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ASTM F307-13(2020)

(Practice)

Standard Practice for Sampling Pressurized Gas for Gas Analysis

Standard Practice for Sampling Pressurized Gas for Gas Analysis

ABSTRACT
This practice describes the procedure for obtaining a sample of pressurized gas for gas analysis from a system or component. A sample pressure vessel shall be evacuated and sealed with a minimum vacuum pressure. The vessel shall then be attached to the designated pressurized sample port. The pressurized gas is allowed to enter the sample vessel until the pressure is equal to the pressure of the system or component. The pressure shall be secured and the sample vessel assigned for appropriate analysis. The apparatus shall consist of connecting lines, miscellaneous fittings, tie-downs, and a gas sample vessel.
SCOPE
1.1 This practice describes procedures for obtaining a sample of pressurized gas for gas analysis from a system or component.  
1.2 The values stated in SI units are to be regarded as the standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For hazard statement, see Section 6.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
31-Mar-2020
ICS
71.040.40 - Chemical analysis
Technical Committee
E21 - Space Simulation and Applications of Space Technology
Drafting Committee
E21.05 - Contamination
Current Stage
Ref Project

Relations

Replaces
ASTM F307-13 - Standard Practice for Sampling Pressurized Gas for Gas Analysis
Effective Date
01-Apr-2020
Refers
ASTM F310-07(2020) - Standard Practice for Sampling Cryogenic Aerospace Fluids
Effective Date
01-Apr-2020
Refers
ASTM F310-07(2012) - Standard Practice for Sampling Cryogenic Aerospace Fluids
Effective Date
01-Nov-2012
Refers
ASTM G93-03(2011) - Standard Practice for Cleaning Methods and Cleanliness Levels for Material and Equipment Used in Oxygen-Enriched Environments
Effective Date
01-Apr-2011
Refers
ASTM F310-07 - Standard Practice for Sampling Cryogenic Aerospace Fluids
Effective Date
01-Apr-2007
Refers
ASTM F310-04 - Standard Practice for Sampling Cryogenic Aerospace Fluids
Effective Date
01-Sep-2004
Refers
ASTM G93-03e1 - Standard Practice for Cleaning Methods and Cleanliness Levels for Material and Equipment Used in Oxygen-Enriched Environments
Effective Date
01-Nov-2003
Refers
ASTM F310-70(1996) - Standard Practice for Sampling Cryogenic Aerospace Fluids
Effective Date
01-Jan-2000
Refers
ASTM F310-70(2000) - Standard Practice for Sampling Cryogenic Aerospace Fluids
Effective Date
01-Jan-2000
Refers
ASTM G93-96 - Standard Practice for Cleaning Methods and Cleanliness Levels for Material and Equipment Used in Oxygen-Enriched Environments
Effective Date
10-Apr-1996
Referred By
ASTM D8098-23 - Standard Test Method for Permanent Gases in C<inf>2</inf> and C<inf>3</inf> Hydrocarbon Products by Gas Chromatography and Pulse Discharge Helium Ionization Detector
Effective Date
01-Apr-2020
Referred By
ASTM D3246-15 - Standard Test Method for Sulfur in Petroleum Gas by Oxidative Microcoulometry (Withdrawn 2024)
Effective Date
01-Apr-2020
Referred By
ASTM D6667-21 - Standard Test Method for Determination of Total Volatile Sulfur in Gaseous Hydrocarbons and Liquefied Petroleum Gases by Ultraviolet Fluorescence
Effective Date
01-Apr-2020
Referred By
ASTM D5234-92(2017) - Standard Guide for Analysis of Ethylene Product
Effective Date
01-Apr-2020
Referred By
ASTM D5507-21a - Standard Test Method for Determination of Trace Organic Impurities in Monomer Grade Vinyl Chloride by Capillary Column/Multidimensional Gas Chromatography
Effective Date
01-Apr-2020

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ASTM F307-13(2020) - Standard Practice for Sampling Pressurized Gas for Gas Analysis
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: F307 − 13 (Reapproved 2020)
Standard Practice for
Sampling Pressurized Gas for Gas Analysis
ThisstandardisissuedunderthefixeddesignationF307;thenumberimmediatelyfollowingthedesignationindicatestheyearoforiginal
adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.Asuperscript
epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope 4. Summary of Practice
1.1 This practice describes procedures for obtaining a 4.1 Evacuated Sample Vessel Procedure—A sample pres-
sample of pressurized gas for gas analysis from a system or sure vessel is evacuated and sealed with a minimum vacuum
-3
component. pressure of 10 torr. The vessel is then attached to the
designated pressurized sample port. The pressurized gas is
1.2 The values stated in SI units are to be regarded as the
allowed to enter the sample vessel until the pressure is equal to
standard.
the pressure of the system or component. The pressure is
1.3 This standard does not purport to address all of the
secured and the sample vessel assigned for appropriate analy-
safety concerns, if any, associated with its use. It is the
sis.
responsibility of the user of this standard to establish appro-
4.2 Purged Sample Vessel Procedure—The pressurized gas
priate safety, health, and environmental practices and deter-
sample port is opened to establish a low level purge.Asample
mine the applicability of regulatory limitations prior to use.
vessel with valves opened at each end is attached to the
For hazard statement, see Section 6.
pressurized sample port.The pressurized sample port is opened
1.4 This international standard was developed in accor-
and the purge pressure is increased to completely purge the
dance with internationally recognized principles on standard-
vessel prior to sample capture. The vessel valves and sample
ization established in the Decision on Principles for the
port valves are then closed and the sample vessel delivered for
Development of International Standards, Guides and Recom-
analysis.
mendations issued by the World Trade Organization Technical
Barriers to Trade (TBT) Committee.
5. Apparatus
NOTE 1—All apparatus used in the sample taking should be verified as
2. Referenced Documents
cleaned and packaged within the requirements of the allowable contami-
2.1 ASTM Standards:
nation of the system.
F310 Practice for Sampling Cryogenic Aerospace Fluids
5.1 Connecting Lines, rigid or flexible, pressure rated and
G93 Guide for Cleanliness Levels and Cleaning Methods for
identified within recognized safety codes.
Materials and Equipment Used in Oxygen-Enriched En-
5.2 Miscellaneous Fittings, as needed for sampling point
vironments
adaption.
3. Terminology
5.3 Tie-downs, suitable for sample line restraint in accord
3.1 Definitions:
with pressure, temperature, and recognized safety codes.
3.1.1 sample port—the designated point in a system or
5.4 Gas Sample Vessel, rated for the appropriate maximum
component from which a representative gas sample may be
and minimum pressure for the gas analysis method to be used.
taken.
This vessel should have valves at inlet and outlet to enable
lockup of vacuum or pressure. (See Fig. 1.)
This practice is under the jurisdiction of ASTM Committee E21 on Space
NOTE 2—The gas sample vessel capacity is selected in accord with
Simulation andApplications of Space Technology and is the direct responsibility of
desired sample volume. For evacuated vessel sampling, a recommended
Subcommittee E21.05 on Contamination. ASTM Committee D02 on Petroleum
8-L(500-in ) volume has been determined adequate to aerospace industry.
Products and Lubricants maintains a continued interest in this practice and will
Evacuated sample vessels should be helium leak tested prior to use.
make use of it in the future.
Current edition approved April 1, 2020. Published April 2020. Originally
approved in 1966. Last previous edition approved in 2013 as F307 – 13. DOI:
6. Safety Hazards
10.1520/F0307-13R20.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or 6.1 Personnel must stand clear of exiting gas.
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
6.2 Ear protection must be used when gas flow approaches
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. sonic velocity.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959.
...

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ABSTRACT
This practice describes the apparatuses needed, and the procedures for connecting, preparing, and sampling pressurized gas blow down systems and components for particulate contamination by the use an automatic particle monitor. The sensing unit of the automatic particle monitor is connected to the designated sample port which is under purge condition. The system flow rate is then adjusted to the sample flow rate requirement. Finally, all the gas passing through the sensing unit is monitored for particulate contamination until the required sample volume has been analyzed.
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1.1 This guide covers the general technique of “spiking” aqueous samples with organic analytes or components. It is intended to be applicable to a broad range of organic materials in aqueous media. Although the specific details and handling procedures required for all types of compounds are not described, this general approach is given to serve as a guideline to the analyst in accurately preparing spiked samples for subsequent analysis or comparison. Guidance is also provided to aid the analyst in calculating recoveries and interpreting results. It is the responsibility of the analyst to determine whether the methods and materials cited here are compatible with the analytes of interest.  
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5.1 Chloride present in aviation turbine fuel can originate from refinery salt drier carryover or possibly from seawater contamination (for example, product transferred by barge). Elevated chloride levels have caused corrosive and abrasive wear of aircraft fuel control systems leading to engine failure.4
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1.1 This test method covers a rapid means of determining chloride content of aviation turbine fuel. This methodology is applicable for chloride concentrations between 0 mg/L to 0.5 mg/L. This methodology will not detect chlorine originating from chlorinated organic compounds (that is, covalent bond).  
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SIGNIFICANCE AND USE
4.1 Titration techniques using KF reagent are one of the most widely used for the determination of water.  
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Note 1: Some acids, such as formic, acetic, and adipic acid, are slowly esterified. When using pyridine-free reagents, commercially available buffer solutions can be added to the sample prior to titration. With formic acid, it may be necessary to use methanol-free solvents and titrants (1).4
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5.1 This test method is useful for the determination of elemental concentrations in the range of approximately 0.1 µgg-1 to 10 percent (%) (See Table X1.1) in soda-lime glass samples (7 and 8). A standard test method can aid in the interchange of data between laboratories and in the creation and use of glass databases.  
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1.1 This test method covers a procedure for the quantitative elemental analysis of the following seventeen elements: lithium (Li), magnesium (Mg), aluminum (Al), potassium (K), calcium (Ca), iron (Fe), titanium (Ti), manganese (Mn), rubidium (Rb), strontium (Sr), zirconium (Zr), barium (Ba), lanthanum (La), cerium (Ce), neodymium (Nd), hafnium (Hf) and lead (Pb) through the use of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) for the forensic comparison of glass fragments. The potential of these elements to provide the best discrimination among different sources of soda-lime glasses has been published elsewhere (1-5).2 Silicon (Si) is also monitored for use as a normalization standard. Additional elements may be added as needed, for example, tin (Sn) can be used to monitor the orientation of float glass fragments.  
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5.1 This test method is useful in determining the extrapolated onset temperature, the peak heat flow temperature and the heat of reaction of a material. Any onset temperature determined by this test method is not valid for use as the sole information used for determination of storage or processing conditions.  
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SCOPE
1.1 This test method determines the exothermic heat of reaction of thermally reactive chemicals or chemical mixtures, using milligram specimen sizes, by differential scanning calorimetry. Such reactive materials may include thermally unstable or thermoset materials.  
1.2 This test method also determines the extrapolated onset temperature and peak heat flow temperature for the exothermic reaction.  
1.3 This test method may be performed on solids, liquids or slurries.  
1.4 The applicable temperature range of this test method is 25 °C to 600 °C.  
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.6 This standard is related to Test Method E537, but provides additional information.  
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
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Standard Test Method for On-Line Measurement of Residue After Evaporation of High-Purity Water

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5.1 Even so-called high-purity water will contain contaminants. While not always present, these contaminants may contribute one or more of the following: dissolved active ionic substances such as calcium, magnesium, sodium, potassium, manganese, ammonium, bicarbonates, sulfates, nitrates, chloride and fluoride ions, ferric and ferrous ions, and silicates; dissolved organic substances such as pesticides, herbicides, plasticizers, styrene monomers, deionization resin material; and colloidal suspensions such as silica. While this test method facilitates the monitoring of these contaminants in high-purity water, in real time, with one instrument, this test method is not capable of identifying the various sources of residue contamination or detecting dissolved gases or suspended particles.  
5.2 This test method is calibrated using weighed amounts of an artificial contaminant (potassium chloride). The density of potassium chloride is reasonably typical of contaminants found in high-purity water; however, the response of this test method is clearly based on a response to potassium chloride. The response to actual contaminants found in high-purity water may differ from the test method's calibration. This test method is not different from many other analytical test methods in this respect.  
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5.1 Organic as well as inorganic chlorine compounds can prove harmful to equipment and reactions in processes involving hydrocarbons.  
5.2 Maximum chloride levels are often specified for process streams and for hydrocarbon products.  
5.3 Organic chloride species are potentially damaging to refinery processes. Hydrochloric acid can be produced in hydrotreating or reforming reactors and this acid accumulates in condensing regions of the refinery.
SCOPE
1.1 This test method covers the determination of organic chloride in aromatic hydrocarbons, their derivatives, and related chemicals.  
1.2 This test method is applicable to samples with chloride concentrations to 25 mg/kg. The limit of detection (LOD) is 0.2 mg/kg and the limit of quantitation (LOQ) is 0.7 mg/kg. With careful analytical technique or the measurement of replicates, or both, this method can be used to successfully analyze concentrations below the LOD.
Note 1: The maximum is the highest concentration from the interlaboratory study and the LOD and LOQ were calculated from Performance Testing Program (PTP) data. See Table 1.  
1.3 This test method is preferred over Test Method D5194 for products, such as styrene, that are polymerized by the sodium biphenyl reagent.  
1.4 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.5 Organic chloride values of samples containing inorganic chlorides will be biased high due to partial recovery of inorganic species during combustion. Interference from inorganic species can be reduced by water washing the sample before analysis. This does not apply to water soluble samples.  
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see 7.3 and Section 9.  
1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D6827-02(2023)(Test Method)
Standard Test Method for Zinc Analysis of Floor Polishes and Floor Polish Polymers By Flame Atomic Absorption (A.A.)

SIGNIFICANCE AND USE
2.1 This test method is generally accepted for the preparation of floor polish and floor polish polymers for the analysis of total zinc content. Knowing the total zinc content of a floor finish or polymer can aid in determining the proper disposal method of used or unwanted product.
SCOPE
1.1 This laboratory test method covers the analysis of floor polishes and floor polish polymers for total zinc content.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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