CEN/TR 16045:2010
(Main)Construction Products - Assessment of release of dangerous substances - Content of regulated dangerous substances - Selection of analytical methods
Construction Products - Assessment of release of dangerous substances - Content of regulated dangerous substances - Selection of analytical methods
This Technical Report describes appropriate standard test methods for the determination of the content of regulated dangerous substances in construction products. Because of the similarity of the analytical methods for digests and eluates from leaching, the analysis of eluates from leaching is also covered.
This Technical Report is relevant to all substances covered by the provisions of the main body of Mandate M/366, i.e. those included in the work programme for the emission into indoor air, and release to surface water, ground water and soil.
The list of regulated substances provided by the Commission in document "Indicative list of regulated dangerous substances" [1] defines the substances, for which analytical methods for content will in principle be needed. This report will be limited to this list.
NOTE 1 Sampling for content analysis is addressed by applying the relevant product standards and or by applying WI 00351013, Construction products - Assessment of release of dangerous substances - Complement to sampling (TR 4) [7] in case the sampling protocol for technical properties does not adequately address requirements in testing posed by the assessment of release to soil, surface and groundwater.
NOTE 2 Based on this selection of appropriate test methods from other fields, horizontal test methods for analysing the chemical content of construction products will be developed as ENs.
NOTE 3 In Annex B a compilation is given of the content regulations for construction products for health or environmental reasons.
Bauprodukte - Bewertung der Freisetzung von gefährlichen Stoffen - Gehalt an geregelten gefährlichen Stoffen - Auswahl von analytischen Verfahren
Der vorliegende Technische Bericht beschreibt geeignete Normprüfverfahren für die Bestimmung des Gehaltes an regulierten (geregelten) gefährlichen Stoffen in Bauprodukten. Auf Grund der Ähnlichkeit der analytischen Verfahren für Aufschlussprodukte und Eluate aus Auslaugungen, wird auch die Analyse von Eluaten aus Auslaugungen berücksichtigt.
Dieser Technische Bericht ist für alle Stoffe relevant, die von den Vorgaben des Hauptteils vom Mandat M/366 erfasst sind, d. h. diejenigen, die im Arbeitsprogramm für die Emission in die Innenraumluft und die Freisetzung in Oberflächenwasser, Grundwasser und Boden enthalten sind.
Die von der Kommission im Verzeichnis „Indicative list of regulated dangerous substances“ [1] bereitgestellte Liste der regulierten gefährlichen Stoffe legt die Stoffe fest, für die Analysenverfahren zur Gehaltsbestimmung prinzipiell notwendig sind. Dieser Bericht beschränkt sich auf diese Liste.
ANMERKUNG 1 Die Probenahme für die Gehaltsanalyse wird in den relevanten Produktnormen und/oder in WI 00351013, Construction products ― Assessment of release of dangerous substances ― Complement to sampling (TR 4) [7] behandelt, wobei das letztgenannte Dokument heranzuziehen ist, wenn das Probenahmeprotokoll für technische Merkmale die von der Beurteilung der Freisetzung in Oberflächenwasser, Grundwasser und Boden auferlegten Prüfanforderungen nicht ausreichend berücksichtigt.
ANMERKUNG 2 Auf Grundlage dieser Auswahl geeigneter Prüfverfahren aus anderen Fachgebieten werden horizontale Prüfverfahren für die Analyse des Chemikaliengehaltes von Bauprodukten als EN-Normen entwickelt.
ANMERKUNG 3 In Anhang B ist eine Zusammenstellung der aus Gesundheits- oder Umweltschutzgründen festgelegten Gehaltsvorschriften für Bauprodukte enthalten.
Produits de construction - Evaluation des émissions de substances dangereuses - Contenu en substances dangereuses réglementées - Sélection des méthodes analytiques
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Vsebnost reguliranih nevarnih snovi - Izbira analitskih metod
To tehnično poročilo opisuje primerne standardne preskusne metode za določevanje vsebnosti reguliranih nevarnih snovi v gradbenih proizvodih. Zaradi podobnosti analitičnih metod za izvlečke in izlužke pri izluževanju, je zajeta tudi analiza izlužke pri izluževanju. To tehnično poročilo je pomembno za vse snovi, ki jih zajemajo določbe glavnega telesa mandata M/366, t.j. tiste, ki so vključene v delovni program za emisije v zrak v zaprtih prostorih ter izpust v površinske in podtalne vode ter zemljo. Seznam reguliranih snovi, ki ga je priskrbela Komisija v dokumentu »Okvirni seznam reguliranih nevarnih snovi«, opredeljuje snovi, za vsebnost katerih bodo načeloma potrebne analitične metode. To poročilo je omejeno na ta seznam.
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
01-januar-2011
*UDGEHQLSURL]YRGL2FHQMHYDQMHVSURãþDQMDQHYDUQLKVQRYL9VHEQRVW
UHJXOLUDQLKQHYDUQLKVQRYL,]ELUDDQDOLWVNLKPHWRG
Construction Products - Assessment of release of dangerous substances - Content of
regulated dangerous substances - Selection of analytical methods
Bauprodukte - Bewertung der Freisetzung von gefährlichen Substanzen - Inhalt von
geregelten gefährlichen Substanzen - Auswahl von analytischen Verfahren
Produits de construction - Evaluation des émissions de substances dangereuses -
Contenu en substances dangereuses réglementées - Sélection des méthodes
analytiques
Ta slovenski standard je istoveten z: CEN/TR 16045:2010
ICS:
13.020.99 Drugi standardi v zvezi z Other standards related to
varstvom okolja environmental protection
91.100.01 Gradbeni materiali na Construction materials in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
TECHNICAL REPORT
CEN/TR 16045
RAPPORT TECHNIQUE
TECHNISCHER BERICHT
November 2010
ICS 91.100.01
English Version
Construction Products - Assessment of release of dangerous
substances - Content of regulated dangerous substances -
Selection of analytical methods
Produits de construction - Evaluation des émissions de Bauprodukte - Bewertung der Freisetzung von gefährlichen
substances dangereuses - Contenu en substances Substanzen - Inhalt von geregelten gefährlichen
dangereuses réglementées - Sélection des méthodes Substanzen - Auswahl von analytischen Verfahren
analytiques
This Technical Report was approved by CEN on 5 June 2010. It has been drawn up by the Technical Committee CEN/TC 351.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2010 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TR 16045:2010: E
worldwide for CEN national Members.
Contents Page
Foreword . 4
1 Scope . 6
2 Abbreviations, terms and definitions . 6
2.1 Abbreviations . 6
2.2 Terms and definitions . 7
3 Approach . 8
4 Available content test methods.11
4.1 Introduction .11
4.2 Inorganic substances .11
4.2.1 Major, minor and trace elements.11
4.2.2 Anions .18
4.2.3 Special analysis of Cr (VI) .20
4.2.4 Non-destructive methods .22
4.3 Total organic carbon .22
4.4 Organic substances .23
4.4.1 General .23
4.4.2 Gas extraction and analytical methods for measuring VOC (SVOC) content of
products .27
4.4.3 Solvent extraction and related analytical methods for measuring organic substances
in solid matrices .30
5 Test methods for eluates obtained by leaching .33
5.1 Introduction .33
5.2 Inorganic substances in eluates .34
5.3 Organic substances in eluates .36
5.4 Method for dissolved organic matter (DOC) .39
6 Particles .39
6.1 Introduction .39
6.2 Asbestos .40
6.3 Synthetic vitreous (silicate) fibres .40
7 Performance of methods .42
8 Conclusions and recommendations .42
8.1 Conclusions .42
8.1.1 General .42
8.1.2 Specific comments for specific substances .43
8.2 Recommendations .44
Annex A (informative) Background to CEN/TC 351/WIs 6/14 Content .46
A.1 Description in mandate M/366 (CEN/TC 351 N 004) .46
A.2 Description in the work programme of CEN/TC 351, as drafted by CEN/BT WG 176 in
June 2005 and confirmed by CEN/TC 351 (CEN/TC 351 N 0026) .46
A.3 Draft proposal to activate WI 00351007 (CEN/TC 351/WG 5 N 022) .47
Annex B (informative) Compilation of content regulations for construction products for
health or environmental reasons .48
B.1 Introduction .48
B.2 Regulated substances .49
B.3 Regulations .52
Annex C (informative) Standards for metals in alloys .54
Bibliography .56
Tables
Table 1 ― Major, minor and trace elements to be considered under the CPD and available test
m ethods . 12
Table 2 — Digestion methods for major, minor and trace elements . 13
Table 3 — Analytical methods for major, minor and trace elements. 16
Table 4 — Anions to be considered under the CPD and available test methods . 18
Table 5 — Digestion methods for anions . 19
Table 6 — Analytical methods for anions . 20
Table 7 — Specific element to be considered under the CPD and available test methods . 21
Table 8 — Methods for extraction and analysis of Cr (VI) . 21
Table 9 — Instrumental quantification methods for major, minor and trace elements . 22
Table 11 — Organic substances to be considered under the CPD and available test methods . 24
Table 12 — Gas extraction and analysis methods for measuring VOC (SVOC) content of
products . 28
Table 13 — Solvent extraction and analytical methods for measuring organic substances in
solid matrices . 31
Table 14 — Analytical methods for inorganic substances in eluates . 34
Table 15 — Analytical methods for organic substances in eluates . 36
Table 16 — Quantification methods for DOC . 39
Table 17 — Particles to be considered under the CPD and available test methods . 40
Table 18 — Quantification methods for asbestos . 40
Table 19 — Quantification methods for silicate fibres . 41
Table B.1 — Content regulated substances in the I"Indicative list" . 49
Table B.2 — Regulations regarding content in the ‘indicative list’ . 52
Table C.1 — List of standards for metals in alloys, etc. . 54
Figures
Figure 1 — Principles of horizontal analytical methods . 10
Foreword
This document (CEN/TR 16045:2010) has been prepared by Technical Committee CEN/TC 351
“Construction Products − Assessment of release of dangerous substances”, the secretariat of which is
held by NEN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent
rights.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
Under Work Item 6, Mandate M/366 describes the need for CEN standards to test the chemical content of
construction products. However, in the first meeting of CEN/BT WG 176, the predecessor to CEN/TC 351
(June 2005, Gouda, The Netherlands), it was decided that a Technical Report (TR) should be drafted first.
This TR was for administrative reasons given work item (WI) number 14. The background and guidelines
for carrying out this work are outlined in Annex A of this report:
a wide range of methods exist, focus will be on existing documents;
one of the criteria for the selection of standard test methods could be the information on validation;
content determination should not be used for certification of emissions unless this is the only
practicable or legally correct solution.
It is emphasized that the focus of the CPD is on the release of dangerous substances, not on content.
Content testing may only be applied for product release/emissions certification of a material if emissions
testing is prohibitively expensive or when it is specifically required by regulation – for example in the case
of banned substances such as certain metals or asbestos.
However, content testing may be useful as a complementary quick screening method for in-house quality
control of product emissions (e.g. as a routine check of product uniformity/conformity). Content tests can
also be relevant within the scope of the continuous surveillance by the app
...
Questions, Comments and Discussion
Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.