Packaging - Flexible packaging material - Determination of residual solvents by dynamic headspace gas chromatography-Absolute method

This standard describes methods for the quantitative determination of residual solvents in flexible packaging by dynamic headspace chromatography where the chemical identities of the residual solvents to be determined are known before commencing the analysis. Residues from thermal decomposition products are not within the scope of this standard.
The method is applicable to flexible packaging materials that may consist of mono- or multiplayer plastic films, paper or board, foil or combinations thereof.
This method does not apply to residual solvents with amounts lower than 0,5 mg/m².

Verpackung, Flexible Packstoffe - Bestimmung der Restlösemittel durch dynamische Dampfraumanalyse mittels Gaschromatographie - Absolutes Verfahren

Diese Norm beschreibt Verfahren zur quantitativen Bestimmung von Restlösemitteln in flexiblen Verpackungen durch dynamische Dampfraumanalyse mittels Gaschromatographie, wobei die chemischen Identitäten der zu bestimmenden Restlösemittel im Vorfeld der Analyse bekannt sind. Die Bestimmung von Resten thermischer Zersetzungsprodukte liegt nicht im Anwendungsbereich dieser Norm.
Das Verfahren ist anwendbar für flexible Packstoffe, die aus einschichtigen oder mehrschichtigen Kunststofffolien, Papier oder Karton, Metallfolien oder Verbunden dieser Materialien bestehen.
Dieses Verfahren ist nicht anwendbar für Restlösemittelgehalte kleiner als 0,5 mg/m2.

Emballage - Matériaux d'emballage souples - Détermination des solvants résiduels par chromatographie en phase gazeuse et espace de tête dynamique - Méthode absolue

La présente norme décrit des méthodes de détermination quantitative des solvants résiduels dans les emballages souples, par chromatographie en phase gazeuse et espace de tête dynamique, l'identité chimique des solvants résiduels à déterminer selon cette méthode devant être connue avant le début de l'analyse. Les résidus issus des produits de décomposition thermique n'entrent pas dans le domaine d'application de la présente norme.
La méthode s'applique aux matériaux d'emballages souples pouvant être constitués de films plastiques mono- ou multicouches, de papier ou de carton, de feuille d'aluminium ou d'une combinaison de ces matériaux.
La présente méthode ne s'applique pas aux solvants résiduels dont les quantités sont inférieures à 0,5 mg/m2.

Embalaža – Prožni embalažni materiali – Določevanje ostanka topil z dinamičnim vzorčevalnikom iz plinske faze (headspace) za plinsko kromatografijo - Absolutna metoda

General Information

Status
Published
Publication Date
06-Apr-2004
Withdrawal Date
30-Oct-2004
Technical Committee
CEN/TC 261 - Packaging
Current Stage
9093 - Decision to confirm - Review Enquiry
Start Date
22-Oct-2020
Completion Date
23-Sep-2025

Overview

EN 14479:2004 (CEN) specifies a quantitative analytical method for the determination of residual solvents in flexible packaging materials using dynamic headspace gas chromatography (GC) - Absolute method. The standard applies where the chemical identities of the target residual solvents are known before analysis. It covers mono- and multi-layer plastic films, paper or board, foil and combinations of these flexible packaging materials. The method excludes residues originating from thermal decomposition products and does not apply to solvent amounts below 0.5 mg/m².

Key Topics and Requirements

  • Scope of application: Designed for flexible packaging materials (films, paper/board, foil, multilayer combinations).
  • Analytical approach: Uses dynamic headspace gas chromatography, a technique that transfers volatile residues from the sample headspace into the GC for quantitative analysis.
  • Absolute method: Intended for quantitative determination when the chemical identity of each residual solvent is known prior to testing (not a screening method).
  • Detection threshold: Not applicable for residual solvents present at amounts lower than 0.5 mg/m².
  • Exclusions: Does not cover residues formed by thermal decomposition during processing or testing.
  • Quantification focus: Emphasizes reliable, repeatable measurement for regulatory compliance and quality control.

Applications and Users

EN 14479:2004 is practical for organizations and professionals involved in:

  • Packaging manufacturers performing in-house quality control of flexible packaging materials (films, foils, paper laminates).
  • Analytical testing laboratories conducting accredited residual solvent testing by headspace GC.
  • Food-contact materials compliance teams ensuring safety and regulatory adherence for packaging that may retain solvent residues.
  • Material scientists and R&D groups validating process changes, solvent removal efficiency or alternative packaging formulations.
  • Regulatory bodies and auditors requiring standardized methods for comparing residual solvent data across suppliers.

Typical use cases include verification of solvent removal after coating, lamination or printing processes, supplier qualification testing, and supporting declarations for product safety.

Related Standards

  • Standards and guidance on gas chromatography, headspace analysis, and packaging materials testing are complementary to EN 14479:2004.
  • For regulatory compliance, pair this method with applicable national or international regulations on food-contact materials and chemical migration testing.

Keywords: EN 14479:2004, residual solvents, dynamic headspace gas chromatography, flexible packaging, absolute method, packaging materials testing, headspace GC, solvent residues.

Frequently Asked Questions

EN 14479:2004 is a standard published by the European Committee for Standardization (CEN). Its full title is "Packaging - Flexible packaging material - Determination of residual solvents by dynamic headspace gas chromatography-Absolute method". This standard covers: This standard describes methods for the quantitative determination of residual solvents in flexible packaging by dynamic headspace chromatography where the chemical identities of the residual solvents to be determined are known before commencing the analysis. Residues from thermal decomposition products are not within the scope of this standard. The method is applicable to flexible packaging materials that may consist of mono- or multiplayer plastic films, paper or board, foil or combinations thereof. This method does not apply to residual solvents with amounts lower than 0,5 mg/m².

This standard describes methods for the quantitative determination of residual solvents in flexible packaging by dynamic headspace chromatography where the chemical identities of the residual solvents to be determined are known before commencing the analysis. Residues from thermal decomposition products are not within the scope of this standard. The method is applicable to flexible packaging materials that may consist of mono- or multiplayer plastic films, paper or board, foil or combinations thereof. This method does not apply to residual solvents with amounts lower than 0,5 mg/m².

EN 14479:2004 is classified under the following ICS (International Classification for Standards) categories: 55.040 - Packaging materials and accessories. The ICS classification helps identify the subject area and facilitates finding related standards.

EN 14479:2004 is associated with the following European legislation: EU Directives/Regulations: 80/232/EEC, 87/356/EEC. When a standard is cited in the Official Journal of the European Union, products manufactured in conformity with it benefit from a presumption of conformity with the essential requirements of the corresponding EU directive or regulation.

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Standards Content (Sample)


2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.PHWRGDVerpackung, Flexible Packstoffe - Bestimmung der Restlösemittel durch dynamische Dampfraumanalyse mittels Gaschromatographie - Absolutes VerfahrenEmballage - Matériaux d'emballage souples - Détermination des solvants résiduels par chromatographie en phase gazeuse et espace de tete dynamique - Méthode absoluePackaging - Flexible packaging material - Determination of residual solvents by dynamic headspace ga
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記事タイトル:EN 14479:2004 - 包装 - 柔軟包装材料 - 動的ヘッドスペースガスクロマトグラフィ-絶対法による残留溶剤の決定 記事の内容:この規格は、残留溶剤の量を定量的に測定するための方法を提供しており、化学的に特定された残留溶剤の化学的同一性が、分析を始める前に既知である必要があります。熱分解生成物からの残留物はこの規格の対象外です。 この方法は、単層または複数層のプラスチックフィルム、紙または板、箔、またはこれらの組み合わせからなる柔軟包装材料に適用されます。 この方法は、0.5 mg/m²未満の量の残留溶剤には適用されません。

The article discusses the EN 14479:2004 standard, which provides methods for determining the amount of residual solvents in flexible packaging materials using dynamic headspace gas chromatography. This method is suitable for packaging materials made of plastic films, paper, board, foil, or combinations of these materials. However, it is important to note that this standard does not cover thermal decomposition products and is not applicable to residual solvents present in amounts less than 0.5 mg/m².

기사 제목: EN 14479:2004 - 포장 - 유연한 포장 재료 - 동적 헤드스페이스 가스 크로마토그래피 절대법을 통한 잔류 용매의 결정 기사 내용: 이 표준은 유연한 포장에서 잔류 용매의 양적 결정을 위한 동적 헤드스페이스 크로마토그래피의 방법을 기술한다. 분석 전에 결정될 잔류 용매의 화학적 신원이 알려져 있어야 한다. 열분해 생성물로 인한 잔류물은 이 표준의 범위를 벗어난다. 이 방법은 단계나 다중 플라스틱 필름, 종이나 판지, 호일 또는 이러한 재료의 조합으로 이루어진 유연한 포장 재료에 적용된다. 이 방법은 0.5 mg/m²보다 낮은 양의 잔류 용매에는 적용되지 않는다.