EN ISO 17294-2:2004
(Main)Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) - Part 2: Determination of 62 elements (ISO 17294-2:2003)
Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) - Part 2: Determination of 62 elements (ISO 17294-2:2003)
ISO 17294-2:2003 specifies a method for the determination of the elements aluminium, antimony, arsenic, barium, beryllium, bismuth, boron, cadmium, caesium, calcium, cerium, chromium, cobalt, copper, dysprosium, erbium, europium, gadolinium, gallium, germanium, gold, hafnium, holmium, indium, iridium, lanthanum, lead, lithium, lutetium, magnesium, manganese, molybdenum, neodymium, nickel, palladium, phosphorus, platinum, potassium, praseodymium, rubidium, rhenium, rhodium, ruthenium, samarium, scandium, selenium, silver, sodium, strontium, terbium, tellurium, thorium, thallium, thulium, tin, tungsten, uranium, vanadium, yttrium, ytterbium, zinc, and zirconium in water (for example drinking water, surface water, groundwater, wastewater and eluates).
Taking into account the specific and additionally occurring interferences, these elements can also be determined in digests of water, sludges and sediments.
The working range depends on the matrix and the interferences encountered. In drinking water and relatively unpolluted waters, the limit of application is between 0,1 micrograms per litre and 1,0 micrograms per litre for most elements.
The detection limits of most elements are affected by blank contamination and depend predominantly on the laboratory air-handling facilities available.
The lower limit of application is higher in cases where the determination is likely to suffer from interferences or in case of memory effects.
Wasserbeschaffenheit - Anwendung der induktiv gekoppelten Plasma-Massenspektrometrie (ICP-MS) - Teil 2: Bestimmung von 62 Elementen (ISO 17294-2:2003)
Dieser Teil von ISO 17294 legt ein Verfahren zur Bestimmung der Elemente Aluminium, Antimon, Arsen, Barium, Beryllium, Bismut, Bor, Cadmium, Caesium, Calcium, Cer, Chrom, Cobalt, Kupfer, Dysprosium, Erbium, Europium, Gadolinium, Gallium, Germanium, Gold, Hafnium, Holmium, Indium, Iridium, Lanthan, Blei, Lithium, Lutetium, Magnesium, Mangan, Molybdän, Neodym, Nickel, Palladium, Phosphor, Platin, Kalium, Praseodym, Rubidium, Rhenium, Rhodium, Ruthenium, Samarium, Scandium, Selen, Silber, Natrium, Strontium, Terbium, Tellur, Thorium, Thallium, Thulium, Zinn, Wolfram, Uran, Vanadium, Yttrium, Ytterbium, Zink und Zirkonium in Wasser [z. B. Trinkwasser, Oberflächenwasser, Grundwasser, Abwasser und Eluate (9.2)] fest.
Unter Berücksichtigung der spezifischen und zusätzlich auftretenden Störungen können diese Elemente auch in wässrigen Aufschlüssen von Schlämmen und Sedimenten (z. B. Aufschlüssen nach ISO 15587 1 oder ISO 15587 2) bestimmt werden.
Der Arbeitsbereich hängt von der Matrix und den zu erwartenden Störungen ab. In Trinkwasser und relativ unbelastetem Wasser beträgt die untere Grenze des Anwendungsbereichs für die meisten Elemente zwischen 0,1 µg/l und 1,0 µg/l (siehe Tabelle 1).
Die Nachweisgrenzen der meisten Elemente werden durch erhöhte Blindwerte beeinträchtigt, und diese hängen überwiegend von den verfügbaren Einrichtungen zur Reinhaltung der Laborluft ab.
Die untere Grenze des Anwendungsbereichs wird höher ausfallen, wenn damit zu rechnen ist, dass bei der Bestimmung Störungen auftreten (siehe Abschnitt 5), oder im Falle des Auftretens von Verschleppungseffekten (siehe 8.2 von ISO 17294 1).
Qualité de l'eau - Application de la spectrométrie de masse avec plasma à couplage inductif (ICP-MS) - Partie 2: Dosage de 62 éléments (ISO 17294-2:2003)
L'ISO 17294-2:2003 spécifie une méthode de dosage des éléments suivants dans l'eau (par exemple l'eau potable, l'eau de surface, l'eau souterraine, les eaux usées et les éluats): aluminium, antimoine, arsenic, baryum, béryllium, bismuth, bore, cadmium, césium, calcium, cérium, chrome, cobalt, cuivre, dysprosium, erbium, europium, gadolinium, gallium, germanium, or, hafnium, holmium, indium, iridium, lanthane, plomb, lithium, lutétium, magnésium, manganèse, molybdène, néodyme, nickel, palladium, phosphore, platine, potassium, praséodyme, rubidium, rhénium, rhodium, ruthénium, samarium, scandium, sélénium, argent, sodium, strontium, terbium, tellure, thorium, thallium, thulium, étain, tungstène, uranium, vanadium, yttrium, ytterbium, zinc et zirconium.
Compte tenu des interférences spécifiques et des interférences non spécifiques, ces éléments peuvent également être dosés dans des minéralisats d'eau, de boues et de sédiments.
La gamme de travail dépend de la matrice et des interférences rencontrées. Dans l'eau potable et dans les eaux relativement peu polluées, la limite d'application est comprise entre 0,1 microgrammes par litre et 1,0 microgrammes par litre pour la plupart des éléments.
Les limites de détection de la plupart des éléments sont influencées par la contamination du blanc qui dépend, dans une large mesure, des installations de traitement de l'air dont dispose le laboratoire.
La limite inférieure d'application sera plus élevée dans les cas où la détermination est susceptible d'être soumise à des interférences ou en cas d'effets de mémoire.
Kakovost vode - Uporaba induktivno sklopljene plazme z masno selektivnim detektorjem (ICP-MS) - 2. del: Določevanje 62 elementov (ISO 17294-2:2003)
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-februar-2005
.DNRYRVWYRGH±8SRUDEDLQGXNWLYQRVNORSOMHQHSOD]PH]PDVQRVHOHNWLYQLP
GHWHNWRUMHP ,&306 ±GHO 'RORþHYDQMHHOHPHQWRY ,62
Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) -
Part 2: Determination of 62 elements (ISO 17294-2:2003)
Wasserbeschaffenheit - Anwendung der induktiv gekoppelten Plasma-
Massenspektrometrie (ICP-MS) - Teil 2: Bestimmung von 62 Elementen (ISO 17294-
2:2003)
Qualité de l'eau - Application de la spectrométrie de masse avec plasma a couplage
inductif (ICP-MS) - Partie 2: Dosage de 62 éléments (ISO 17294-2:2003)
Ta slovenski standard je istoveten z: EN ISO 17294-2:2004
ICS:
13.060.50 3UHLVNDYDYRGHQDNHPLþQH Examination of water for
VQRYL chemical substances
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EUROPEAN STANDARD
EN ISO 17294-2
NORME EUROPÉENNE
EUROPÄISCHE NORM
October 2004
ICS 13.060.50
English version
Water quality - Application of inductively coupled plasma mass
spectrometry (ICP-MS) - Part 2: Determination of 62 elements
(ISO 17294-2:2003)
Qualité de l'eau - Application de la spectrométrie de masse Wasserbeschaffenheit - Anwendung der induktiv
avec plasma à couplage inductif (ICP-MS) - Partie 2: gekoppelten Plasma-Massenspektrometrie (ICP-MS) - Teil
Dosage de 62 éléments (ISO 17294-2:2003) 2: Bestimmung von 62 Elementen (ISO 17294-2:2003)
This European Standard was approved by CEN on 30 September 2004.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
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versions.
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Slovenia, Spain, Sweden, Switzerland and United Kingdom.
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© 2004 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 17294-2:2004: E
worldwide for CEN national Members.
Foreword
The text of ISO 17294-2:2003 has been prepared by Technical Committee ISO/TC 147 "Water
quality" of the International Organization for Standardization (ISO) and has been taken over as
which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of
an identical text or by endorsement, at the latest by April 2005, and conflicting national
standards shall be withdrawn at the latest by April 2005.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of
the following countries are bound to implement this European Standard: Austria, Belgium,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary,
Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
Endorsement notice
The text of ISO 17294-2:2003 has been approved by CEN as EN ISO 17294-2:2004 without any
modifications.
NOTE Normative references to International Standards are listed in annex ZA (normative).
Annex ZA
(normative)
Normative references to international publications
with their relevant European publications
This European Standard incorporates by dated or undated reference, provisions from other
publications. These normative references are cited at the appropriate places in the text and the
publications are listed hereafter. For dated references, subsequent amendments to or revisions of
any of these publications apply to this European Standard only when incorporated in it by
amendment or revision. For undated references the latest edition of the publication referred to
applies (including amendments).
NOTE Where an International Publication has been modified by common modifications, indicated
by (mod.), the relevant EN/HD applies.
Publication Year Title EN Year
ISO 3696 1987 Water for analytical laboratory use - EN ISO 3696 1995
Specification and test methods
ISO 5667-1 1980 Water quality - Sampling - Part 1: EN 25667-1 1993
Guidance on the design of sampling
programmes
ISO 5667-2 1991 Water quality - Sampling - Part 2: EN 25667-2 1993
Guidance on sampling techniques
ISO 15587-1 2002 Water quality - Digestion for the EN ISO 15587-1 2002
determination of selected elements
in water - Part 1: Aqua regia
digestion
ISO 15587-2 2002 Water quality - Digestion for the EN ISO 15587-2 2002
determination of selected elements
in water - Part 2: Nitric acid digestion
INTERNATIONAL ISO
STANDARD 17294-2
First edition
2003-09-01
Water quality — Application of
inductively coupled plasma mass
spectrometry (ICP-MS) —
Part 2:
Determination of 62 elements
Qualité de l'eau — Application de la spectrométrie de masse avec
plasma à couplage inductif (ICP-MS) —
Partie 2: Dosage de 62 éléments
Reference number
ISO 17294-2:2003(E)
©
ISO 2003
ISO 17294-2:2003(E)
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ii © ISO 2003 — All rights reserved
ISO 17294-2:2003(E)
Contents Page
Foreword. iv
Introduction . v
1 Scope. 1
2 Normative references . 3
3 Terms and definitions. 3
4 Principle . 3
5 Interferences. 4
6 Reagents . 8
7 Apparatus . 11
8 Sampling . 12
9 Sample pre-treatment . 12
10 Procedure . 13
11 Calculation. 14
12 Precision . 15
13 Test report . 15
Annex A (informative) Description of the matrices of the samples used for the interlaboratory trial. 19
Bibliography . 21
ISO 17294-2:2003(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 17294-2 was prepared by Technical Committee ISO/TC 147, Water quality, Subcommittee SC 2, Physical,
chemical and biochemical methods.
ISO 17294 consists of the following parts, under the general title Water quality — Application of inductively
coupled plasma mass spectrometry (ICP-MS):
Part 1: General guidelines and basic principles
Part 2: Determination of 62 elements
iv © ISO 2003 — All rights reserved
ISO 17294-2:2003(E)
Introduction
When applying this part of ISO 17294, it is necessary in each case, depending on the range to be tested, to
determine if and to what extent additional conditions should be established.
INTERNATIONAL STANDARD ISO 17294-2:2003(E)
Water quality — Application of inductively coupled plasma
mass spectrometry (ICP-MS) —
Part 2:
Determination of 62 elements
WARNING — Persons using this part of ISO 17294 should be familiar with normal laboratory practice.
This part of ISO 17294 does not purport to address all of the safety problems, if any, associated with
its use. It is the responsibility of the user to establish appropriate safety and health practices and to
ensure compliance with any national regulatory conditions.
IMPORTANT — It is absolutely essential that tests, conducted in accordance with this part of
ISO 17294, be carried out by suitably qualified staff.
1 Scope
This part of ISO 17294 specifies a method for the determination of the elements aluminium, antimony, arsenic,
barium, beryllium, bismuth, boron, cadmium, caesium, calcium, cerium, chromium, cobalt, copper, dysprosium,
erbium, europium, gadolinium, gallium, germanium, gold, hafnium, holmium, indium, iridium, lanthanum, lead,
lithium, lutetium, magnesium, manganese, molybdenum, neodymium, nickel, palladium, phosphorus, platinum,
potassium, praseodymium, rubidium, rhenium, rhodium, ruthenium, samarium, scandium, selenium, silver,
sodium, strontium, terbium, tellurium, thorium, thallium, thulium, tin, tungsten, uranium, vanadium, yttrium,
ytterbium, zinc, and zirconium in water [for example drinking water, surface water, groundwater, wastewater
and eluates (9.2)].
Taking into account the specific and additionally occurring interferences, these elements can also be
determined in digests of water, sludges and sediments (for example digests of water as specified in
ISO 15587-1 or ISO 15587-2).
The working range depends on the matrix and the interferences encountered. In drinki
...
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