Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials

SIGNIFICANCE AND USE
Definitions given in Section 4 are intended for use in all standards on analytical chemistry for metals, ores, and related materials. The definitions should be used uniformly and consistently. The purpose of this terminology is to promote clear understanding and interpretation of the standards in which definitions are used.
SCOPE
1.1 This is a compilation of terms commonly used in analytical chemistry for metals, ores, and related materials. Terms that are generally understood or defined adequately in other readily available sources are either not included or their sources are identified.
1.2 A definition is a single sentence with additional information included in a discussion.
1.3 Definitions identical to those published by another standards organization or ASTM committee are identified with the name of the organization or the identifying document and ASTM committee.
1.4 Definitions specific to a particular field (such as emission spectrometry) are identified with an italicized introductory phrase.

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Publication Date
14-Sep-2011
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: E135 − 11b
StandardTerminology Relating to
Analytical Chemistry for Metals, Ores, and Related
1
Materials
This standard is issued under the fixed designation E135; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 3. Significance and Use
1.1 This is a compilation of terms commonly used in
3.1 Definitions given in Section 4 are intended for use in all
analytical chemistry for metals, ores, and related materials.
standards on analytical chemistry for metals, ores, and related
Terms that are generally understood or defined adequately in
materials. The definitions should be used uniformly and
other readily available sources are either not included or their
consistently. The purpose of this terminology is to promote
sources are identified.
clear understanding and interpretation of the standards in
which definitions are used.
1.2 A definition is a single sentence with additional infor-
mation included in a discussion.
4. Terminology Definitions
1.3 Definitions identical to those published by another
standards organization orASTM committee are identified with
aim interlaboratory uncertainty, n—the maximum deviation
the name of the organization or the identifying document and
(95 % confidence) to be allowed in the design of the total
ASTM committee.
interlaboratory uncertainty of a test method, beginning with
the preparation of a homogeneous sample and ending with a
1.4 Definitions specific to a particular field (such as emis-
final report value to the client. E2437
sion spectrometry) are identified with an italicized introductory
phrase.
aim uncertainty budget, n—during the development of a
standard performance-based test method, the target alloca-
2. Referenced Documents
tion of interlaboratory measurement uncertainty among spe-
2
2.1 ASTM Standards: cific components of a measurement process that contribute
E1914 Practice for Use of Terms Relating to the Develop-
significantly to the overall deviation. The target allocation is
ment and Evaluation of Methods for Chemical Analysis made by the task group and serves as guidance for interlabo-
E2437 Practice for Designing and Validating Performance-
ratory test participants during method testing. E2437
Based Test Methods for theAnalysis of Metals, Ores, and
analytical curve—see calibration curve.
Related Materials
E2438 Practice for Implementing Standard Performance
analyte, n—in methods of chemical analysis, the constituent
Based Test Methods for theAnalysis of Metals, Ores, and
determined by a chemical measurement process. E1914
Related Materials
analytical gap, n—in atomic emission spectrometry,theregion
3
2.2 ISO Standard:
betweentwoelectrodesinwhichthespecimenisexcitedand
ISO Guide 30 Terms and Definitions Used in Connection
from which radiant energy is used for analysis.
with Reference Materials
analytical line, n—in atomic spectrometry, the particular
wavelengthofelectromagneticradiationusedindetermining
1
This terminology is under the jurisdiction of ASTM Committee E01 on the presence or concentration of an element.
Analytical Chemistry for Metals, Ores, and Related Materials and is the direct
responsibility of Subcommittee E01.23 on Terminology and Editorial.
arc, condensed—see discharge, triggered capacitor.
Current edition approved Sept. 15, 2011. Published March 2012. Originally
noncapacitive ac arc, n—in atomic emission spectrometry,a
approved in 1958. Last previous edition approved in 2011 as E135 – 11a. DOI:
10.1520/E0135-11B.
series of separate electrical discharges, individually self-
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
initiating or initiated separately by another means, in which
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
each current pulse has a polarity that is reversed from the
Standards volume information, refer to the standard’s Document Summary page on
previous one.
the ASTM website.
3
Available fromAmerican National Standards Institute (ANSI), 25 W. 43rd St.,
4th Floor, New York, NY 10036, http://www.ansi.org. arc line—not recommended, see atom line.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
E135 − 11b
atom line, n—in atomic emission spectrometry, a spectral line given measurement procedure, that can be distinguished
resulting from radiation emitted during electron transition as from the background signal at a specified confidence level.
an excited atom returns to a lower energy level. E1914
DISCUSSION—The detection limit may be design
...

This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:E135–11a Designation:E135–11b
Standard Terminology Relating to
Analytical Chemistry for Metals, Ores, and Related
1
Materials
This standard is issued under the fixed designation E135; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This is a compilation of terms commonly used in analytical chemistry for metals, ores, and related materials.Terms that are
generally understood or defined adequately in other readily available sources are either not included or their sources are identified.
1.2 A definition is a single sentence with additional information included in a discussion.
1.3 Definitions identical to those published by another standards organization orASTM committee are identified with the name
of the organization or the identifying document and ASTM committee.
1.4 Definitions specific to a particular field (such as emission spectrometry) are identified with an italicized introductory phrase.
2. Referenced Documents
2
2.1 ASTM Standards:
E1914 Practice for Use of Terms Relating to the Development and Evaluation of Methods for Chemical Analysis
E2437 Practice for Designing and Validating Performance-Based Test Methods for the Analysis of Metals, Ores, and Related
Materials
E2438 Practice for Implementing Standard Performance Based Test Methods for the Analysis of Metals, Ores, and Related
Materials
1
This terminology is under the jurisdiction ofASTM Committee E01 onAnalytical Chemistry for Metals, Ores, and Related Materials and is the direct responsibility of
Subcommittee E01.23 on Terminology and Editorial.
Current edition approved JuneSept. 15, 2011. Published August 2011.March 2012. Originally approved in 1958. Last previous edition approved in 2011 as E135 – 11a.
DOI: 10.1520/E0135-11AB.
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
E135–11b
3
2.2 ISO Standard:
ISO Guide 30 Terms and Definitions Used in Connection with Reference Materials
3. Significance and Use
3.1 Definitions given in Section 4 are intended for use in all standards on analytical chemistry for metals, ores, and related
materials. The definitions should be used uniformly and consistently. The purpose of this terminology is to promote clear
understanding and interpretation of the standards in which definitions are used.
4. Terminology Definitions
aim interlaboratory uncertainty, n—the maximum deviation (95 % confidence) to be allowed in the design of the total
interlaboratory uncertainty of a test method, beginning with the preparation of a homogeneous sample and ending with a final
report value to the client. E2437
aim uncertainty budget, n—during the development of a standard performance-based test method, the target allocation of
interlaboratory measurement uncertainty among specific components of a measurement process that contribute significantly to
the overall deviation. The target allocation is made by the task group and serves as guidance for interlaboratory test participants
during method testing. E2437
analytical curve—see calibration curve.
analyte, n—in methods of chemical analysis, the constituent determined by a chemical measurement process. E1914
analytical gap, n—in atomic emission spectrometry, the region between two electrodes in which the specimen is excited and from
which radiant energy is used for analysis.
analytical line, n—in atomic spectrometry, the particular wavelength of electromagnetic radiation used in determining the
presence or concentration of an element.
arc, condensed—see discharge, triggered capacitor.
continuous dc arc, n—a self-maintaining dc discharge.
noncapacitive ac arc, n—in atomic emission spectrometry, a series of separate electrical discharges, individually self-initiating or
initiated separately by another means, in which each current pulse has a polarity that is reversed from the previous one.
arc line—not recommended, see atom line.
atom line, n—in atomic emission spectrometry, a spectral line resulting from radiation emitted during
...

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