Pulp, paper and paperboard - Determination of bisphenol A in extracts from paper and paperboard

This Technical Report specifies an analytical test method for the determination of bisphenol A in solvent extracts of paper and board materials and articles intended to come into contact with foodstuffs using a high performance liquid chromatograph coupled to a fluorescence detector (HPLC-FLD).
This method can be applied to determine Bisphenol A (see table 1) in concentrations ranging from 0,025 mg/l to 2 mg/l in the solvent extracts, corresponding to 0,05 mg/kg to 4 mg/kg paper and board. The measurement range can easily be extended up to 40 mg/kg by adjusting the concentration factor of the solvent extract.

Zellstoff, Papier und Karton - Bestimmung von Bisphenol A in Papier- und Kartonextrakten

Dieses Dokument legt ein Analyseverfahren zur Bestimmung von Bisphenol A in Lösemittelextrakten von Materialien aus Papier und Pappe und Gegenständen, die dazu bestimmt sind, mit Lebensmitteln in Berührung zu kommen, unter Verwendung eines Hochleistungsflüssigkeitschromatographen, der mit einem Fluoreszenzdetektor gekoppelt ist (HPLC-FLD), fest.
Dieses Verfahren kann angewendet werden, um Bisphenol A (siehe Tabelle 1) in Konzentrationen von 0,025 mg/l bis 2 mg/l in den Lösemittelextrakten, entsprechend 0,05 mg/kg bis 4 mg/kg Papier und Pappe, zu bestimmen. Der Messbereich kann durch Einstellen des Konzentrationsfaktors des Lösemittelextrakts leicht auf bis zu 40 mg/kg erweitert werden.

Cellulose, papier et canon —- Détermination des bisphenol A dans des extraits de papier et canon

Le présent document décrit une méthode d'essai analytique pour la détermination du bisphénol A dans des extraits par solvant de matériaux et d'articles en papier et en carton destinés à entrer en contact avec les denrées alimentaires, à l'aide d'un chromatographe en phase liquide à haute performance couplé à un détecteur de fluorescence (CLHP-DFL).
Cette méthode peut être appliquée pour déterminer le bisphénol A (voir Tableau 1) dans des concentrations de 0,025 mg/l à 2 mg/l dans les extraits par solvant, correspondant à 0,05 mg/kg à 4 mg/kg de papier et de carton. La plage de mesure peut être facilement étendue jusqu'à 40 mg/kg en ajustant le facteur de concentration de l'extrait par solvant.

Vlaknine, papir, karton in lepenka - Ugotavljanje bisfenola A v ekstraktih papirja, kartona in lepenke

General Information

Status
Published
Public Enquiry End Date
19-May-2020
Publication Date
07-Sep-2020
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
03-Sep-2020
Due Date
08-Nov-2020
Completion Date
08-Sep-2020

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SLOVENSKI STANDARD
SIST-TS CEN/TS 17497:2020
01-oktober-2020

Vlaknine, papir, karton in lepenka - Ugotavljanje bisfenola A v ekstraktih papirja,

kartona in lepenke

Pulp, paper and paperboard - Determination of bisphenol A in extracts from paper and

paperboard
Zellstoff, Papier und Karton - Bestimmung von Bisphenol A in Papier- und
Kartonextrakten

Cellulose, papier et canon - Détermination des bisphenol A dans des extraits de papier et

canon
Ta slovenski standard je istoveten z: CEN/TS 17497:2020
ICS:
85.060 Papir, karton in lepenka Paper and board
SIST-TS CEN/TS 17497:2020 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
SIST-TS CEN/TS 17497:2020
---------------------- Page: 2 ----------------------
SIST-TS CEN/TS 17497:2020
CEN/TS 17497
TECHNICAL SPECIFICATION
SPÉCIFICATION TECHNIQUE
August 2020
TECHNISCHE SPEZIFIKATION
ICS 85.060
English Version
Pulp, paper and paperboard - Determination of bisphenol
A in extracts from paper and paperboard

Cellulose, papier et carton - Détermination des Zellstoff, Papier und Karton - Bestimmung von

bisphénol A dans des extraits de papier et carton Bisphenol A in Papier- und Kartonextrakten

This Technical Specification (CEN/TS) was approved by CEN on 19 July 2020 for provisional application.

The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to

submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.

CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS

available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in

parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,

Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and

United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 17497:2020 E

worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
SIST-TS CEN/TS 17497:2020
CEN/TS 17497:2020 (E)
Contents Page

European foreword ....................................................................................................................................................... 3

1 Scope .................................................................................................................................................................... 4

2 Normative references .................................................................................................................................... 4

3 Terms and definitions ................................................................................................................................... 4

4 Principle ............................................................................................................................................................. 4

5 Materials ............................................................................................................................................................. 5

6 Apparatus ........................................................................................................................................................... 5

7 Reagents ............................................................................................................................................................. 5

8 Sampling ............................................................................................................................................................. 6

9 Preparation of the analysis samples ........................................................................................................ 6

10 Procedure........................................................................................................................................................... 7

10.1 Example of suitable HPLC conditions for the analysis of bisphenol A ......................................... 7

10.2 Calibration ......................................................................................................................................................... 7

10.3 Analysis of the sample extracts .................................................................................................................. 7

11 Expression of results ...................................................................................................................................... 8

12 Test report ......................................................................................................................................................... 8

Annex A (informative) FLD chromatograms of calibration solutions with 0,05 mg/l and

1 mg/l bisphenol A in acetonitrile ............................................................................................................ 9

---------------------- Page: 4 ----------------------
SIST-TS CEN/TS 17497:2020
CEN/TS 17497:2020 (E)
European foreword

This document (CEN/TS 17497:2020) has been prepared by Technical Committee CEN/TC 172 “Pulp,

paper and board”, the secretariat of which is held by DIN.

Attention is drawn to the possibility that some of the elements of this document may be the subject of

patent rights. CEN shall not be held responsible for identifying any or all such patent rights.

According to the CEN/CENELEC Internal Regulations, the national standards organisations of the

following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria,

Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,

Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of

North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the

United Kingdom.
---------------------- Page: 5 ----------------------
SIST-TS CEN/TS 17497:2020
CEN/TS 17497:2020 (E)
1 Scope

This document specifies an analytical test method for the determination of bisphenol A in solvent

extracts of paper and board materials and articles intended to come into contact with foodstuffs using a

high performance liquid chromatograph coupled to a fluorescence detector (HPLC-FLD).

This method can be applied to determine bisphenol A (see Table 1) in concentrations ranging from

0,025 mg/l to 2 mg/l in the solvent extracts, corresponding to 0,05 mg/kg to 4 mg/kg paper and board.

The measurement range can easily be extended up to 40 mg/kg by adjusting the concentration factor of

the solvent extract.
Table 1 — Bisphenol A
Name Abbreviation Formula CAS N° Structure
C H O
Bisphenol A BPA 80–05–7
15 16 2
2 Normative references

The following documents are referred to in the text in such a way that some or all of their content

constitutes requirements of this document. For dated references, only the edition cited applies. For

undated references, the latest edition of the referenced document (including any amendments) applies.

EN ISO 186, Paper and board - Sampling to determine average quality (ISO 186)
EN ISO 536, Paper and board - Determination of grammage (ISO 536)

EN ISO 638, Paper, board and pulps - Determination of dry matter content - Oven-drying method (ISO 638)

3 Terms and definitions
No terms and definitions are listed in this document.
ISO and IEC maintain terminological databases for use in
...

SLOVENSKI STANDARD
kSIST-TS FprCEN/TS 17497:2020
01-maj-2020

Vlaknine, papir, karton in lepenka - Ugotavljanje bisfenola A v ekstraktih papirja,

kartona in lepenke

Pulp, paper and paperboard - Determination of bisphenol A in extracts from paper and

paperboard
Zellstoff, Papier und Karton - Bestimmung von Bisphenol A in Papier- und
Kartonextrakten

Cellulose, papier et canon - Détermination des bisphenol A dans des extraits de papier

et canon
Ta slovenski standard je istoveten z: FprCEN/TS 17497
ICS:
85.060 Papir, karton in lepenka Paper and board
kSIST-TS FprCEN/TS 17497:2020 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
kSIST-TS FprCEN/TS 17497:2020
---------------------- Page: 2 ----------------------
kSIST-TS FprCEN/TS 17497:2020
FINAL DRAFT
TECHNICAL SPECIFICATION
FprCEN/TS 17497
SPÉCIFICATION TECHNIQUE
TECHNISCHE SPEZIFIKATION
March 2020
ICS 85.060
English Version
Pulp, paper and paperboard - Determination of bisphenol
A in extracts from paper and paperboard

Cellulose, papier et canon ¿- Détermination des Zellstoff, Papier und Karton - Bestimmung von

bisphenol A dans des extraits de papier et canon Bisphenol A in Papier- und Kartonextrakten

This draft Technical Specification is submitted to CEN members for Vote. It has been drawn up by the Technical Committee

CEN/TC 172.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,

Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and

United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are

aware and to provide supporting documentation.

Warning : This document is not a Technical Specification. It is distributed for review and comments. It is subject to change

without notice and shall not be referred to as a Technical Specification.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. FprCEN/TS 17497:2020 E

worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
kSIST-TS FprCEN/TS 17497:2020
FprCEN/TS 17497:2020 (E)
Contents Page

European foreword ....................................................................................................................................................... 3

1 Scope .................................................................................................................................................................... 4

2 Normative references .................................................................................................................................... 4

3 Terms and definitions ................................................................................................................................... 4

4 Principle ............................................................................................................................................................. 4

5 Materials ............................................................................................................................................................. 5

6 Apparatus ........................................................................................................................................................... 5

7 Reagents ............................................................................................................................................................. 5

8 Sampling ............................................................................................................................................................. 6

9 Preparation of the analysis samples ........................................................................................................ 6

10 Procedure........................................................................................................................................................... 7

10.1 Example of suitable HPLC conditions for the analysis of bisphenol A ......................................... 7

10.2 Calibration ......................................................................................................................................................... 7

10.3 Analysis of the sample extracts .................................................................................................................. 7

11 Expression of results ...................................................................................................................................... 8

12 Test report ......................................................................................................................................................... 8

Annex A (informative) FLD chromatograms of calibration solutions with 0,05 mg/l and

1 mg/l bisphenol A in acetonitrile ............................................................................................................ 9

---------------------- Page: 4 ----------------------
kSIST-TS FprCEN/TS 17497:2020
FprCEN/TS 17497:2020 (E)
European foreword

This document (FprCEN/TS 17497:2020) has been prepared by Technical Committee CEN/TC 172

“Pulp, paper and board”, the secretariat of which is held by DIN.
This document is currently submitted to the Vote on TS.
---------------------- Page: 5 ----------------------
kSIST-TS FprCEN/TS 17497:2020
FprCEN/TS 17497:2020 (E)
1 Scope

This document specifies an analytical test method for the determination of bisphenol A in solvent

extracts of paper and board materials and articles intended to come into contact with foodstuffs using a

high performance liquid chromatograph coupled to a fluorescence detector (HPLC-FLD).

This method can be applied to determine Bisphenol A (see Table 1) in concentrations ranging from

0,025 mg/l to 2 mg/l in the solvent extracts, corresponding to 0,05 mg/kg to 4 mg/kg paper and board.

The measurement range can easily be extended up to 40 mg/kg by adjusting the concentration factor of

the solvent extract.
Table 1 — Bisphenol A
Name Abbreviation Formula CAS N° Structure
C H O
Bisphenol A BPA 80–05–7
15 16 2
2 Normative references

The following documents are referred to in the text in such a way that some or all of their content

constitutes requirements of this document. For dated references, only the edition cited applies. For

undated references, the latest edition of the referenced document (including any amendments) applies.

EN ISO 186, Paper and board - Sampling to determine average quality (ISO 186)
EN ISO 536, Paper and board - Determination of grammage (ISO 536)

EN ISO 638, Paper, board and pulps - Determination of dry matter content - Oven-drying method (ISO 638)

3 Terms and definitions
No terms and definitions are listed in this document.

ISO and IEC maintain terminological databases for use in standardization at the following addresses:

— IEC Electropedia: available at http://www.electropedia.org/
— ISO Online browsing platform: available at http://www.iso.org/obp
4 Principle
To assess the content of bisphenol A in paper and board materials,
...

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