FprEN 14385

Stationary source emissions - Determination of the total emission of As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb, Tl and V

This document specifies a manual reference method for the determination of the mass concentration of specific elements in stationary source emissions. The method is applicable to each of the specific elements in the concentration range of 0,005 mg/m3 to 5 mg/m3.
This document has been validated for the determination of the mass concentration of metals in incineration exhaust gases - applying the performance criteria stated in Clause 9 - for the following elements:
-   arsenic (As), cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), antimony (Sb), thallium (Tl), and vanadium (V) and their compounds.
The document can be used to determine metals other than those listed above (for example, selenium (Se) (ISO 17211), tellurium (Te), beryllium (Be), tin (Sn) and zinc (Zn)).
NOTE 1   These other metals mentioned above are commonly required by National Regulations, but this document currently has not yet been validated for these metals.
The document was validated for waste incinerators, but it is also applicable to other industrial processes, the practical experience shows that it can be applied over wide concentration ranges and various emission sources.
If mercury is intended to be determined as well, this can be sampled in a side stream arrangement of the sampling train (EN 13211) [5].
NOTE 2   This document has been validated with the described materials, equipment, sampling, and digestion performances etc., followed by analyses with atomic absorption spectroscopy (AAS) and inductively coupled plasma optical emission spectroscopy (ICP-OES,) or inductively coupled mass spectrometry (ICP-MS). This does not exclude the use of other types of equipment or analyses that meet the requirements and have been proven to be equivalent to the described European Standard.

Emissionen aus stationären Quellen - Bestimmung der Gesamtemission von As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb, Tl und V

Dieses Dokument legt ein manuelles Referenzmessverfahren zur Bestimmung der Massenkonzentration bestimmter Elemente in den Emissionen aus stationären Quellen fest. Das Verfahren ist für jedes der zu bestimmenden Elemente im Konzentrationsbereich von 0,005 mg/m3 bis 5 mg/m3 anwendbar.
Dieses Dokument wurde zur Bestimmung der Massenkonzentrationen von Metallen in Abgasen von Verbrennungsanlagen unter Anwendung der in Abschnitt 9 festgelegten Leistungskriterien für die folgenden Elemente validiert:
-   Arsen (As), Cadmium (Cd), Chrom (Cr), Kobalt (Co), Kupfer (Cu), Mangan (Mn), Nickel (Ni), Blei (Pb), Antimon (Sb), Thallium (Tl), Vanadium (V) und deren Verbindungen.
Dieses Dokument kann zur Bestimmung anderer als der oben genannten Metalle verwendet werden (z. B. Selen (Se) (ISO 17211), Tellur (Te), Beryllium (Be), Zinn (Sn) und Zink (Zn)).
ANMERKUNG 1   Diese anderen oben aufgeführten Metalle werden in der Regel von nationalen Vorschriften vorgeschrieben, allerdings wurde dieses Dokument derzeit noch nicht für diese Metalle validiert.
Dieses Dokument wurde für Müllverbrennungsanlagen validiert, ist aber auch auf andere industrielle Prozesse anwendbar. Die praktische Erfahrung zeigt, dass es auf eine Vielzahl von Konzentrationsbereichen und verschiedene Emissionsquellen angewendet werden kann.
Falls es beabsichtigt ist, Quecksilber ebenfalls mitzubestimmen, so kann dies durch die Probenahme im Teilstromverfahren erfolgen (EN 13211) [5].
ANMERKUNG 2   Dieses Dokument wurde mit den beschriebenen Materialien, Ausrüstungen, Probenahme- und Aufschlussverfahren usw. und den anschließend durchgeführten Analysen mit Atomabsorptionsspektroskopie (AAS) und induktiv gekoppelter Plasma-Emissionsspektroskopie (ICP OES) oder induktiv gekoppelter Massenspektrometrie (ICP MS) validiert. Dies schließt nicht die Verwendung anderer Geräte, Analysen, Materialien und Vorgehensweisen aus, die die Anforderungen erfüllen und deren Äquivalenz zu den beschriebenen Vorgehensweisen in dieser Europäischen Norm nachgewiesen ist.

Émissions de sources fixes - Détermination de l'émission totale de As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb, TI et V

Le présent document décrit une méthode de référence manuelle de détermination de la concentration massique d’éléments spécifiques dans les émissions de sources fixes. Cette méthode est applicable à chacun de ces éléments dans la plage de concentration comprise entre 0,005 mg/m3 et 5 mg/m3.
Le présent document a été validé pour la détermination de la concentration massique des métaux dans les effluents gazeux d’incinération, en appliquant les critères de performance énoncés à l’Article 9, pour les éléments suivants :
-   arsenic (As), cadmium (Cd), chrome (Cr), cobalt (Co), cuivre (Cu), manganèse (Mn), nickel (Ni), plomb (Pb), antimoine (Sb), thallium (Tl) et vanadium (V) et leurs composés.
Le document peut être utilisé pour doser des métaux autres que ceux listés ci-dessus (par exemple, sélénium (Se) (ISO 17211), tellure (Te), béryllium (Be), étain (Sn) et zinc (Zn)).
NOTE 1   Ces autres métaux susmentionnés sont couramment exigés par les réglementations nationales,
mais à l’heure actuelle, le présent document n’a pas encore été validé pour ces métaux.
Le document a été validé pour les incinérateurs de déchets, mais il est aussi applicable à d’autres procédés industriels. L’expérience pratique révèle qu’il peut être appliqué sur de larges plages de concentration et diverses sources d’émission.
S’il est prévu de déterminer également le mercure, il est possible d’effectuer le prélèvement avec une ligne secondaire du système de prélèvement (EN 13211) [5].
NOTE 2   Le présent document a été validé sur la base des performances des matériels, de l’équipement, du prélèvement et de la minéralisation décrits, etc. suivis des analyses par spectroscopie d’absorption atomique (AAS) et spectroscopie d’émission optique à plasma à couplage inductif (ICP-OES,) ou spectrométrie de masse à couplage inductif (ICP-MS). Ceci n’exclut pas l’utilisation d’autres types d’équipements ou d’analyses qui répondent aux exigences fixées dans la présente Norme européenne et dont l’équivalence a été prouvée.

Emisije nepremičnih virov - Določevanje celotne emisije As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb, TI in V

General Information

• Status: Not Published
• Publication Date: 18-Dec-2024
• ICS: 13.040.40 - Stationary source emissions
• Technical Committee: CEN/TC 264 - Air quality
• Drafting Committee: CEN/TC 264/WG 8 - Measurement of total mercury emissions
• Current Stage: 5020 - Submission to Vote - Formal Approval
• Start Date: 29-Aug-2024
• Due Date: 03-Oct-2024
• Completion Date: 29-Aug-2024
• Directive: 2001/997 - Incineration of waste
• Directive: 89/369/EEC - Prevention of air pollution from new municipal waste incineration plants
• Directive: 89/429/EEC - Reduction of air pollution from existing municipal waste incineration plants
• Directive: 94/67/EC - Incineration of hazardous waste
• Mandate: M/232 - Emissions of Heavy metals & metalloides to the air
• Ref Project: oSIST prEN 14385:2023 - Stationary source emissions - Determination of the total emission of As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb, Tl and V

Relations

• Revises: EN 14385:2004 - Stationary source emissions - Determination of the total emission of As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb, TI and V
• Effective Date: 28-Jan-2023

Standards Content (Sample)

SLOVENSKI STANDARD
01-oktober-2023
Emisije nepremičnih virov - Določevanje celotne emisije As, Cd, Cr, Co, Cu, Mn, Ni,
Pb, Sb, TI in V
Stationary source emissions - Determination of the total emission of As, Cd, Cr, Co, Cu,
Mn, Ni, Pb, Sb, Tl and V
Emissionen aus stationären Quellen - Bestimmung der Gesamtemission von As, Cd, Cr,
Co, Cu, Mn, Ni, Pb, TI und V
Emissions de sources fixes - Détermination de l'émission totale de As, Cd, Cr, Co, Cu,
Mn, Ni, Pb, Sb, TI et V
Ta slovenski standard je istoveten z: prEN 14385
ICS:
13.040.40 Emisije nepremičnih virov Stationary source emissions
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

DRAFT
EUROPEAN STANDARD
prEN 14385
NORME EUROPÉENNE
EUROPÄISCHE NORM
August 2023
ICS 13.040.40 Will supersede EN 14385:2004
English Version
Stationary source emissions - Determination of the total
emission of As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb, Tl and V
Émissions de sources fixes - Détermination de Emissionen aus stationären Quellen - Bestimmung der
l'émission totale de As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb, TI Gesamtemissionen von As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb,
et V TI und V
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 264.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 14385:2023 E
worldwide for CEN national Members.

prEN 14385:2023 (E)
Contents Page
European foreword . 5
Introduction . 6
1 Scope . 7
2 Normative references . 7
3 Terms and definitions, symbols and abbreviations . 7
3.1 Terms and definitions . 7
3.2 Symbols . 9
3.3 Abbreviations . 9
4 Principle .10
5 Apparatus and Chemicals .10
5.1 Apparatus and Chemicals .10
5.2 Chemicals and filter material .13
6 Sampling equipment .15
6.1 General requirements .15
6.2 Isokinetic sampling equipment .15
6.3 Absorbers and absorption efficiency .16
7 Cleaning of the sampling equipment prior to sampling .17
8 Procedure.17
8.1 General requirements .17
8.2 Preparation and installation of equipment .17
8.3 Performance of the sampling .19
8.4 Disassembling the equipment .19
8.5 Field blanks .20
8.6 Requirements for storage of the samples .20
8.7 Pre-treatment before analysis .21
8.8 Analysis .23
9 Expression of results .25
10 Test report .28
Annex A (informative) Examples of absorption vessels .29
Annex B (informative) Types of isokinetic equipment and leak test methods .30
B.1 Types of isokinetic equipment .30
B.2 Leak test methods .31
Annex C (informative) Pre-cleaning procedures of the sampling equipment at the laboratory
and determination of the absorption efficiency .35
C.1 General .35
C.2 Chemicals .35
C.2.1 General .35
C.2.2 Rinsing solution .35
prEN 14385:2023 (E)
C.2.3 Diluted Aqua regia . 35
C.2.4 Laboratory cleaning solution . 35
C.2.5 Dilute hydrogen peroxide . 35
C.2.6 Rinsing acid . 35
C.3 Equipment . 35
C.3.1 Procedure A . 35
C.3.2 Procedure B . 36
C.3.2.1 Filter housing . 36
C.3.2.2 Probe, nozzle . 36
C.3.3 Procedure C. 36
C.4 Absorption and storage bottles . 36
C.4.1 Procedure A . 36
C.4.2 Procedure B . 36
C.4.3 Procedure C. 36
C.4.4 Procedure D . 37
Annex D (informative) Measurement results of two field tests . 38
D.1 Absorption efficiency . 38
D.2 Repeatability . 38
D.3 Reproducibility . 40
Annex E (informative) Pre-tests for the determination of the efficiency, of the digestion and
of the performance of the analytical procedures . 42
E.1 42
E.2 Comments of Field Study Data . 44
E.2.1 General . 44
E.2.2 Pre-treatment and analysis . 45
E.2.3 Absorption efficiency . 46
E.2.4 Detection limit . 46
E.2.5 Repeatability and reproducibility . 46
Annex F (informative) Example of assessment of compliance of the standard reference
method . 47
F.1 Introduction . 47
F.2 Elements required for the uncertainty determinations . 47
F.2.1 Model equation . 47
F.3 Example of an uncertainty calculation in case of side-stream sampling system . 47
F.3.1 General . 47
F.3.2 Determination of the model equations . 48
prEN 14385:2023 (E)
F.3.3 Equations for calculating combined uncertainties of gas volumes sampled in
standardized conditions .50
F.3.4 Equations for calculating combined uncertainties of concentrations .51
F.3.5 Quantification of standard uncertainty components .54
F.3.5.1 Standards uncertainties of parameters taken into account in the volume gas
uncertainties .54
F.3.5.2 Standard uncertainties of analysis: .
...