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ASTM D5386-93b(2000)e1

(Test Method)

Standard Test Method for Color of Liquids Using Tristimulus Colorimetry

Standard Test Method for Color of Liquids Using Tristimulus Colorimetry

SCOPE
1.1 This test method covers an instrumental method for the CIE (Commission International de l'Eclairage) tristimulus measurement of the color of near-clear liquid samples. The measurement is converted to color ratings in the platinum-cobalt system.
1.2 This test method has been found applicable to the color measurement of clear, liquid samples, free of haze, with nominal platinum cobalt color values in the 0 to 30 range. It is applicable to nonfluorescent liquids with light absorption characteristics similar to those of the platinum cobalt color standard solutions. Test Methods D1686, D2108, and E450 deal with the visual and instrumental measurement of near-clear liquids.
1.3 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
09-Feb-2000
ICS
71.080.01 - Organic chemicals in general
Technical Committee
D16 - Aromatic, Industrial, Specialty and Related Chemicals
Drafting Committee
D16.04 - Instrumental Analysis
Current Stage
Ref Project

Relations

Replaced By
ASTM D5386-04 - Standard Test Method for Color of Liquids Using Tristimulus Colorimetry
Effective Date
01-Jan-2004
Referred By
ASTM D2378-22 - Standard Specification for Formaldehyde 50 % Grade Uninhibited and 37 % Grade Inhibited and Uninhibited
Effective Date
10-Feb-2000
Referred By
ASTM D4416-09(2023) - Standard Specification for Acrylic Acid
Effective Date
10-Feb-2000
Referred By
ASTM D1718-09(2023) - Standard Specification for Isobutyl Acetate (95 % Grade)
Effective Date
10-Feb-2000
Referred By
ASTM D3193-19 - Standard Specification for Ethylbenzene
Effective Date
10-Feb-2000
Referred By
ASTM D2916-09(2023) - Standard Specification for Isophorone
Effective Date
10-Feb-2000
Referred By
ASTM D1969-22 - Standard Specification for 2-Ethylhexanol
Effective Date
10-Feb-2000
Referred By
ASTM D2694-05(2019) - Standard Specification for Diethylene Glycol<sup>,</sup>
Effective Date
10-Feb-2000
Referred By
ASTM D330-07(2021) - Standard Specification for 2-Butoxyethanol
Effective Date
10-Feb-2000
Referred By
ASTM D740-11(2019) - Standard Specification for Methyl Ethyl Ketone<sup>,</sup>
Effective Date
10-Feb-2000
Referred By
ASTM D843-19 - Standard Specification for Nitration Grade Xylene
Effective Date
10-Feb-2000
Referred By
ASTM D2827-19 - Standard Specification for Styrene Monomer
Effective Date
10-Feb-2000
Referred By
ASTM E202-18 - Standard Test Methods for Analysis of Ethylene Glycols and Propylene Glycols
Effective Date
10-Feb-2000
Referred By
ASTM E805-22 - Standard Practice for Identification of Instrumental Methods of Color or Color-Difference Measurement of Materials
Effective Date
10-Feb-2000
Referred By
ASTM D608-05(2019) - Standard Specification for Dibutyl Phthalate
Effective Date
10-Feb-2000

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ASTM D5386-93b(2000)e1 - Standard Test Method for Color of Liquids Using Tristimulus ColorimetryASTM D5386-93b(2000)e1 - Standard Test Method for Color of Liquids Using Tristimulus Colorimetry
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ASTM D5386-93b(2000)e1 - Standard Test Method for Color of Liquids Using Tristimulus Colorimetry
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn. Contact ASTM
International (www.astm.org) for the latest information.
e1
Designation:D5386–93b (Reapproved 2000)
Standard Test Method for
Color of Liquids Using Tristimulus Colorimetry
This standard is issued under the fixed designation D 5386; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
e NOTE—Editorial changes made throughout in March 2000.
1. Scope E 179 Guide for Selection of Geometric Conditions for
Measurement of Reflectance and Transmission Properties
1.1 This test method covers an instrumental method for the
of Materials
CIE (Commission International de l’Eclairage) tristimulus
E 308 Practice for Computing the Colors of Objects by
measurement of the color of near-clear liquid samples. The
Using the CIE System
measurement is converted to color ratings in the platinum-
E 450 Method for Measurement of Color of Low-Colored
cobalt system.
Clear Liquids Using the Hunterlab Color Difference
1.2 This test method has been found applicable to the color
Meter
measurement of clear, liquid samples, free of haze, with
E 691 Practice for Conducting an Interlaboratory Study to
nominal platinum cobalt color values in the 0 to 30 range. It is
Determine the Precision of Test Methods
applicable to nonfluorescent liquids with light absorption
2.2 Other Document:
characteristics similar to those of the platinum cobalt color
OSHA Regulations, 29 CFR, paragraphs 1910.1000 and
standard solutions. Test Methods D 1686, D 2108, and E 450
1910.1200
deal with the visual and instrumental measurement of near-
clear liquids.
3. Summary of Test Method
1.3 This standard does not purport to address all of the
3.1 Color is measured by tristimulus values of light trans-
safety concerns, if any, associated with its use. It is the
mitted by a sample as percent of light transmitted by distilled
responsibility of the user of this standard to establish appro-
water. Convert the measured tristimulus values by appropriate
priate safety and health practices and determine the applica-
equations to the platinum-cobalt scale.
bility of regulatory limitations prior to use.
4. Significance and Use
2. Referenced Documents
4.1 The major objective of the visual platinum-cobalt (Pt-
2.1 ASTM Standards:
2 Co) method of color measurement, as defined in Test Method
D 1193 Specification for Reagent Water
D 1209, is to rate specific materials for yellowness. This
D 1209 Test Method for Color of Clear Liquids (Platinum-
3 yellowness is frequently the result of the undesirable tendency
Cobalt Scale)
of liquid hydrocarbons to absorb blue light due to contamina-
D 1686 Test Method for Color of SolidAromatic Hydrocar-
tion in processing, storage or shipping.
bons and Related Materials in the Molten State (Platinum-
3 4.2 Clear liquids can be rated for light absorbing yellowish
Cobalt Scale)
4 or brownish contaminants, using scales that simulate the
D 1925 Test Method for Yellowness Index of Plastics
long-established visual-comparison method just cited. Where
D 2108 Test Method for Color of Halogenated Organic
5 needed, dimensions of color can be reported to identify any
Solvents and Their Admixtures (Platinum-Cobalt Scale)
pinkness or greenness (one dimension), or grayness.
D 3437 Practice for Sampling and Handling Liquid Cyclic
Products
5. Apparatus
5.1 Instrument, with the following provisions:
5.1.1 Instrument Sensor, shall provide a beam for illuminat-
This test method is under the jurisdiction of ASTM Committee D16 on
ing the sample cell in transmission. The instrument shall be
Aromatic Hydrocarbons and Related Chemicals and is the direct responsibility of
Subcommittee D16.04 on Instrumental Analysis.
Current edition approved Sept. 15 and Oct. 15, 1993. Published December 1993.
Originally published as D 5386 – 93. Last previous edition D 5386 – 93. Annual Book of ASTM Standards, Vol 06.01.
2 7
Annual Book of ASTM Standards, Vol 11.01. Discontinued 1993; see 1992 Annual Book of ASTM Standards, Vol. 15.05.
3 8
Annual Book of ASTM Standards, Vol 06.04. Annual Book of ASTM Standards, Vol 14.02.
4 9
Annual Book of ASTM Standards, Vol 08.01. Available from the Superintendent of Documents, U.S. Government Printing
Annual Book of ASTM Standards, Vol 15.05. Office, Washington, DC 20402.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn. Contact ASTM
International (www.astm.org) for the latest information.
e1
D5386–93b (2000)
TABLE 2 Platinum-Cobalt Colar Standards
capable of converting light measured in total transmission
through the sample cell to CIE X Y Z tristimulus color values Color Standard Color Standard
Stock Solution, mL Stock Solution mL
Number Number
for the measurement conditions of CIE illuminant C and the
1 0.20 10 2.00
CIE 1931 2 degree standard observer as described in Guide
2 0.40 11 2.20
E 179 and Practice E 308.
3 0.60 12 2.40
5.1.2 The CIE X Y Z tristimulus color values shall be
4 0.80 13 2.60
5 1.00 14 2.80
convertible to the instrumental yellowness index (Y1) defined
6 1.20 15 3.00
by Test Method D 1925 and Practice E 308. A correlation
7 1.40 20 4.00
between measured yellowness index (YI) (Test Method
8 1.60 25 5.00
9 1.80 30 6.00
D 1925) values and the Pt-Co standard solutions shall be used
to yield an equivalent instrumental Pt-Co rating for liquid
hydrocarbon samples.
5.1.3 Sa
...

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1.1 This test method covers the procedure for distillation of heavy hydrocarbon mixtures having initial boiling points greater than 150 °C (300 °F), such as heavy crude oils, petroleum distillates, residues, and synthetic mixtures. It employs a potstill with a low pressure drop entrainment separator operated under total takeoff conditions. Distillation conditions and equipment performance criteria are specified and typical apparatus is illustrated.  
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1.6 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warnings, see 6.5.4.2, 6.5.6.3, 6.9.3, 9.5, 9.7, and A2.3.1.3.  
1.8 WARNING—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use Caution when handling mercury and mercury-containing...

  • Standard
    18 pages
    English language
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  • Standard
    18 pages
    English language
    sale 15% off