EN 12619:2013
(Main)Stationary source emissions - Determination of the mass concentration of total gaseous organic carbon - Continuous flame ionisation detector method
Stationary source emissions - Determination of the mass concentration of total gaseous organic carbon - Continuous flame ionisation detector method
This European Standard specifies a flame ionisation detector (FID) method. It is intended for use as a standard reference method for the measurement of the mass concentration of gaseous and vaporous organic substances (expressed as TVOC) in stationary source emissions (e.g. emissions from waste incinerators and solvent using processes, emission measurements according to 2010/75/EU) in the concentration range up to 1 000 mg/m³.
This European Standard specifies the requirements for an instrument using flame ionisation detection, together with procedures for its operation. The results obtained using this standard are expressed in milligrams per cubic metre (mg/m³) as total carbon (TVOC).
This European Standard is not applicable for permanently installed automated measuring systems (AMS).
Alternative methods to this method may be used provided that the user can demonstrate equivalence, based on the principles of CEN/TS 14793.
Emissionen aus stationären Quellen - Bestimmung der Massenkonzentration des gesamten gasförmigen organisch gebundenen Kohlenstoffs - Kontinuierliches Verfahren mit dem Flammenionisationsdetektor
Diese Europäische Norm legt ein Flammionisationsdetektor-Verfahren (FID) fest. Es ist als Standardreferenz-verfahren für die Messung der Massenkonzentration von gas- und dampfförmigen organischen Substanzen (angegeben als TVOC (en: total volatile organic carbon)) in Emissionen aus stationären Quellen (z. B. Müllverbrennungsanlagen, Lösungsmittel verwendende Prozesse, Messungen nach 2010/75/EU) im Konzentrationsbereich bis 1000 mg/m3 konzipiert.
Diese Europäische Norm legt die Anforderungen für ein Messgerät mit Flammenionisationsdetektion sowie die Vorgehensweise bei dessen Betrieb fest. Die nach dieser Norm ermittelten Ergebnisse werden als Gesamtkohlenstoff (TVOC) in Milligramm je Kubikmeter (mg/m3) angegeben.
Diese Europäische Norm ist nicht für fest installierte automatische Messeinrichtungen (AMS (en: automated measuring system)) anwendbar.
Alternative Verfahren dürfen angewendet werden, wenn deren Äquivalenz entsprechend den Grundsätzen der CEN/TS 14793 belegt wurde.
D'autres méthodes peuvent être utilisées à condition que l'utilisateur puisse en démontrer l'équivalence, selon
les principes décrits dans la CEN/TS 14793.
Emissions de sources fixes - Détermination de la concentration massique en carbone organique total - Méthode du détecteur continu à ionisation de flamme
La méthode de détecteur à ionisation de flamme (FID) spécifiée dans la présente Norme européenne est
destinée à être utilisée comme méthode de référence normalisée pour le mesurage de la concentration
massique en substances organiques à l'état de gaz ou de vapeur (exprimées en COVT) dans les émissions
de sources fixes (par exemple, les émissions provenant des incinérateurs de déchets et des process utilisant
des solvants, mesurages des émissions conformément à la Directive 2010/75/UE) dans la plage de
concentration allant jusqu'à 1 000 mg/m3.
La présente Norme européenne spécifie les exigences pour un instrument utilisant la détection à ionisation de
flamme, ainsi que les modes opératoires liés à son fonctionnement. Les résultats obtenus en utilisant la
présente norme sont exprimés en milligrammes par mètre cube (mg/m3) de carbone total (COVT).
La présente Norme européenne ne s’applique pas aux systèmes de mesurage automatisés (AMS) installés
en permanence.
D'autres méthodes peuvent être utilisées à condition que l'utilisateur puisse en démontrer l'équivalence, selon
les principes décrits dans la CEN/TS 14793.
Emisije nepremičnih virov - Določevanje masnih koncentracij celotnega organskega ogljika v plinasti fazi - Kontinuirana metoda plamenske ionizacijske detekcije
Metoda iz tega evropskega standarda je namenjena za uporabo kot standardna referenčna metoda. Ta evropski standard določa sklop minimalnih zahtev za delovanje instrumenta, ki uporablja plamensko ionizacijsko detekcijo, skupaj s postopki za njegovo umerjanje in upravljanje, za merjenje masne koncentracije celotnega organskega ogljika v plinasti fazi (TOC) in za emisije topil celotnih hlapnih organskih spojin (TVOC) v emisijah nepremičnih virov. Ta evropski standard je primeren za merjenje emisij celotnega organskega ogljika in celotnih hlapnih organskih spojin v plinasti ali parni fazi, kot so emisije iz sežigalnic odpadkov in procesov na podlagi topil. Rezultati, pridobljeni v skladu s tem standardom, so izraženi v miligramih na kubični meter kot skupni ogljik (mg/m3). Ta standard je primeren za uporabo v razponu 1 mg/m3 do najmanj 1000 mg/m3. Ta evropski standard se ne uporablja za trajno vgrajene avtomatske merilne sisteme (AMS). Za trajno vgrajene AMS glej standard EN 15267-3.
General Information
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Standards Content (Sample)
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.QHJDGHWHNFLMHEmissionen aus stationären Quellen - Bestimmung der Massenkonzentration des gesamten gasförmigen organisch gebundenen Kohlenstoffs - Kontinuierliches Verfahren mit dem FlammenionisationsdetektorEmissions de sources fixes - Détermination de la concentration massique en carbone organique total - Méthode du détecteur continu à ionisation de flammeStationary source emissions - Determination of the mass concentration of total gaseous organic carbon - Continuous flame ionisation detector method13.040.40Stationary source emissionsICS:Ta slovenski standard je istoveten z:EN 12619:2013SIST EN 12619:2013en,fr,de01-april-2013SIST EN 12619:2013SLOVENSKI
STANDARDSIST EN 13526:2002SIST EN 12619:20001DGRPHãþD
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 12619
January 2013 ICS 13.040.40 Supersedes EN 12619:1999, EN 13526:2001English Version
Stationary source emissions - Determination of the mass concentration of total gaseous organic carbon - Continuous flame ionisation detector method
Emissions de sources fixes - Détermination de la concentration massique en carbone organique total - Méthode du détecteur continu à ionisation de flamme
Emissionen aus stationären Quellen - Bestimmung der Massenkonzentration des gesamten gasförmigen organisch gebundenen Kohlenstoffs - Kontinuierliches Verfahren mit dem Flammenionisationsdetektor This European Standard was approved by CEN on 24 November 2012.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2013 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 12619:2013: ESIST EN 12619:2013
Determination of the performance characteristics of a FID . 12 Annex B (informative)
Basic functionality of an FID . 15 Annex C (informative)
Measurement uncertainty and associated statistics . 18 Annex D (informative)
Safety measures . 20 Annex E (informative)
Significant technical changes . 21 Bibliography. 22
This European Standard specifies the requirements for an instrument using flame ionisation detection, together with procedures for its operation. The results obtained using this standard are expressed in milligrams per cubic metre (mg/m³) as total carbon (TVOC). This European Standard is not applicable for permanently installed automated measuring systems (AMS). Alternative methods to this method may be used provided that the user can demonstrate equivalence, based on the principles of CEN/TS 14793. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 15259, Air quality — Measurement of stationary source emissions — Requirements for measurement sections and sites and for the measurement objective, plan and report EN 15267-1, Air quality — Certification of automated measuring systems — Part 1: General principles EN 15267-2, Air quality — Certification of automated measuring systems — Part 2: Initial assessment of the AMS manufacturer’s quality management system and post certification surveillance for the manufacturing process EN 15267-3:2007, Air quality — Certification of automated measuring systems — Part 3: Performance criteria and test procedures for automated measuring systems for monitoring emissions from stationary sources EN ISO 9169, Air quality — Definition and determination of performance characteristics of an automatic measuring system (ISO 9169) EN ISO 14956, Air quality — Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty (ISO 14956) 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 combustion air air supply used for the combustion of fuel gas in an instrument using flame ionisation detection 3.2 detection limit minimum concentration of a substance which produces an observable response, which is two times the standard deviation at zero SIST EN 12619:2013
Key 1 polarisation voltage 6 fuel gas 2 electrodes 7 sample gas 3 ions 8 jet 4 flame 9 amplifier and readout 5 combustion air Figure 1 — Principle of FID SIST EN 12619:2013
Key 1 sampling probe 6 bypass (optional) 2 zero and span gas inlet 7 test gas inlet for functional tests 3 particle filter, heated 8 FID 4 sampling line, heated 9 data evaluation system 5 external sample pump (optional), heated
Figure 2 — Example of the set-up of the measuring system 5 Requirements for apparatus and gases 5.1 Requirements for the measurement system The sampling system shall meet the following requirements:
It shall be made of stainless steel, polytetrafluoroethylene or polypropylenefluoride. If an alternative material is used, it shall be proven that it is chemically and physically inert to the constituents of the flue gas under analysis. The design and configuration of the sampling device used shall ensure the residence time of the sample gas within the device is minimised in order to reduce the response time of the measuring system. It will be designed to ensure a sample residence time less than 60 s. With long sampling lines or high flow resistance, the use of an external pump with bypass is recommended. It shall be heated throughout to at least 180 °C. NOTE Sampling lines in PTFE have a maximum temperature of 200 °C. All instruments that are certified are tested at 180 °C. It shall have a heated filtering device upstream of the sampling line to trap all particles liable to impair the operation of the apparatus. It shall have an inlet for applying zero and span gases at or close to the probe inlet of the sampling probe, upstream of the filter. This is to check the sampling system including the filter assembly. The FID and sampling system shall comply with the performance requirements of EN 15267-3. SIST EN 12619:2013
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