, chromium VI and total chromium content in inorganic fertilizers.

Anorganische Düngemittel - Bestimmung spezifischer Kontaminanten

Dieses Dokument legt Verweisungen auf Verfahren zur Bestimmung der folgenden Kontaminanten fest: Quecksilber, Cadmium, Nickel, Kupfer, Zink, Arsen, Blei, Chrom(VI), Biuret, Perchlorat und der Gesamtgehalt an Chrom in anorganischen Düngemitteln.
Dieses Dokument ist anwendbar auf EU Düngeprodukte der Kategorien PFC 1(C) und PFC 7, vorausgesetzt, die Mischung besteht ausschließlich aus EU Düngeprodukten der Kategorie PFC 1(C), PFC 2 und PFC 5 der Verordnung (EU) 2019/1009 [3].
Ein Überblick über die Verweisungen auf Verfahren zur Bestimmung der spezifischen Kontaminanten wird in Tabelle 1 gegeben.
ANMERKUNG 1   Die Bestimmung von Kupfer und Zink als Spurennährstoffe in anorganischen Düngemitteln wird in CEN/TS 17754:2022 behandelt.
ANMERKUNG 2   Die Bestimmung von Kupfer in Ammoniumnitratdüngemitteln mit hohem Stickstoffgehalt wird in CEN/TS 17751:2022 behandelt.

Engrais inorganiques - Détermination des contaminants spécifiques

Le présent document spécifie les références des méthodes de détermination des contaminants suivants : la teneur en mercure, en cadmium, en nickel, en cuivre, en zinc, en arsenic, en plomb, en chrome (VI), en biuret, en perchlorate et en chrome total dans les engrais inorganiques.
Le présent document est applicable aux fertilisants UE classés en PFC 1(C) et PFC 7 tant que la combinaison ne se compose que de fertilisants UE classés en PFC 1(C), PFC 2 et PFC 5 comme spécifié dans le règlement (UE) 2019/1009 [3].
Un aperçu des références aux méthodes de détermination des contaminants spécifiques est donné dans le Tableau 1.
NOTE 1   Le dosage du cuivre et du zinc dans les engrais inorganiques en tant qu'oligo-éléments est couvert par la CEN/TS 17754:2022.
NOTE 2   Le dosage du cuivre dans les engrais à base de nitrate d'ammonium à forte teneur en azote est couvert par la CEN/TS 17751:2022.

Anorganska gnojila - Določevanje specifičnih onesnaževal

Ta dokument navaja metode za določevanje vsebnosti biureta, živega srebra, kadmija, niklja, bakra, cinka, arzena, svinca, perklorata, kroma VI in celotnega kroma v anorganskih gnojilih.

General Information

Status
Published
Public Enquiry End Date
02-Jan-2022
Publication Date
08-Jan-2023
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
06-Jan-2023
Due Date
13-Mar-2023
Completion Date
09-Jan-2023

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Standards Content (Sample)

SLOVENSKI STANDARD
SIST-TS CEN/TS 17753:2023
01-februar-2023
Anorganska gnojila - Določevanje specifičnih onesnaževal
Inorganic fertilizers - Determination of specific contaminants
Anorganische Düngemittel - Bestimmung spezifischer Kontaminanten
Engrais inorganiques - Détermination des contaminants spécifiques
Ta slovenski standard je istoveten z: CEN/TS 17753:2022
ICS:
65.080 Gnojila Fertilizers
SIST-TS CEN/TS 17753:2023 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST-TS CEN/TS 17753:2023

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SIST-TS CEN/TS 17753:2023


CEN/TS 17753
TECHNICAL SPECIFICATION

SPÉCIFICATION TECHNIQUE

April 2022
TECHNISCHE SPEZIFIKATION
ICS 65.080
English Version

Inorganic fertilizers - Determination of specific
contaminants
Engrais inorganiques - Détermination des Anorganische Düngemittel - Bestimmung spezifischer
contaminants spécifiques Kontaminanten
This Technical Specification (CEN/TS) was approved by CEN on 13 March 2022 for provisional application.

The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to
submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.

CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS
available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in
parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2022 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 17753:2022 E
worldwide for CEN national Members.

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SIST-TS CEN/TS 17753:2023
CEN/TS 17753:2022 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 6
4 Sampling and sample preparation . 6
4.1 Sampling . 6
4.2 Sample preparation . 6
5 Determination of specific contaminants . 6
5.1 Mercury (Hg) . 6
5.2 Cadmium (Cd), nickel (Ni), arsenic (As) and lead (Pb) . 6
5.3 Copper (Cu) and zinc (Zn) . 7
5.4 Chromium(VI) (Cr(VI)) . 7
5.5 Biuret (C H N O ) . 7
2 5 3 2
5.6 Perchlorate (ClO -) . 7
4
5.7 Total chromium (Cr(total)) . 7
Bibliography . 9

2

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SIST-TS CEN/TS 17753:2023
CEN/TS 17753:2022 (E)
European foreword
This document (CEN/TS 17753:2022) has been prepared by Technical Committee CEN/TC 260
“Fertilizers and liming materials”, the secretariat of which is held by DIN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a standardization request given to CEN by the European
Commission and the European Free Trade Association.
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN/CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United
Kingdom.

3

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SIST-TS CEN/TS 17753:2023
CEN/TS 17753:2022 (E)
Introduction
Regulation (EU) 2019/1009 [3] lays down the rules on the making available on the market of EU
fertilizing products and the specific safety and quality requirements for the defined product function
categories (PFCs). Inorganic fertilizers have been classified into PFC 1(C).
The specific safety and quality requirements in relation to specific contaminants (i.e. the mercury,
cadmium, nickel, copper, zinc, arsenic, lead, chromium VI, biuret, perchlorate and total chromium
content) are defined in this document as well as normative references of the test methods to be used in
order to measure the compliance with the related requirement in the Regulation (EU) 2019/1009 [3].

4

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SIST-TS CEN/TS 17753:2023
CEN/TS 17753:2022 (E)
1 Scope
This document specifies references to methods for the determination of the following contaminants:
mercury, cadmium, nickel, copper, zinc, arsenic, lead, chromium(VI), biuret, perchlorate and total
chromium content in inorganic fertilizers.
This document is applicable to EU fertilizing products classified as PFC 1(C) and PFC 7 as long as the
blend only consists of EU fertilizing products classified as PFC 1(C), PFC 2 and PFC 5 as specified in the
Regulation (EU) 2019/1009 [3].
An overview of the references to methods for the determination of the specific contaminants is given in
Table 1.
NOTE 1 The determination of copper and zinc in inorganic fertilizers as micronutrients is covered by
CEN/TS 17754:2022.
NOTE 2 The determination of copper in ammonium nitrate fertilizers of high nitrogen content is covered by
CEN/TS 17751:2022.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 1482
...

SLOVENSKI STANDARD
kSIST-TS FprCEN/TS 17753:2021
01-december-2021
Anorganska gnojila - Določevanje določenih onesnaževal
Inorganic fertilizers - Determination of specific contaminants
Anorganische Düngemittel - Bestimmung spezifischer Kontaminanten
Engrais inorganiques - Détermination des contaminants spécifiques
Ta slovenski standard je istoveten z: FprCEN/TS 17753
ICS:
65.080 Gnojila Fertilizers
kSIST-TS FprCEN/TS 17753:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
kSIST-TS FprCEN/TS 17753:2021

---------------------- Page: 2 ----------------------
kSIST-TS FprCEN/TS 17753:2021


FINAL DRAFT
TECHNICAL SPECIFICATION
FprCEN/TS 17753
SPÉCIFICATION TECHNIQUE

TECHNISCHE SPEZIFIKATION

November 2021
ICS 65.080
English Version

Inorganic fertilizers - Determination of specific
contaminants
Engrais inorganiques - Détermination des Anorganische Düngemittel - Bestimmung spezifischer
contaminants spécifiques Kontaminanten


This draft Technical Specification is submitted to CEN members for Vote. It has been drawn up by the Technical Committee
CEN/TC 260.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a Technical Specification. It is distributed for review and comments. It is subject to change
without notice and shall not be referred to as a Technical Specification.


EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. FprCEN/TS 17753:2021 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------
kSIST-TS FprCEN/TS 17753:2021
FprCEN/TS 17753:2021 (E)
Contents Page

European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 6
4 Sampling and sample preparation . 6
4.1 Sampling . 6
4.2 Sample preparation . 6
5 Determination of specific contaminants . 6
5.1 Mercury (Hg) . 6
5.2 Cadmium (Cd), nickel (Ni), arsenic (As) and lead (Pb) . 6
5.3 Copper and zinc . 7
5.4 Chromium VI . 7
5.5 Biuret . 7
5.6 Perchlorate . 7
5.7 Total chromium . 7
Bibliography . 9


2

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kSIST-TS FprCEN/TS 17753:2021
FprCEN/TS 17753:2021 (E)
European foreword
This document (FprCEN/TS 17753:2021) has been prepared by Technical Committee CEN/TC 260
“Fertilizers and liming materials”, the secretariat of which is held by DIN.
This document is currently submitted to the Vote on TS.
This document has been prepared under a standardization request given to CEN by the European
Commission and the European Free Trade Association.
3

---------------------- Page: 5 ----------------------
kSIST-TS FprCEN/TS 17753:2021
FprCEN/TS 17753:2021 (E)
Introduction
Regulation (EU) 2019/1009 [3] lays down the rules on the making available on the market of EU
fertilizing products and the specific safety and quality requirements for the defined product function
categories (PFCs). Inorganic fertilizers have been classified into PFC 1(C).
The specific safety and quality requirements in relation to specific contaminants (i.e. the mercury,
cadmium, nickel, copper, zinc, arsenic, lead, chromium VI, biuret, perchlorate and total chromium
content) are defined in this document as well as normative references of the test methods to be used in
order to measure the compliance with the related requirement in the Regulation (EU) 2019/1009 [3].
4

---------------------- Page: 6 ----------------------
kSIST-TS FprCEN/TS 17753:2021
FprCEN/TS 17753:2021 (E)
1 Scope
This document specifies references to methods for the determination of the following contaminants:
mercury, cadmium, nickel, copper, zinc, arsenic, lead, chromium VI, biuret, perchlorate and total
chromium content in inorganic fertilizers.
This document is applicable to EU fertilizing products classified as PFC 1(C) and PFC 7 as long as the
blend only consists of EU fertilizing products classified as PFC 1(C), PFC 2 and PFC 5 as specified in the
Regulation (EU) 2019/1009 [3].
An overview of the references to methods for the determination of the specific contaminants is given in
Table 1.
NOTE 1 The determination of copper and zinc in inorganic fertilizers as micronutrients is covered by
1
FprCEN/TS 17754:2021 .
NOTE 2 The determination of copper in ammonium nitrate fertilizers of high nitrogen content is covered by
2
FprCEN/TS 17751:2021 .
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 1482-1:2007, Fertilizers and liming materials - Sampling and sample preparation - Part 1: Sampling
EN 1482-2:2007, Fertilizers and liming materials - Sampling and sample preparation - Part 2: Sample
preparation
EN 1482-3:2016, Fertilizers and liming materials - Sampling and sample preparation - Part 3: Sampling of
static heaps
EN 12944-1:1999, Fertilizers and liming materials and soil improvers - Vocabulary - Part 1: General terms
EN 12944-2:1999, Fertilizers and liming materials and soil improv
...

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