ASTM D5359-98(2004)
(Specification)Standard Specification for Glass Cullet Recovered from Waste for Use in Manufacture of Glass Fiber
Standard Specification for Glass Cullet Recovered from Waste for Use in Manufacture of Glass Fiber
ABSTRACT
This specification describes glass cullet recovered from municipal waste destined for disposal, but intended for the manufacture of glass fiber for use in insulation-type products. The glass cullet shall primarily be soda-lime bottle glass and shall be one of three grades depending upon the total usage rate requirement of the user. The three grades shall satisfy the specified chemical composition, color mix, contamination, and particle size requirements.
SCOPE
1.1 This specification describes glass cullet recovered from municipal waste destined for disposal. The recovered cullet is intended for use in the manufacture of glass fiber used for insulation-type products.
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Standards Content (Sample)
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Designation: D5359 – 98 (Reapproved 2004)
Standard Specification for
Glass Cullet Recovered from Waste for Use in Manufacture
of Glass Fiber
This standard is issued under the fixed designation D5359; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
TABLE 1 Chemical Composition
1. Scope
Grade 1 2 3
1.1 This specification describes glass cullet recovered from
Use Range 0 to5%inbatch 5to15%inbatch >15%inbatch
municipal waste destined for disposal. The recovered cullet is
intended for use in the manufacture of glass fiber used for
Oxide Weight 6Range Weight 6Range Weight 6Range
% % % % % %
insulation-type products.
SiO 68–77 NA 68–77 1.00 68–77 1.00
2. Referenced Documents Al O 0–7 NA 0–7 0.50 0–7 0.50
2 3
CaO 5–15 NA 5–15 0.50 5–15 0.50
2.1 ASTM Standards:
MgO 0–5 NA 0–5 0.50 0–5 0.50
Na O 8–18 NA 8–18 0.50 8–18 0.50
C162 Terminology of Glass and Glass Products
K O 0–4 NA 0–4 0.50 0–4 0.50
D4129 Test Method for Total and Organic Carbon in Water
Fe O <0.5 NA <0.5 0.05 <0.5 0.05
2 3
by High Temperature Oxidation and by Coulometric De-
Cr O <0.2 NA <0.15 0.03 <0.1 0.02
2 3
SO <0.4 NA <0.3 0.03 <0.2 0.02
tection 3
All other <0.5 NA <0.3 0.05 <0.1 0.02
E688 Test Methods for Waste Glass as a Raw Material for
oxides
A
Glass Manufacturing
C <0.15 NA <0.10 0.02 <0.05 0.01
H O <0.5 NA <0.5 0.05 <0.5 0.05
LOI <0.45 NA <0.30 0.05 <0.15 0.03
3. Terminology
A
Carbon is determined directly by instrumental method such as Coulometrics,
3.1 For definitions of terms used in this specification, refer
Inc. Model 5010 Coulometer. Test Method D4129 uses this instrumentation for
to Terminology C162.
total and organic carbon in water. The instrument can be readily adapted to solid
materials such as cullet.
4. General Requirements
4.1 Glass cullet from municipal waste is primarily soda-
means a change in the glass FeO content. This affects the heat
lime bottle glass and shall be one of three grades depending
transfer in the melt and can affect furnace efficiency and glass
upon the total usage rate requirement of the user. The three
quality. See Table 2.
grades shall satisfy the following chemical composition, color
4.4 Contaminants—Free metals, magnetic or nonmagnetic,
mix, contamination, and particle size requirements as listed in
are not oxidized in the glass melting process and, therefore, are
Section 4:
insoluble. Metals will pool on the furnace floor and leak
4.2 Chemical Composition—See Table 1.
through joints causing premature wear of refractories and
4.3 Color Mix—Color is an indicator of the oxidation state
electrical shorts, which can lead to glass leaks. Some metals
of container cullet. SO gas solubility in the glass melt is a
will attack and destroy precious metal skimmers and thermo-
function of the glass oxidation state. Changes in the oxidation
couples and molybdenum electrodes. Examples are silver, tin,
state of cullet added to the fiberglass batch can shift the glass
lead, and aluminum.
oxidation state causing the release of dissolved SO gas, which
4.4.1 Other inorganic materials and refractories will not
can upset the furnace.Achange in the glass oxidation state also
melt in the glass melting process. Other inorganics can be
porcelains, ceramics, or high-temperature glasses. Refractories
can be remnants of furnace construction materi
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