Protective clothing - Performance requirements for protective clothing worn by operators applying pesticides and for re-entry workers - Amendment 1: Surrogate test chemical (ISO 27065:2017/Amd 1:2019)

This International Standard establishes minimum performance, classification, and labelling requirements
for protective clothing worn by operators handling liquid pesticide products as well as re-entry workers. Pesticide
handling includes application of diluted formulations, mixing and loading, and other activities such as cleaning
of contaminated equipment and containers. Protective clothing covered by this International Standard
includes, but is not limited to, shirts, jackets, trousers, coveralls, aprons, protective sleeves, caps/hats and
other headwear made with textile material, and material placed below knapsack/backpack sprayers. This
International Standard does not address items used for the protection of the respiratory tract, hands, and feet.
This International Standard does not address protection against biocides, fumigants or highly volatile liquids.

Schutzkleidung - Leistungsanforderungen an Schutzkleidung für die Anwender von Pflanzenschutzmitteln sowie Personen für Nachfolgearbeiten - Änderung 1: Surrogat Prüfchemikalie (ISO 27065:2017/Amd 1:2019)

Habillement de protection - Exigences de performance pour les vêtements de protection portés par les opérateurs appliquant des pesticides et pour les travailleurs de rentrée - Amendement 1: Produit chimique de substitution d'essai (ISO 27065:2017/Amd 1:2019)

Varovalna obleka - Zahtevane lastnosti za varovalno oblačilo, ki ga nosijo osebe, ki rokujejo s pesticidi, in delavci pri ponovnem vstopu na kontaminirano območje - Dopolnilo A1: Nadomestni kemijski preskus (ISO 27065:2017/Amd 1:2019)

Ta mednarodni standard določa minimalne zahteve glede zmogljivosti, razvrščanja in označevanja varovalnih oblačil za izvajalce tretiranja, ki ravnajo s tekočimi pesticidi, in delavce pri ponovnem vstopu na kontaminirano območje. Ravnanje s pesticidi vključuje njihov nanos v razredčeni sestavi, mešanje in polnjenje ter druge dejavnosti, kot so čiščenje kontaminirane opreme in posode. Med varovalna oblačila, ki so zajeta v tem mednarodnem standardu, med drugim spadajo zlasti srajce, jopiči, hlače, kombinezoni, predpasniki, zaščitni rokavi, kape/klobuki in druga pokrivala iz tekstilnih materialov ter materiali, nameščeni pod nahrbtne škropilnike. Ta mednarodni standard ne obravnava predmetov, ki se uporabljajo za zaščito dihalnih poti, rok in nog. Ta mednarodni standard ne obravnava zaščite pred biocidi, fumiganti ali izjemno hlapne tekočine.

General Information

Status
Published
Publication Date
29-Oct-2019
Withdrawal Date
29-Apr-2020
Current Stage
6060 - Definitive text made available (DAV) - Publishing
Start Date
30-Oct-2019
Completion Date
30-Oct-2019

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SLOVENSKI STANDARD
01-januar-2020
Varovalna obleka - Zahtevane lastnosti za varovalno oblačilo, ki ga nosijo osebe,
ki rokujejo s pesticidi, in delavci pri ponovnem vstopu na kontaminirano območje -
Dopolnilo A1: Nadomestni kemijski preskus (ISO 27065:2017/Amd 1:2019)
Protective clothing - Performance requirements for protective clothing worn by operators
applying pesticides and for re-entry workers - Amendment 1: Surrogate test chemical
(ISO 27065:2017/Amd 1:2019)
Schutzkleidung - Leistungsanforderungen an Schutzkleidung für die Anwender von
Pflanzenschutzmitteln sowie Personen für Nachfolgearbeiten - Änderung 1 (ISO
27065:2017/Amd 1:2019)
Habillement de protection - Exigences de performance pour les vêtements de protection
portés par les opérateurs appliquant des pesticides et pour les travailleurs de rentrée -
Amendement 1: Produit chimique de substitution d'essai (ISO 27065:2017/Amd 1:2019)
Ta slovenski standard je istoveten z: EN ISO 27065:2017/A1:2019
ICS:
13.340.10 Varovalna obleka Protective clothing
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 27065:2017/A1
EUROPEAN STANDARD
NORME EUROPÉENNE
October 2019
EUROPÄISCHE NORM
ICS 13.340.10
English Version
Protective clothing - Performance requirements for
protective clothing worn by operators applying pesticides
and for re-entry workers - Amendment 1: Surrogate test
chemical (ISO 27065:2017/Amd 1:2019)
Habillement de protection - Exigences de performance Schutzkleidung - Leistungsanforderungen an
pour les vêtements de protection portés par les Schutzkleidung für die Anwender von
opérateurs appliquant des pesticides et pour les Pflanzenschutzmitteln sowie Personen für
travailleurs de rentrée - Amendement 1: Produit Nachfolgearbeiten - Änderung 1 (ISO
chimique de substitution d'essai (ISO 27065:2017/Amd 1:2019)
27065:2017/Amd 1:2019)
This amendment A1 modifies the European Standard EN ISO 27065:2017; it was approved by CEN on 14 October 2019.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for inclusion of
this amendment into the relevant national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This amendment exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the
same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 27065:2017/A1:2019 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 27065:2017/A1:2019) has been prepared by Technical Committee ISO/TC 94
"Personal safety -- Personal protective equipment" in collaboration with Technical Committee CEN/TC
162 “Protective clothing including hand and arm protection and lifejackets” the secretariat of which is
held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by April 2020, and conflicting national standards shall be
withdrawn at the latest by April 2020.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association, and supports essential requirements of EU Directive(s).
For the relationship with EU Directive(s), see informative Annex ZA, included in EN ISO 27065:2017.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 27065:2017/Amd 1:2019 has been approved by CEN as EN ISO 27065:2017/A1:2019
without any modification.
INTERNATIONAL ISO
STANDARD 27065
Second edition
2017-09-15
AMENDMENT 1
2019-10
Protective clothing — Performance
requirements for protective clothing
worn by operators applying pesticides
and for re-entry workers
AMENDMENT 1: Surrogate test chemical
Habillement de protection — Exigences de performance pour les
vêtements de protection portés par les opérateurs appliquant des
pesticides et pour les travailleurs de rentrée
AMENDEMENT 1: Produit chimique de substitution pour essai
Reference number
ISO 27065:2017/Amd.1:2019(E)
©
ISO 2019
ISO 27065:2017/Amd.1:2019(E)
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved

ISO 27065:2017/Amd.1:2019(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/ patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see www .iso .org/
iso/ foreword .html.
This document was prepared by Technical Committee ISO/TC 94, Personal safety — Personal protective
equipment, Subcommittee SC 13, Protective clothing.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/ members .html.
ISO 27065:2017/Amd.1:2019(E)
Protective clothing — Performance requirements for
protective clothing worn by operators applying pesticides
and for re-entry workers
AMENDMENT 1: Surrogate test chemical
Introduction, seventh paragraph, fourth sentence
Replace
"The test chemical selected for testing is an emulsifiable concentrate that is representative of a worst
case scenario for penetration and repellency."
with
"The test chemical selected for testing is a pesticide surrogate that is representative of a worst case
scenario for penetration."
6.2
Delete footnote 1, and replace the text in the main paragraphs with the following:
"Materials for Level C1 and Level C2 protective clothing shall be tested in accordance with ISO 22608,
Method A, using 0,2 ml of test chemical. Three specimens shall be tested for each material. The test
chemical shall be diluted pesticide surrogate EC-DY, an emulsion of Disperse Yellow 26 in water. Water
grade 3 (according to ISO 3696) or deionized water shall be used to prepare the diluted solution with
2,5 % EC-DY. See Annex C concerning selection of test chemical and Annex G for composition of the test
chemical.
For materials for protective clothing classified as Level C1, the upper limit for percent penetration shall
be 40 %. For materials classified as Level C2, the upper limit for percent penetration shall be 5 %.
In addition, materials for protective clothing shall be tested for resistance to penetration according to
ISO 22608 Method B if one or more of the following requirements are met:
a) the test results for materials for protective clothing classified as Level C1 are greater than 40 %
but less than 48 % (i.e. at least one specimen shows its result greater than 40 % and the three test
specimens show their result lower than 48 %).
b) the test results for materials for protective clothing classified as Level C2 are greater than 5 %
but less than 6 % (i.e. at least one specimen shows its result greater than 5 % and the three test
specimens show their result lower than 6 %).If the specimens are tested with both methods A and
B, the results obtained by Method B shall be used for determining penetration classification and
reporting requirements.
NOTE 1 For Method A, a gravimetric method, the difference in the mass of the collector layer before and after
testing is used to calculate the % penetration. Method A is used in the first instance because this is the simpler
and less-expensive of the two test methods. However, in some cases the increase in mass of the collector layer is
due to water and/or water vapour penetration. Therefore, for validation Method B is required as the chemical
analysis required for Method B confirms the amount of the actual dye/active ingredient that has penetrated.
For materials for protective clothing classified as Level C1, the three specimens tested shall have
maximum penetration of 40 %.
ISO 27065:2017/Amd.1:2019(E)
For materials for protective clothing classified as Level C2, the three specimens tested shall have
maximum penetration of 5 %.
NOTE 2 ISO 22608 is an accelerated laboratory test that differentiates the penetration performance of
materials and seams. The maximum allowable penetration of 40 % is derived from the data analysis of cotton
and cotton/polyester protective clothing used for operator exposure studies. The 40 % penetration limit for
Level C1 protective clothing is based on analysis of lab data as well as operator exposure study data. Studies
conducted with the reference fabric for Level C1 had less than 5 % penetration through the garment in operator
exposure studies. Therefore, it is not possible to substitute laboratory penetration data for field penetration
data. For this reason, the laboratory test data are used only to classify materials and seams. It cannot be used
as default protection factors for risk assessment. References [4] and [5] provide additional information on the
analysis to establish the 40 % limit value for Level C1 and the 5 % limit value for Level C2."

6.4
Replace paragraphs prior to NOTE 1 with the following.
"For Level C3 protective clothing, three specimens shall be tested for cumulative permeation in
accordance with ISO 19918. Use(s) claimed by the manufacturer and stated in accordance with Clause 10
c) shall be used as the basis for conducting the permeation test. See Annex C concerning selection of
test chemical and Annex G for composition of the test chemical.
— For protection against diluted formulations, the test shall be conducted for 1 h using pesticide
surrogate EC-DY (an emulsion of Disperse Yellow 26), diluted with water grade 3 (according to
ISO 3696) or deionized water to 2,5 % EC-DY.
— For protection against concentrates for short duration, the test shall be conducted for 15 min using
pesticide surrogate EC-DY (without dilution).
Additional testing may be requir
...

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