ASTM D3193-09
(Specification)Standard Specification for Ethylbenzene
Standard Specification for Ethylbenzene
ABSTRACT
This specification covers ethylbenzene. Different tests shall be conducted in order to determine the following properties of ethylbenzene: purity, benzene content, toluene content, xylene content, cumene content, diethylbenzene content, chloride content, sulfur content, and color.
SCOPE
1.1 This specification covers ethylbenzene.
1.2 Consult current OSHA regulations, supplier's Material Safety Data Sheets for all materials, and local regulations used in this specification.
1.3 The following applies to all specified limits in this specification for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
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Designation: D3193 −09
StandardSpecification for
1
Ethylbenzene
This standard is issued under the fixed designation D3193; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* D5808 Test Method for Determining Chloride in Aromatic
Hydrocarbons and Related Chemicals by Microcoulom-
1.1 This specification covers ethylbenzene.
etry
1.2 Consult current OSHA regulations, supplier’s Material
D7183 Test Method for Determination of Total Sulfur in
Safety Data Sheets for all materials, and local regulations used
Aromatic Hydrocarbons and Related Chemicals by Ultra-
in this specification.
violet Fluorescence
1.3 The following applies to all specified limits in this E29 Practice for Using Significant Digits in Test Data to
Determine Conformance with Specifications
specification for purposes of determining conformance with
this specification, an observed value or a calculated value shall 2.2 Other Document:
OSHA Regulations, 29 CFR paragraphs 1910.1000 and
be rounded off “to the nearest unit” in the last right-hand digit
3
used in expressing the specification limit, in accordance with 1910.1200
the rounding-off method of Practice E29.
3. Properties
2. Referenced Documents
3.1 Ethylbenzene shall conform to the following require-
2
ments:
2.1 ASTM Standards:
D1209 Test Method for Color of Clear Liquids (Platinum- Property Specification ASTM
Test Method
Cobalt Scale)
D3437 Practice for Sampling and Handling Liquid Cyclic
Purity, min, weight % 99.00 D5060
Products Benzene, max, weight % 0.1 D5060
Toluene, max, weight % 0.4 D5060
D4176 Test Method for FreeWater and Particulate Contami-
Xylenes, max, weight % 0.4 D5060
nation in Distillate Fuels (Visual Inspection Procedures)
Cumene, max, weight % 0.03 D5060
Diethylbenzene, max, weight % 0.003 D5060
D5060 Test Method for Determining Impurities in High-
Chlorides, max, mg/kg 1 D5194 or D5808
Purity Ethylbenzene by Gas Chromatography
Sulfur, max, mg/kg 1 D7183
D5194 Test Method for Trace Chloride in Liquid Aromatic
Color, max, Pt-Co 10 D1209 or D5386
A
Hydrocarbons Appearance D4176
A
D5386 Test Method for Color of Liquids Using Tristimulus Clear liquid, free of sediment and haze when observed at 18.3 to 25.6°C (65 to
78°F).
Colorimetry
4. Sampling
1
This specification is under the jurisdiction of ASTM Committee D16 on
4.1 The material shall be sampled in accordance with
Aromatic Hydrocarbons and Related Chemicals and is the direct responsibility of
Practice D3437.
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D3193–96(Reapproved2003) Designation: D 3193 – 09
Standard Specification for
1
Ethylbenzene
This standard is issued under the fixed designation D 3193; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This specification covers ethylbenzene.
1.2 Consult current OSHA regulations, supplier’s Material Safety Data Sheets for all materials, and local regulations used in
this specification.
1.3 The following applies to all specified limits in this specification for purposes of determining conformance with this
specification, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used
in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
2. Referenced Documents
2
2.1 ASTM Standards:
D 1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D 3437 Practice for Sampling and Handling Liquid Cyclic Products
2
D3961Test Method for Trace Quantities of Sulfur in Liquid Aromatic Hydrocarbons by Oxidative Microcoulometry
D4045Test Method for Sulfur in Petroleum Products by Hydrogenolysis and Rateometric Colorimetry 4176 Test Method for
Free Water and Particulate Contamination in Distillate Fuels (Visual Inspection Procedures)
D 5060 Test Method for Determining Impurities in High-Purity Ethylbenzene by Gas Chromatography
D 5194 Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons
D 5386 Test Method for Color of Liquids Using Tristimulus Colorimetry
D 5808 Test Method for Determining Organic Chloride in Aromatic Hydrocarbons and Related Chemicals by Microcoulem-
2
etry Test Method for Determining Organic Chloride inAromatic Hydrocarbons and Related Chemicals by Microcoulometry
D 7183 Test Method for Determination of Total Sulfur in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet
Fluorescence
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
2.2 Other Document:
OSHA Regulations, 29 CFR,
3
OSHA Regulations, 29 CFR paragraphs 1910.1000 and 1910.1200
3. Properties
3.1 Ethylbenzene shall conform to the following requirements:
Property Specifica- ASTM Test
tion Method
Purity, min, weight % 99.00 D 5060
Benzene, max, weight % 0.1 D 5060
Toluene, max, weight % 0.4 D 5060
Xylenes, max, weight % 0.4 D 5060
Cumene, max, weight % 0.03 D 5060
1
This specification is under the jurisdiction of ASTMSTEM Committee D16 on Aromatic Hydrocarbons and Related Chemicals and is the direct responsibility of
Subcommittee D16.07 on Styrene, Ethylbenzene, and C and C Aromatic Hydrocarbons.
9 10
Current edition approved Jan. 10, 2003.
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D3193–96(Reapproved2003) Designation: D 3193 – 09
Standard Specification for
1
Ethylbenzene
This standard is issued under the fixed designation D 3193; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This specification covers ethylbenzene.
1.2 Consult current OSHA regulations, supplier’s Material Safety Data Sheets for all materials, and local regulations used in
this specification.
1.3 The following applies to all specified limits in this specification for purposes of determining conformance with this
specification, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used
in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
2. Referenced Documents
2
2.1 ASTM Standards:
D 1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D 3437 Practice for Sampling and Handling Liquid Cyclic Products
2
D3961Test Method for Trace Quantities of Sulfur in Liquid Aromatic Hydrocarbons by Oxidative Microcoulometry
D4045Test Method for Sulfur in Petroleum Products by Hydrogenolysis and Rateometric Colorimetry 4176 Test Method for
Free Water and Particulate Contamination in Distillate Fuels (Visual Inspection Procedures)
D 5060 Test Method for Determining Impurities in High-Purity Ethylbenzene by Gas Chromatography
D 5194 Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons
D 5386 Test Method for Color of Liquids Using Tristimulus Colorimetry
D 5808 Test Method for Determining Organic Chloride in Aromatic Hydrocarbons and Related Chemicals by Microcoulem-
2
etry Test Method for Determining Organic Chloride inAromatic Hydrocarbons and Related Chemicals by Microcoulometry
D 7183 Test Method for Determination of Total Sulfur in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet
Fluorescence
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
2.2 Other Document:
OSHA Regulations, 29 CFR,
3
OSHA Regulations, 29 CFR paragraphs 1910.1000 and 1910.1200
3. Properties
3.1 Ethylbenzene shall conform to the following requirements:
Property Specifica- ASTM Test
tion Method
Purity, min, weight % 99.00 D 5060
Benzene, max, weight % 0.1 D 5060
Toluene, max, weight % 0.4 D 5060
Xylenes, max, weight % 0.4 D 5060
Cumene, max, weight % 0.03 D 5060
Diethylbenzene, max, weight % 0.003 D 5060
1
This specification is under the jurisdiction of ASTMSTEM Committee D16 on Aromatic Hydrocarbons and Related Chemicals and is the direct responsibilit
...
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