Bitumen and bituminous binders - Determination of the pH value of bituminous emulsions

This document specifies a method for measuring the pH value of bituminous emulsions.
It is applicable to anionic, cationic bituminous emulsions and bituminous emulsions prepared by means of non-ionic surfactant.
In certain circumstances, the pH value can provide an indication of the ionic character of a bituminous emulsion. However, this indication should be confirmed by a particle polarity test conforming to EN 1430 [1].
WARNING - The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this document to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.

Bitumen und bitumenhaltige Bindemittel - Bestimmung des pH-Wertes von Bitumenemulsionen

Dieses Dokument legt ein Verfahren zur Bestimmung des pH Wertes von Bitumenemulsionen fest.
Es ist auf anionische, kationische Bitumenemulsionen und Bitumenemulsionen, die mit Hilfe von nicht-ionischen Tensiden vorbereitet wurden, anwendbar.
Unter bestimmten Umständen kann der pH Wert einen Hinweis auf den Ionencharakter einer Bitumen-emulsion geben. Dieser Hinweis sollte jedoch durch eine Prüfung der Teilchenpolarität nach EN 1430 [1] bestätigt werden.
WARNUNG - Die Anwendung dieses Dokumentes kann die Anwendung gefährlicher Stoffe, Arbeitsgänge und Geräte mit sich bringen. Dieses Dokument beansprucht nicht, alle damit verbundenen Sicherheitsprobleme zu behandeln. Es liegt in der Verantwortung des Anwenders dieses Dokuments, geeignete Sicherheits- und Gesundheitsschutz¬maßnahmen vorzusehen und im Vorfeld die Anwendbarkeit von einschränkenden Vorschriften zu klären.

Bitumes et liants bitumineux - Détermination du pH des émulsions bitumineuses

Ce document spécifie une méthode pour la détermination du pH des émulsions bitumineuses.
Il est applicable aux émulsions bitumineuses anioniques, cationiques et aux émulsions bitumineuses préparées à l’aide de surfactants non-ioniques.
Dans certains cas, la valeur du pH peut fournir une indication sur le caractère ionique de l’émulsion bitumineuse. Toutefois, il convient de confirmer cette indication en effectuant un essai de détermination de la polarité des particules conformément à l’EN 1430 [1].
AVERTISSEMENT - L'utilisation de ce document implique l'intervention de produits, d'opérations et d'équipements à caractère dangereux. Le présent document n'est pas censé aborder tous les problèmes de sécurité concernés par son usage. Il est de la responsabilité de son utilisateur d'établir des règles d'hygiène et de sécurité appropriées et de déterminer l'applicabilité des restrictions réglementaires avant utilisation.

Bitumen in bitumenska veziva - Določevanje pH vrednosti bitumenskih emulzij

Ta dokument določa metodo za merjenje pH vrednosti bitumenskih emulzij.
Uporablja se za anionske in kationske bitumenske emulzije ter bitumenske emulzije, pripravljene z neionsko površinsko aktivno snovjo.
V določenih okoliščinah se lahko pH vrednost uporablja kot pokazatelj ionskega značaja bitumenske emulzije. Vendar ta podatek naj se potrdi s preskusom polarnosti delcev v skladu s standardom EN 1430 [1].
OPOZORILO: Pri uporabi tega dokumenta so lahko prisotni nevarni materiali, postopki in oprema. Ta dokument ne obravnava vseh varnostnih težav, ki se navezujejo na njegovo uporabo. Za vzpostavitev ustreznih varnostnih in zdravstvenih praks ter za določitev uporabnosti regulativnih omejitev pred uporabo je odgovoren uporabnik tega dokumenta.

General Information

Status
Published
Public Enquiry End Date
19-Mar-2021
Publication Date
23-Aug-2022
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
05-Aug-2022
Due Date
10-Oct-2022
Completion Date
24-Aug-2022

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Standards Content (Sample)

SLOVENSKI STANDARD
SIST EN 12850:2022
01-september-2022
Nadomešča:
SIST EN 12850:2009
Bitumen in bitumenska veziva - Določevanje pH vrednosti bitumenskih emulzij
Bitumen and bituminous binders - Determination of the pH value of bituminous emulsions
Bitumen und bitumenhaltige Bindemittel - Bestimmung des pH-Wertes von
Bitumenemulsionen
Bitumes et liants bitumineux - Détermination du pH des émulsions bitumineuses
Ta slovenski standard je istoveten z: EN 12850:2022
ICS:
75.140 Voski, bitumni in drugi naftni Waxes, bituminous materials
proizvodi and other petroleum products
91.100.50 Veziva. Tesnilni materiali Binders. Sealing materials
SIST EN 12850:2022 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
SIST EN 12850:2022

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SIST EN 12850:2022


EN 12850
EUROPEAN STANDARD

NORME EUROPÉENNE

July 2022
EUROPÄISCHE NORM
ICS 75.140; 91.100.50 Supersedes EN 12850:2009
English Version

Bitumen and bituminous binders - Determination of the
pH value of bituminous emulsions
Bitumes et liants bitumineux - Détermination du pH Bitumen und bitumenhaltige Bindemittel -
des émulsions bitumineuses Bestimmung des pH-Wertes von Bitumenemulsionen
This European Standard was approved by CEN on 13 June 2022.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2022 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 12850:2022 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------
SIST EN 12850:2022
EN 12850:2022 (E)
Contents Page
European foreword . 3
1 Scope . 4
2 Normative references . 4
3 Terms and definitions . 4
4 Principle . 4
5 Reagents and materials . 4
6 Apparatus . 5
7 Sampling . 5
8 Procedure. 5
9 Expression of results . 6
10 Precision . 6
10.1 General . 6
10.2 Repeatability . 6
10.3 Reproducibility . 6
11 Test report . 6
Bibliography . 7

2

---------------------- Page: 4 ----------------------
SIST EN 12850:2022
EN 12850:2022 (E)
European foreword
This document (EN 12850:2022) has been prepared by Technical Committee CEN/TC 336 “Bituminous
binders”, the secretariat of which is held by AFNOR.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by January 2023, and conflicting national standards shall
be withdrawn at the latest by January 2023.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN 12850:2009.
The main technical changes are:
— the number of required standard buffer solutions is at least two which bracket the expected pH value
to be measured (5.4 and Clause 8);
— the requirement to use certified buffer solutions and to follow manufacturer’s instructions for their
verification and storage conditions (5.4);
— the requirement to calibrate according to the manufacturer’s instructions for the used pH meter and
with the obligation to test pH = 7 and to frame the expected pH value (Clause 8);
— the requirement that the calibration temperatures are compliant with those indicated for each buffer
solution (Clause 8).
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland,
Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Polan
...

SLOVENSKI STANDARD
oSIST prEN 12850:2021
01-marec-2021
Bitumen in bitumenska veziva - Določevanje pH vrednosti bitumenskih emulzij
Bitumen and bituminous binders - Determination of the pH value of bituminous emulsions
Bitumen und bitumenhaltige Bindemittel - Bestimmung des pH-Wertes von
Bitumenemulsionen
Bitumes et liants bitumineux - Détermination du pH des émulsions bitumineuses
Ta slovenski standard je istoveten z: prEN 12850
ICS:
75.140 Voski, bitumni in drugi naftni Waxes, bituminous materials
proizvodi and other petroleum products
91.100.50 Veziva. Tesnilni materiali Binders. Sealing materials
oSIST prEN 12850:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
oSIST prEN 12850:2021

---------------------- Page: 2 ----------------------
oSIST prEN 12850:2021


DRAFT
EUROPEAN STANDARD
prEN 12850
NORME EUROPÉENNE

EUROPÄISCHE NORM

January 2021
ICS 75.140; 91.100.50 Will supersede EN 12850:2009
English Version

Bitumen and bituminous binders - Determination of the
pH value of bituminous emulsions
Bitumes et liants bitumineux - Détermination du pH Bitumen und bitumenhaltige Bindemittel -
des émulsions bitumineuses Bestimmung des pH-Wertes von Bitumenemulsionen
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 336.

If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.


EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 12850:2021 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------
oSIST prEN 12850:2021
prEN 12850:2021 (E)
Contents Page
European foreword . 3
1 Scope . 4
2 Normative references . 4
3 Terms and definitions . 4
4 Principle . 4
5 Reagents and materials . 4
6 Apparatus . 5
7 Sampling . 5
8 Procedure. 5
9 Expression of results . 6
10 Precision . 6
10.1 General . 6
10.2 Repeatability . 6
10.3 Reproducibility . 6
11 Test report . 6
Bibliography . 7
2

---------------------- Page: 4 ----------------------
oSIST prEN 12850:2021
prEN 12850:2021 (E)
European foreword
This document (prEN 12850:2021) has been prepared by Technical Committee CEN/TC 336 “Bituminous
binders”, the secretariat of which is held by AFNOR.
This document is currently submitted to the CEN Enquiry.
This document will supersede EN 12850:2009.
The main technical changes are:
— the number of required standard buffer solutions is at least three and allows to frame the expected
pH value to be measured (5.4 and Clause 8);
— the requirement to use certified buffer solutions and to follow manufacturer’s instructions for their
verification and storage conditions (5.4);
— the requirement to calibrate according to the manufacturer’s instructions for the used pH meter and
with the obligation to test pH = 7 and to frame the expected pH value (Clause 8);
— the requirement that the calibration temperatures are compliant with those indicated for each buffer
solution (Clause 8).
3

---------------------- Page: 5 ----------------------
oSIST prEN 12850:2021
prEN 12850:2021 (E)
1 Scope
This document specifies a method for
...

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