ASTM D5526-12
(Test Method)Standard Test Method for Determining Anaerobic Biodegradation of Plastic Materials Under Accelerated Landfill Conditions
Standard Test Method for Determining Anaerobic Biodegradation of Plastic Materials Under Accelerated Landfill Conditions
SIGNIFICANCE AND USE
Decomposition of a plastic within a landfill involves biological processes that will affect the decomposition of other materials enclosed by, or in close proximity to, the plastic. Rapid degradation of the plastic has the ability to increase the economic feasibility of landfill-gas recovery, minimize the duration of after-care of the landfill, and make possible the recovery of the volume reduction of the waste due to biodegradation during the active life of the landfill. This procedure has been developed to permit determination of the anaerobic biodegradability of plastic products when placed in biologically active environments simulating landfill conditions.
As degradation occurs inevitably in a landfill, it is of immediate concern that the plastic materials do not produce toxic metabolites or end products under the various conditions that have the potential to occur in a landfill. The mixtures remaining after completion of the test method, containing fully or partially degraded plastic materials or extracts, can be submitted subsequently to ecotoxicity testing in order to assess the environmental hazards posed by the breakdown of plastics to varying degrees in landfills. This test method has been designed to assess biodegradation under optimum and less-than-optimum conditions.
Limitations—Because a wide variation exists in the construction and operation of landfills, and because regulatory requirements for landfills vary greatly, this procedure is not intended to simulate the environment of all landfills. However, it is expected to closely resemble the environment of a biologically active landfill. More specifically, the procedure is intended to create a standard laboratory environment that permits rapid and reproducible determination of the anaerobic biodegradability under accelerated landfill conditions, while at the same time producing reproducible mixtures of fully and partially decomposed household waste with plastic materials for ecotoxicological assessm...
SCOPE
1.1 This test method covers determination of the degree and rate of anaerobic biodegradation of plastic materials in an accelerated-landfill test environment. This test method is also designed to produce mixtures of household waste and plastic materials after different degrees of decomposition under conditions that resemble landfill conditions. The test materials are mixed with pretreated household waste and exposed to a methanogenic inoculum derived from anaerobic digesters operating only on pretreated household waste. The anaerobic decomposition occurs under dry (more than 30 % total solids) and static nonmixed conditions. The mixtures obtained after this test method can be used to assess the environmental and health risks of plastic materials that are degraded in a landfill.
1.2 This test method is designed to yield a percentage of conversion of carbon in the sample to carbon in the gaseous form under conditions that resemble landfill conditions. It is possible that this test method will not simulate all conditions found in landfills, especially biologically inactive landfills. This test method more closely resembles those types of landfills in which the gas generated is recovered or even actively promoted, or both, for example, by inoculation (codeposition of anaerobic sewage sludge and anaerobic leachate recirculation), moisture control in the landfill (leachate recirculation), and temperature control (short-term injection of oxygen and heating of recirculated leachate) (1-7).
1.3 This test method is designed to produce partially degraded mixtures of municipal solid waste and plastics that can be used to assess the ecotoxicological risks associated with the anaerobic degradation of plastics after various stages of anaerobic biodegradation in a landfill.
1.4 Claims of performance shall be limited to the numerical result obtained in the test and not be used for unqualified “biodegradable” claims. Reports shall ...
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Designation:D5526 −12
Standard Test Method for
Determining Anaerobic Biodegradation of Plastic Materials
1
Under Accelerated Landfill Conditions
This standard is issued under the fixed designation D5526; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope “biodegradable”claims.Reportsshallclearlystatethepercent-
age of net gaseous carbon generation for both the test and
1.1 Thistestmethodcoversdeterminationofthedegreeand
reference samples at the completion of the test. Furthermore,
rate of anaerobic biodegradation of plastic materials in an
results shall not be extrapolated past the actual duration of the
accelerated-landfill test environment. This test method is also
test.
designed to produce mixtures of household waste and plastic
materials after different degrees of decomposition under con- 1.5 The values stated in SI units are to be regarded as the
standard.
ditions that resemble landfill conditions. The test materials are
mixed with pretreated household waste and exposed to a
1.6 This standard does not purport to address all of the
methanogenic inoculum derived from anaerobic digesters op-
safety concerns, if any, associated with its use. It is the
erating only on pretreated household waste. The anaerobic
responsibility of the user of this standard to establish appro-
decomposition occurs under dry (more than 30% total solids)
priate safety and health practices and determine the applica-
and static nonmixed conditions. The mixtures obtained after
bility of regulatory limitations prior to use. Specific hazards
this test method can be used to assess the environmental and
statements are given in Section 8.
health risks of plastic materials that are degraded in a landfill.
NOTE 1—There is no known ISO equivalent to this standard.
1.2 This test method is designed to yield a percentage of
2. Referenced Documents
conversion of carbon in the sample to carbon in the gaseous
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2.1 ASTM Standards:
form under conditions that resemble landfill conditions. It is
possible that this test method will not simulate all conditions D618Practice for Conditioning Plastics for Testing
D883Terminology Relating to Plastics
found in landfills, especially biologically inactive landfills.
This test method more closely resembles those types of D1293Test Methods for pH of Water
landfills in which the gas generated is recovered or even D1888MethodsOfTestforParticulateandDissolvedMatter
4
actively promoted, or both, for example, by inoculation (code- in Water (Withdrawn 1989)
position of anaerobic sewage sludge and anaerobic leachate D2908Practice for Measuring Volatile Organic Matter in
recirculation), moisture control in the landfill (leachate Water by Aqueous-Injection Gas Chromatography
recirculation), and temperature control (short-term injection of D3590Test Methods for Total Kjeldahl Nitrogen in Water
2
oxygen and heating of recirculated leachate) (1-7). D4129Test Method for Total and Organic Carbon in Water
by High Temperature Oxidation and by Coulometric
1.3 This test method is designed to produce partially de-
Detection
graded mixtures of municipal solid waste and plastics that can
E260Practice for Packed Column Gas Chromatography
beusedtoassesstheecotoxicologicalrisksassociatedwiththe
E355PracticeforGasChromatographyTermsandRelation-
anaerobic degradation of plastics after various stages of an-
ships
aerobic biodegradation in a landfill.
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2.2 APHA-AWWA-WPCF Standards:
1.4 Claimsofperformanceshallbelimitedtothenumerical
2540DTotal Suspended Solids Dried at 103°–105°C
result obtained in the test and not be used for unqualified
2540EFixed and Volatile Solids Ignited at 550°C
3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
1
ThistestmethodisunderthejurisdictionofASTMCommitteeD20onPlastics contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
and is the direct responsibility of Subcommittee D20.96 on Environmentally Standards volume information, refer to the standard’s Document Summary page on
Degradable Plastics and Biobased Products. the ASTM website.
4
Current edition approved May 1, 2012. Published June 2012. Originally The last approved version of this historical standard is referenced on
ε1
approved in 1994. Last previous edition approved in 2011 as D5526–94(2011) . www.astm.org.
th
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DOI: 10.1520/D5526-12. Standard Methods for the Examination of Water and Wastewater,20 ed.,
2
Theboldfacenumbersinparenthesesrefertothelistofreferencesattheendof 1999, available from American Public Health Association, 800 I Street, NW,
this standard. Washington, D.C. 20001-3710, or http://www.st
...
This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately,ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
´1
Designation:D5526–94 (Reapproved 2011) Designation: D5526 – 12
Standard Test Method for
Determining Anaerobic Biodegradation of Plastic Materials
1
Under Accelerated Landfill Conditions
This standard is issued under the fixed designation D5526; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1
´ NOTE—Reapproved with editorial changes throughout in February 2011.
1. Scope
1.1 This test method covers determination of the degree and rate of anaerobic biodegradation of plastic materials in an
accelerated-landfill test environment. This test method is also designed to produce mixtures of household waste and plastic
materials after different degrees of decomposition under conditions that resemble landfill conditions.The test materials are mixed
with pretreated household waste and exposed to a methanogenic inoculum derived from anaerobic digesters operating only on
pretreated household waste. The anaerobic decomposition occurs under dry (more than 30% total solids) and static nonmixed
conditions. The mixtures obtained after this test method can be used to assess the environmental and health risks of plastic
materials that are degraded in a landfill.
1.2 Thistestmethodisdesignedtoyieldapercentageofconversionofcarboninthesampletocarboninthegaseousformunder
conditions that resemble landfill conditions. It is possible that this test method will not simulate all conditions found in landfills,
especially biologically inactive landfills. This test method more closely resembles those types of landfills in which the gas
generated is recovered or even actively promoted, or both, for example, by inoculation (codeposition of anaerobic sewage sludge
and anaerobic leachate recirculation), moisture control in the landfill (leachate recirculation), and temperature control (short-term
2
injection of oxygen and heating of recirculated leachate) (1-7).
1.3 This test method is designed to produce partially degraded mixtures of municipal solid waste and plastics that can be used
to assess the ecotoxicological risks associated with the anaerobic degradation of plastics after various stages of anaerobic
biodegradation in a landfill.
1.4The values stated in SI units are to be regarded as the standard.
1.5
1.4 Claims of performance shall be limited to the numerical result obtained in the test and not be used for unqualified
“biodegradable” claims. Reports shall clearly state the percentage of net gaseous carbon generation for both the test and reference
samples at the completion of the test. Furthermore, results shall not be extrapolated past the actual duration of the test.
1.5 The values stated in SI units are to be regarded as the standard.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use. Specific hazards statements are given in Section 8.
NOTE 1—There is no known ISO equivalent to this standard.
2. Referenced Documents
3
2.1 ASTM Standards:
D618 Practice for Conditioning Plastics for Testing
D883 Terminology Relating to Plastics
D1293 Test Methods for pH of Water
D1888 Methods Of Test for Particulate and Dissolved Matter in Water
D2908 Practice for Measuring Volatile Organic Matter in Water by Aqueous-Injection Gas Chromatography
D3590 Test Methods for Total Kjeldahl Nitrogen in Water
1
This test method is under the jurisdiction ofASTM Committee D20 on Plastics and is the direct responsibility of Subcommittee D20.96 on Environmentally Degradable
Plastics and Biobased Products.
Current edition approved Feb.May 1, 2011.2012. Published February 2011.June 2012. Originally approved in 1994. Last previous edition approved in 20022011 as
´1
D5526–94(2002)D5526–94(2011) . DOI: 10.1520/D5526-94R11E01. DOI: 10.1520/D5526-12.
2
The boldface numbers in parentheses refer to the list of references at the end of this standard.
3
ForreferencedASTMstandards,visittheASTMwebsite,www.astm.org,orcontactASTMCustomerServiceatservice@astm.org.For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
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