Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Paint Using Small Environmental Chambers

SIGNIFICANCE AND USE
5.1 Latex and alkyd paints are used as coatings for walls, wooden trim, and furnishings in occupied buildings. Paint may be applied to large surface areas and may be applied repeatedly during the lifetime of a building. VOCs are emitted from paint after application to surfaces.  
5.2 There is a need for data on emissions from paint. The data can be used to compare emissions from different products. The data may be used to assist manufacturers in reducing or eliminating VOC emissions from their products. The data may be used to predict concentrations of VOCs in a room or building when used with appropriate indoor air quality models.  
5.3 Standard test practices and procedures are needed for the comparison of emissions data from different laboratories.
SCOPE
1.1 This practice provides procedures for preparing test samples of alkyd primer, alkyd paint, latex primer, or latex paint applied to building materials such as gypsum wallboard, wood, or engineered wood products and procedures for sampling volatile organic compounds (VOCs) emitted from those test samples. Emissions are sampled from small environmental chambers operated under controlled conditions.  
1.2 This practice describes procedures for preparation of test specimens by application of primer or paint to common building materials. Use of the procedures described in this practice for tests with other application methods or substrates may affect the results and not meet the criteria recommended in the practice.  
1.3 This practice describes procedures for collection of VOCs on sorbent tubes and carbonyl compounds on silica gel treated with 2,4-dinitrophenylhydrazine (DNPH) that require analytical methods for measurement of individual organic compound concentrations. This practice does not describe the detailed procedures of analytical methods, but refers to published methods for these analyses.  
1.4 This practice describes procedures for testing and sampling VOCs emitted from paint under controlled conditions. The test conditions, when combined with analytical data, can be used to calculate emission rates. This practice does not recommend a method for the calculations.  
1.5 Values stated in the International System of Units (SI) are to be regarded as the standard.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
31-Mar-2013
Technical Committee
Drafting Committee
Current Stage
Ref Project

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ASTM D6803-13 - Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Paint Using Small Environmental Chambers
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D6803 − 13
Standard Practice for
Testing and Sampling of Volatile Organic Compounds
(Including Carbonyl Compounds) Emitted from Paint Using
1
Small Environmental Chambers
This standard is issued under the fixed designation D6803; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 1.7 This international standard was developed in accor-
dance with internationally recognized principles on standard-
1.1 This practice provides procedures for preparing test
ization established in the Decision on Principles for the
samples of alkyd primer, alkyd paint, latex primer, or latex
Development of International Standards, Guides and Recom-
paint applied to building materials such as gypsum wallboard,
mendations issued by the World Trade Organization Technical
wood, or engineered wood products and procedures for sam-
Barriers to Trade (TBT) Committee.
pling volatile organic compounds (VOCs) emitted from those
test samples. Emissions are sampled from small environmental
2. Referenced Documents
chambers operated under controlled conditions.
2
2.1 ASTM Standards:
1.2 This practice describes procedures for preparation of
D16 TerminologyforPaint,RelatedCoatings,Materials,and
test specimens by application of primer or paint to common
Applications
building materials. Use of the procedures described in this
D1005 Test Method for Measurement of Dry-Film Thick-
practice for tests with other application methods or substrates
ness of Organic Coatings Using Micrometers
mayaffecttheresultsandnotmeetthecriteriarecommendedin
D1212 Test Methods for Measurement of Wet Film Thick-
the practice.
ness of Organic Coatings
D1356 Terminology Relating to Sampling and Analysis of
1.3 This practice describes procedures for collection of
Atmospheres
VOCs on sorbent tubes and carbonyl compounds on silica gel
D3686 Practice for Sampling Atmospheres to Collect Or-
treated with 2,4-dinitrophenylhydrazine (DNPH) that require
ganic Compound Vapors (Activated Charcoal Tube Ad-
analytical methods for measurement of individual organic
compound concentrations. This practice does not describe the sorption Method)
D3687 Practice for Analysis of Organic Compound Vapors
detailed procedures of analytical methods, but refers to pub-
lished methods for these analyses. Collected by the Activated Charcoal Tube Adsorption
Method
1.4 This practice describes procedures for testing and sam-
D5116 Guide for Small-Scale Environmental Chamber De-
pling VOCs emitted from paint under controlled conditions.
terminations of Organic Emissions from Indoor Materials/
The test conditions, when combined with analytical data, can
Products
be used to calculate emission rates. This practice does not
D5197 Test Method for Determination of Formaldehyde and
recommend a method for the calculations.
Other Carbonyl Compounds inAir (Active Sampler Meth-
1.5 Values stated in the International System of Units (SI)
odology)
are to be regarded as the standard.
D5466 Test Method for Determination of Volatile Organic
Compounds in Atmospheres (Canister Sampling Method-
1.6 This standard does not purport to address all of the
ology)
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro- D6196 Practice for Choosing Sorbents, Sampling Param-
eters and Thermal Desorption Analytical Conditions for
priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use. Monitoring Volatile Organic Chemicals in Air
D6345 Guide for Selection of Methods for Active, Integra-
tive Sampling of Volatile Organic Compounds in Air
1
This practice is under the jurisdiction ofASTM Committee D22 on Air Quality
2
and is the direct responsibility of Subcommittee D22.05 on Indoor Air. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved April 1, 2013. Published April 2013. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 2002. Last previous edition approved in 2007 as D6803 – 02 (2007). Standards volume information, refer to the standard’s Document Summary page on
DOI: 10.1520/D6803-13. the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D6803 − 13
D6886 Test Method for Determination of theWeight Percent environmental chambers are operated at designated conditions
Individual Volatile Organic Compounds in Waterborne of airflow rate, temperature, and relative humid
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D6803 − 02 (Reapproved 2007) D6803 − 13
Standard Practice for
Testing and Sampling of Volatile Organic Compounds
(Including Carbonyl Compounds) Emitted from Paint Using
1
Small Environmental Chambers
This standard is issued under the fixed designation D6803; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This practice provides procedures for preparing test samples of alkyd primer, alkyd paint, latex primer, or latex paint applied
to building materials such as gypsum wallboard, wood, or engineered wood products and procedures for sampling volatile organic
compounds (VOCs) emitted from those test samples. Emissions are sampled from small environmental chambers operated under
controlled conditions.
1.2 This practice describes procedures for preparation of test specimens by application of primer or paint to common building
materials. Use of the procedures described in this practice for tests with other application methods or substrates may affect the
results and not meet the criteria recommended in the practice.
1.3 This practice describes procedures for collection of VOCs on sorbent tubes and carbonyl compounds on silica gel treated
with 2,4-dinitrophenylhydrazine (DNPH) that require analytical methods for measurement of individual organic compound
concentrations. This practice does not describe the detailed procedures of analytical methods, but refers to published methods for
these analyses.
1.4 This practice describes procedures for testing and sampling VOCs emitted from paint under controlled conditions. The test
conditions, when combined with analytical data, can be used to calculate emission rates. This practice does not recommend a
method for the calculations.
1.5 Values stated in the International System of Units (SI) are to be regarded as the standard.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
D16 Terminology for Paint, Related Coatings, Materials, and Applications
D1005 Test Method for Measurement of Dry-Film Thickness of Organic Coatings Using Micrometers
D1212 Test Methods for Measurement of Wet Film Thickness of Organic Coatings
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
D1914 Practice for Conversion Units and Factors Relating to Sampling and Analysis of Atmospheres
D3686 Practice for Sampling Atmospheres to Collect Organic Compound Vapors (Activated Charcoal Tube Adsorption Method)
D3687 Practice for Analysis of Organic Compound Vapors Collected by the Activated Charcoal Tube Adsorption Method
D5116 Guide for Small-Scale Environmental Chamber Determinations of Organic Emissions from Indoor Materials/Products
D5197 Test Method for Determination of Formaldehyde and Other Carbonyl Compounds in Air (Active Sampler Methodology)
D5466 Test Method for Determination of Volatile Organic Chemicals in Atmospheres (Canister Sampling Methodology)
D6196 Practice for Selection of Sorbents, Sampling, and Thermal Desorption Analysis Procedures for Volatile Organic
Compounds in Air
D6345 Guide for Selection of Methods for Active, Integrative Sampling of Volatile Organic Compounds in Air
1
This practice is under the jurisdiction of ASTM Committee D22 on Air Quality and is the direct responsibility of Subcommittee D22.05 on Indoor Air.
Current edition approved April 1, 2007April 1, 2013. Published June 2007April 2013. Originally approved in 2002. Last previous edition approved in 20022007 as
D6803 - 02.D6803 - 02(2007). DOI: 10.1520/D6803-02R07.10.1520/D6803-13.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D6803 − 13
E741D6886 Test Method for Determining Air Change in a Single Zone by Means of a Tracer Gas DilutionDetermination of
...

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