Fertilizers - Determination of cold water insoluble nitrogen and hot water insoluble nitrogen in solid urea formaldehyde and methylene urea slow-release fertilizers and determination of the solubility of nutrient polymers in phosphate buffer solution with a pH of 7,5 at 100 °C

This document specifies a method for the determination of the cold and hot water insoluble nitrogen content in solid urea formaldehyde and methylene urea slow-release fertilizers and for the determination of the hot water soluble nitrogen content in nutrient polymers (see Component Material Category CMC 9 as specified in the Regulation (EC) No xxxx/2019 on Fertilizing Products [1]).

Düngemittel - Bestimmung von kalt- und heißwasserunlöslichem Stickstoff in festen langsam freisetzenden Harnstoff-Formaldehyd- und Methylenharnstoff-Düngemitteln sowie Bestimmung der Löslichkeit von Nährstoffpolymeren in Phosphatpufferlösung mit einem pH-Wert von 7,5 bei 100 °C

Dieses Dokument legt ein Verfahren für die Bestimmung des Gehalts an kaltwasserunlöslichem und heißwasserunlöslichem Stickstoff in festen langsam freisetzenden Harnstoff-Formaldehyd- und Methylenharnstoff-Düngemitteln und für die Bestimmung der Löslichkeit von Nährstoffpolymeren in Phosphatpufferlösung mit einem pH-Wert von 7,5 bei 100°C fest.

Engrais - Dosage de l'azote insoluble dans l'eau froide et de l'azote insoluble dans l'eau chaude dans les engrais à libération lente urée-formaldéhyde solides etméthylène-urée, et détermination de la solubilité des polymères nutritifs dans une solution tampon phosphate avec un pH de 7,5 à 100°°C

Le présent document spécifie une méthode pour la détermination de la teneur en azote insoluble dans l’eau froide et dans l’eau chaude dans les engrais à libération lente urée-formaldéhyde solides et méthylène-urée, et pour la détermination de la solubilité des polymères nutritifs dans une solution tampon de phosphate avec un pH de 7,5 à 100°C.

Gnojila - Določevanje v hladni in vroči vodi netopnega dušika, dobljenega s počasnim sproščanjem iz trdnih gnojil urea formaldehida in metilen uree, in določevanje topnosti polimernih hranil v raztopini fosfatnega pufra s pH 7,5 pri 100 °C

General Information

Status
Published
Public Enquiry End Date
01-Aug-2019
Publication Date
08-Mar-2021
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
08-Mar-2021
Due Date
13-May-2021
Completion Date
09-Mar-2021

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SLOVENSKI STANDARD
SIST-TS CEN/TS 17403:2021
01-april-2021
Gnojila - Določevanje v hladni in vroči vodi netopnega dušika, dobljenega s
počasnim sproščanjem iz trdnih gnojil urea formaldehida in metilen uree, in
določevanje topnosti polimernih hranil v raztopini fosfatnega pufra s pH 7,5 pri
100 °C

Fertilizers - Determination of cold water insoluble nitrogen and hot water insoluble

nitrogen in solid urea formaldehyde and methylene urea slow-release fertilizers and

determination of the solubility of nutrient polymers in phosphate buffer solution with a pH

of 7,5 at 100 °C

Düngemittel - Bestimmung von kalt- und heißwasserunlöslichem Stickstoff in festen

langsam freisetzenden Harnstoff-Formaldehyd- und Methylenharnstoff-Düngemitteln

sowie Bestimmung der Löslichkeit von Nährstoffpolymeren in Phosphatpufferlösung mit

einem pH-Wert von 7,5 bei 100 °C

Engrais - Dosage de l'azote insoluble dans l'eau froide et de l'azote insoluble dans l'eau

chaude dans les engrais à libération lente urée-formaldéhyde solides etméthylène-urée,

et détermination de la solubilité des polymères nutritifs dans une solution tampon

phosphate avec un pH de 7,5 à 100°°C
Ta slovenski standard je istoveten z: CEN/TS 17403:2021
ICS:
65.080 Gnojila Fertilizers
SIST-TS CEN/TS 17403:2021 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
SIST-TS CEN/TS 17403:2021
---------------------- Page: 2 ----------------------
SIST-TS CEN/TS 17403:2021
CEN/TS 17403
TECHNICAL SPECIFICATION
SPÉCIFICATION TECHNIQUE
January 2021
TECHNISCHE SPEZIFIKATION
ICS 65.080
English Version
Fertilizers - Determination of cold water insoluble
nitrogen and hot water insoluble nitrogen in solid urea
formaldehyde and methylene urea slow-release fertilizers
and determination of the solubility of nutrient polymers in
phosphate buffer solution with a pH of 7,5 at 100 °C

Engrais - Dosage de l'azote insoluble dans l'eau froide Düngemittel - Bestimmung von kalt- und

et de l'azote insoluble dans l'eau chaude dans les heißwasserunlöslichem Stickstoff in festen langsam

engrais à libération lente urée-formaldéhyde solides freisetzenden Harnstoff-Formaldehyd- und

etméthylène-urée, et détermination de la solubilité des Methylenharnstoff-Düngemitteln sowie Bestimmung

polymères nutritifs dans une solution tampon der Löslichkeit von Nährstoffpolymeren in

phosphate avec un pH de 7,5 à 100 °C Phosphatpufferlösung mit einem pH-Wert von 7,5 bei

100 °C

This Technical Specification (CEN/TS) was approved by CEN on 30 November 2020 for provisional application.

The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to

submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.

CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS

available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in

parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,

Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and

United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 17403:2021 E

worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
SIST-TS CEN/TS 17403:2021
CEN/TS 17403:2021 (E)
Contents Page

European foreword ....................................................................................................................................................... 3

Introduction .................................................................................................................................................................... 4

1 Scope .................................................................................................................................................................... 5

2 Normative references .................................................................................................................................... 5

3 Terms and definitions ................................................................................................................................... 5

4 Sampling and sample preparation ............................................................................................................ 7

4.1 Sampling of products in bags and in bulk .............................................................................................. 7

4.2 Reduction of samples ..................................................................................................................................... 7

5 Determination of the mass fraction of CWIN ......................................................................................... 7

5.1 Principle ............................................................................................................................................................. 7

5.2 Reagents ............................................................................................................................................................. 7

5.3 Apparatus ........................................................................................................................................................... 7

5.4 Procedure........................................................................................................................................................... 7

5.5 Calculation and expression of results ...................................................................................................... 8

6 Determination of the mass fraction of HWIN ........................................................................................ 8

6.1 Principle ............................................................................................................................................................. 8

6.2 Reagents ............................................................................................................................................................. 8

6.3 Apparatus ........................................................................................................................................................... 8

6.4 Procedure........................................................................................................................................................... 8

6.5 Calculation and expression of results ...................................................................................................... 9

7 Determination of the solubility of nutrient polymers in phosphate buffer solution

with a pH of 7,5 at 100 °C .............................................................................................................................. 9

8 Test report ......................................................................................................................................................... 9

Bibliography ................................................................................................................................................................. 11

---------------------- Page: 4 ----------------------
SIST-TS CEN/TS 17403:2021
CEN/TS 17403:2021 (E)
European foreword

This document (CEN/TS 17403:2021) has been prepared by Technical Committee CEN/TC 260

“Fertilizers and liming materials”, the secretariat of which is held by DIN.

Attention is drawn to the possibility that some of the elements of this document may be the subject of

patent rights. CEN shall not be held responsible for identifying any or all such patent rights.

According to the CEN/CENELEC Internal Regulations, the national standards organisations of the

following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria,

Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,

Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of

North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United

Kingdom.
---------------------- Page: 5 ----------------------
SIST-TS CEN/TS 17403:2021
CEN/TS 17403:2021 (E)
Introduction

Solid urea formaldehyde and methylene urea slow-release fertilizers are non-coated and chemically

synthesized nitrogen fertilizers with slow-release effect. In 1924, the first slow-release fertilizer patent

in the world was issued to urea formaldehyde (UF) and in 1955, UF was put into commercial production

as the oldest slow-release fertilizer.

WARNING — Users of this document should be familiar with normal laboratory practice. This document

does not purport to address all of the safety issues, if any, associated with its use. It is the responsibility

of the user to establish appropriate health and safety practices and to ensure compliance with any

national regulatory conditions.

IMPORTANT — It is absolutely essential that tests conducted according to this document are carried out

by suitably trained staff.
---------------------- Page: 6 ----------------------
SIST-TS CEN/TS 17403:2021
CEN/TS 17403:2021 (E)
1 Scope

This document specifies a method for the determination of the cold and hot water insoluble nitrogen

content in solid urea formaldehyde and methylene urea slow-release fertilizers and for the determination

of the solubility of nutrient polymers in a phosphate buffer solution with a pH of 7,5 at 100 °C.

2 Normative references

The following documents are referred to in the text in such a way that some or all of their content

constitutes requirements of this document. For dated references, only the edition cited applies. For

undated references, the latest edition of the referenced document (including any amendments) applies.

EN 1482-2, Fertilizers and liming materials - Sampling and sample preparation - Part 2: Sample

preparation

EN 12944-1, Fertilizers and liming materials and soil improvers - Vocabulary - Part 1: General terms

EN 12944-2, Fertilizers and liming materials and soil improvers - Vocabulary - Part 2: Terms relating to

fertilizers

ISO 5315, Fertilizers — Determination of total nitrogen content — Titrimetric method after distillation

3 Terms and definitions

For the purposes of this document, the terms and definitions given in EN 12944-1 and EN 12944-2 and

the following apply.
ISO and IEC maintain terminological databases for use
...

SLOVENSKI STANDARD
kSIST-TS FprCEN/TS 17403:2019
01-julij-2019
Gnojila - Določevanje v hladni in vroči vodi netopnega dušika, dobljenega s
počasnim sproščanjem iz trdnih gnojil urea formaldehida in metilen uree in iz
polimerov hranil

Fertilizers - Determination of cold water insoluble nitrogen and hot water insoluble

nitrogen in solid urea formaldehyde and methylene urea slow-release fertilizers and in

nutrient polymers

Düngemittel - Bestimmung von kalt- und heißwasserunlöslichem Stickstoff in festen

langsam freisetzenden Harnstoff-Formaldehyden und Methylenharnstoff sowie in
Nährstoffpolymeren

Engrais - Dosage de l’azote insoluble dans l’eau froide et de l’azote insoluble dans l’eau

chaude dans les engrais à libération lente urée formaldéhyde solide et méthylène-urée

et dans les polymères nutritif
Ta slovenski standard je istoveten z: FprCEN/TS 17403
ICS:
65.080 Gnojila Fertilizers
kSIST-TS FprCEN/TS 17403:2019 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
kSIST-TS FprCEN/TS 17403:2019
---------------------- Page: 2 ----------------------
kSIST-TS FprCEN/TS 17403:2019
FINAL DRAFT
TECHNICAL SPECIFICATION
FprCEN/TS 17403
SPÉCIFICATION TECHNIQUE
TECHNISCHE SPEZIFIKATION
May 2019
ICS 61.080
English Version
Fertilizers - Determination of cold water insoluble
nitrogen and hot water insoluble nitrogen in solid urea
formaldehyde and methylene urea slow-release fertilizers
and in nutrient polymers

Engrais - Dosage de l'azote insoluble dans l'eau froide Düngemittel - Bestimmung von kalt- und

et de l'azote insoluble dans l'eau chaude dans les heißwasserunlöslichem Stickstoff in festen langsam

engrais à libération lente urée formaldéhyde solide et freisetzenden Harnstoff-Formaldehyden und

méthylène-urée et dans les polymères nutritif Methylenharnstoff sowie in Nährstoffpolymeren

This draft Technical Specification is submitted to CEN members for Vote. It has been drawn up by the Technical Committee

CEN/TC 260.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,

Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,

Turkey and United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are

aware and to provide supporting documentation.

Warning : This document is not a Technical Specification. It is distributed for review and comments. It is subject to change

without notice and shall not be referred to as a Technical Specification.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. FprCEN/TS 17403:2019 E

worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
kSIST-TS FprCEN/TS 17403:2019
FprCEN/TS 17403:2019 (E)
Contents Page

European foreword ....................................................................................................................................................... 3

Introduction .................................................................................................................................................................... 4

1 Scope .................................................................................................................................................................... 5

2 Normative references .................................................................................................................................... 5

3 Terms and definitions ................................................................................................................................... 5

4 Determination of the mass fraction of CWIN ......................................................................................... 7

4.1 Principle ............................................................................................................................................................. 7

4.2 Reagents ............................................................................................................................................................. 7

4.3 Apparatus ........................................................................................................................................................... 7

4.4 Procedure........................................................................................................................................................... 7

4.5 Calculation and expression of results ...................................................................................................... 8

5 Determination of the mass fraction of HWIN ........................................................................................ 8

5.1 Principle ............................................................................................................................................................. 8

5.2 Reagents ............................................................................................................................................................. 8

5.3 Apparatus ........................................................................................................................................................... 8

5.4 Procedure........................................................................................................................................................... 8

5.5 Calculation and expression of results ...................................................................................................... 9

6 Sampling and sample preparation ............................................................................................................ 9

6.1 Sampling of products in bags and in bulk .............................................................................................. 9

6.2 Reduction of samples ..................................................................................................................................... 9

7 Test report ......................................................................................................................................................... 9

Bibliography ................................................................................................................................................................. 10

---------------------- Page: 4 ----------------------
kSIST-TS FprCEN/TS 17403:2019
FprCEN/TS 17403:2019 (E)
European foreword

This document (FprCEN/TS 17403:2019) has been prepared by Technical Committee CEN/TC 260

“Fertilizers and liming materials”, the secretariat of which is held by DIN.
This document is currently submitted to the Vote on TS.
---------------------- Page: 5 ----------------------
kSIST-TS FprCEN/TS 17403:2019
FprCEN/TS 17403:2019 (E)
Introduction

Solid urea formaldehyde and methylene urea slow-release fertilizers are non-coated and chemically

synthesized nitrogen fertilizers with slow-release effect. In 1924, the first slow-release fertilizer patent

in the world was issued to urea formaldehyde (UF) and in 1955, UF was put into commercial production

as the oldest slow-release fertilizer.

WARNING — Users of this document should be familiar with normal laboratory practice. This

document does not purport to address all of the safety issues, if any, associated with its use. It is the

responsibility of the user to establish appropriate health and safety practices and to ensure compliance

with any national regulatory conditions.

IMPORTANT — It is absolutely essential that tests conducted according to this document are carried

out by suitably trained staff.
---------------------- Page: 6 ----------------------
kSIST-TS FprCEN/TS 17403:2019
FprCEN/TS 17403:2019 (E)
1 Scope

This document specifies a method for the determination of the cold and hot water insoluble nitrogen

content in solid urea formaldehyde and methylene urea slow-release fertilizers and for the

determination of the hot water soluble nitrogen content in nutrient polymers (see Component Material

Category CMC 9 as specified in the Regulation (EC) No xxxx/2019 on Fertilizing Products [2]).

2 Normative references

The following documents are referred to in the text in such a way that some or all of their content

constitutes requirements of this document. For dated references, only the edition cited applies. For

undated references, the latest edition of the referenced document (including any amendments) applies.

EN 12944-1, Fertilizers and liming materials — Vocabulary — Part 1: General terms

EN 12944-2, Fertilizers and liming materials — Vocabulary — Part 2: Terms relating to fertilizers

prEN ISO 14820-2, Fertilizers and liming materials — Sampling and sample preparation — Part 2:

Sample preparation

ISO 5315, Fertilizers — Determination of total nitrogen content — Titrimetric method after distillation

ISO 19670:2017, Fertilizers and soil conditioners — Solid urea aldehyde slow release fertilizers — General

requirements
3 Terms and definitions

For the purposes of this document, the terms and definitions given in EN 12944-1 and EN 12944-2 and

the following apply.

ISO and IEC maintain terminological databases for use in standardization at the following addresses:

— IEC Electropedia: available at http://www.electropedia.org/
— ISO Online browsing platform: available at http://www.iso.org/obp
3.1
urea formaldehyde
slow-release nitrogenous fertilizer obtained by the react
...

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