Inorganic fertilizers - Determination of chelating and complexing agents

This document specifies references to the methods for the determination of specific micronutrients, chelating and complexing agents. The document specifies references to the methods and requirements for inorganic micronutrient fertilizers in accordance with PFC 1 (C) (II) as specified in the Regulation (EU) 2019/1009 [1].
Inorganic micronutrient materials for this purpose are micronutrient salts or oxide and hydroxides, or micronutrient chelates or complexes and mixtures of them, in powder or granular form, aqueous or suspension preparation.

Anorganische Düngemittel - Bestimmung von Chelat- und Komplexbildnern

Dieses Dokument legt Verweisungen auf Verfahren zur Bestimmung von spezifischen Spurennährstoffen, Chelatbildnern und Komplexbildnern fest. Das Dokument legt Verweisungen auf Verfahren und Anforderungen für anorganische Spurennährstoff-Düngemittel in Übereinstimmung mit PFC 1(C)(II) der Verordnung (EU) 2019/1009 [1] fest.
Anorganische Spurennährstoffmaterialien für diesen Zweck sind Spurennährstoffsalze oder  oxide und  hydroxide oder Spurennährstoffchelate oder  komplexe und Mischungen davon, in Pulver- oder Granulatform, wässrigen Präparaten oder Suspensionen.

Engrais inorganiques - Détermination des agents chélatants et complexants

Le présent document spécifie les références aux méthodes de détermination des oligo-éléments spécifiques, des agents chélatants et complexants. Le document spécifie les références aux méthodes et aux exigences relatives aux engrais inorganiques à oligo-éléments conformément à la PFC 1 (C) (II), tel que spécifié dans le règlement (UE) 2019/1009 [1].
Les matières inorganiques à oligo-éléments utilisées à cette fin sont des oligo-éléments sous forme de sels ou d'oxyde ou d'hydroxydes, ou des chélates ou des complexes d'oligo-éléments et des mélanges de ceux-ci, sous forme de poudre ou de granulés, en préparation aqueuse ou en suspension.

Anorganska gnojila - Določevanje sredstev za kelatiranje in kompleksiranje

Ta dokument navaja metode za določevanje specifičnih mikrohranil, sredstev za kelatiranje in kompleksiranje. Dokument določa metode in zahteve za anorganska-mineralna gnojila v skladu s funkcijsko kategorijo PFC 1(C) (II), kot je določeno v Uredbi (EU) 2019/1009 [1].
Anorgansko-mineralna sredstva za ta namen so mikrohranilne soli ali oksidi in hidroksidi ali mikrohranila, ki vsebujejo kelate ali komplekse mikrohranil in/ali njihove mešanice v prahu ali granulah, vodne ali suspenzijske pripravke.

General Information

Status
Published
Public Enquiry End Date
02-Jan-2022
Publication Date
09-Jan-2023
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
06-Jan-2023
Due Date
13-Mar-2023
Completion Date
10-Jan-2023

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Standards Content (Sample)

SLOVENSKI STANDARD
SIST-TS CEN/TS 17791:2023
01-februar-2023
Anorganska gnojila - Določevanje sredstev za kelatiranje in kompleksiranje
Inorganic fertilizers - Determination of chelating and complexing agents
Anorganische Düngemittel - Bestimmung von Chelat- und Komplexbildnern
Engrais inorganiques - Détermination des agents chélatants et complexants
Ta slovenski standard je istoveten z: CEN/TS 17791:2022
ICS:
65.080 Gnojila Fertilizers
SIST-TS CEN/TS 17791:2023 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST-TS CEN/TS 17791:2023

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SIST-TS CEN/TS 17791:2023


CEN/TS 17791
TECHNICAL SPECIFICATION

SPÉCIFICATION TECHNIQUE

April 2022
TECHNISCHE SPEZIFIKATION
ICS 65.080
English Version

Inorganic fertilizers - Determination of chelating and
complexing agents
Engrais inorganiques - Détermination des agents Anorganische Düngemittel - Bestimmung von Chelat-
chélatants et complexants und Komplexbildnern
This Technical Specification (CEN/TS) was approved by CEN on 13 March 2022 for provisional application.

The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to
submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.

CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS
available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in
parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2022 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 17791:2022 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------
SIST-TS CEN/TS 17791:2023
CEN/TS 17791:2022 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references. 5
3 Terms and definitions . 6
4 Sampling and sample preparation . 6
4.1 Sampling . 6
4.2 Sample preparation . 6
5 Requirements . 6
5.1 General . 6
5.2 Determination of the fraction of chelated micronutrients . 6
5.3 Identification of chelating agents . 7
5.4 Determination of the fraction of complexed micronutrients . 7
5.5 Identification of complexing agents . 7
Bibliography . 9

2

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SIST-TS CEN/TS 17791:2023
CEN/TS 17791:2022 (E)
European foreword
This document (CEN/TS 17791:2022) has been prepared by Technical Committee CEN/TC 260 “Fertilizers
and liming materials” the secretariat of which is held by DIN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a Standardization Request given to CEN by the European
Commission and the European Free Trade Association.
Any feedback and questions on this document should be directed to the users’ national standards body. A
complete listing of these bodies can be found on the CEN website.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria, Croatia, Cyprus,
Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy,
Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of North
Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United
Kingdom.
3

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SIST-TS CEN/TS 17791:2023
CEN/TS 17791:2022 (E)
Introduction
Regulation (EU) 2019/1009 [1] lays down the rules on the making available on the market of EU fertilizing
products and the specific safety and quality requirements for the defined product function categories
(PFCs).
Inorganic fertilizers have been classified into PFC 1(C), which has been divided into two groups PFC 1(C)
(I) [inorganic macronutrients fertilizers] and PFC 1(C)(II) [inorganic micronutrient fertilizers].
Micronutrients are considered to be, in plant nutrition, a number of elements known to be needed in small
amounts for proper plant growth and development. The most common are Iron (Fe), Manganese (Mn),
Molybdenum (Mo), Copper (Cu), Zinc (Zn) and Boron (B).
If an inorganic micronutrient fertilizer contains a substance, or one of the substances in the mixture, which
is intended to enhance the long term availability to plants of micronutrients in the EU fertilizing product,
that substance is either a chelating agent or a complexing agent.
The specific safety and quality requirements in relation to the determination of chelating and complexing
agents in inorganic micronutrient fertilizers (PFC 1(C)(II)) are defined in this document as well as the
normative references of the test methods to be used in order to measure the compliance with the related
requirement in the Regulation (EU) 2019/1009 [1].
4

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SIST-TS CEN/TS 17791:2023
CEN/TS 17791:2022 (E)
1 Scope
This document specifies references to the methods for the determination of specific micronutrients,
chelating and complexing agents. The document specifies references to the methods and requirements for
inorganic micronutrient fertilizers in accordance with PFC 1 (C) (II) as specified in the Regulation (EU)
2019/1009 [1].
Inorganic micronutrient materials for this purpose are micronutrient salts or oxide and hydroxides, or
micronutrient chelates or complexes and mixtures of them, in powder or granular form, aqueous or
suspension preparation.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 1482-1:2007, Ferti
...

SLOVENSKI STANDARD
kSIST-TS FprCEN/TS 17791:2021
01-december-2021
[Not translated]
Inorganic fertilizers - Determination of chelating and complexing agents
Anorganische Düngemittel - Bestimmung von Chelat- und Komplexbildnern
Ta slovenski standard je istoveten z: FprCEN/TS 17791
ICS:
65.080 Gnojila Fertilizers
kSIST-TS FprCEN/TS 17791:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
kSIST-TS FprCEN/TS 17791:2021

---------------------- Page: 2 ----------------------
kSIST-TS FprCEN/TS 17791:2021


FINAL DRAFT
TECHNICAL SPECIFICATION
FprCEN/TS 17791
SPÉCIFICATION TECHNIQUE

TECHNISCHE SPEZIFIKATION

November 2021
ICS 65.080
English Version

Inorganic fertilizers - Determination of chelating and
complexing agents
Engrais inorganiques - Détermination des agents Anorganische Düngemittel - Bestimmung von Chelat-
chélatants et complexants und Komplexbildnern


This draft Technical Specification is submitted to CEN members for Vote. It has been drawn up by the Technical Committee
CEN/TC 260.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a Technical Specification. It is distributed for review and comments. It is subject to change
without notice and shall not be referred to as a Technical Specification.


EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMAL I S A T IO N

EUROPÄISCHES KOMITEE FÜR NORMUN G

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. FprCEN/TS 17791:2021 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------
kSIST-TS FprCEN/TS 17791:2021
FprCEN/TS 17791:2021 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references. 5
3 Terms and definitions . 6
4 Sampling and sample preparation . 6
4.1 Sampling . 6
4.2 Sample preparation . 6
5 Requirements . 6
5.1 General . 6
5.2 Determination of the fraction of chelated micronutrients . 6
5.3 Identification of chelating agents . 7
5.4 Determination of the fraction of complexed micronutrients . 7
5.5 Identification of complexing agents . 7
Bibliography . 9

2

---------------------- Page: 4 ----------------------
kSIST-TS FprCEN/TS 17791:2021
FprCEN/TS 17791:2021 (E)
European foreword
This document (FprCEN/TS 17791:2021) has been prepared by Technical Committee CEN/TC 260
“Fertilizers and liming materials” the secretariat of which is held by DIN.
This document is currently submitted to the Vote on TS.
This document has been prepared under a Standardization Request given to CEN by the European
Commission and the European Free Trade Association.
3

---------------------- Page: 5 ----------------------
kSIST-TS FprCEN/TS 17791:2021
FprCEN/TS 17791:2021 (E)
Introduction
Regulation (EU) 2019/1009 [1] lays down the rules on the making available on the market of EU fertilizing
products and the specific safety and quality requirements for the defined product function categories
(PFCs).
Inorganic fertilizers have been classified into PFC 1(C), which has been divided into two groups PFC 1(C)
(I) [inorganic macronutrients fertilizers] and PFC 1(C)(II) [inorganic micronutrient fertilizers].
Micronutrients are considered to be, in plant nutrition, a number of elements known to be needed in small
amounts for proper plant growth and development. The most common are Iron (Fe), Manganese (Mn),
Molybdenum (Mo), Copper (Cu), Zinc (Zn) and Boron (B).
If an inorganic micronutrient fertilizer contains a substance, or one of the substances in the mixture, which
is intended to enhance the long term availability to plants of micronutrients in the EU fertilizing product,
that substance is either a chelating agent or a complexing agent.
The specific safety and quality requirements in relation to the determination of chelating and complexing
agents in inorganic micronutrient fertilizers (PFC 1(C)(II)) are defined in this document as well as the
normative references of the test methods to be used in order to measure the compliance with the related
requirement in the Regulation (EU) 2019/1009 [1].
4

---------------------- Page: 6 ----------------------
kSIST-TS FprCEN/TS 17791:2021
FprCEN/TS 17791:2021 (E)
1 Scope
This document specifies references to the methods for the determination of specific micronutrients,
chelating and complexing agents. The document specifies references to the methods and requirements for
inorganic micronutrient fertilizers in accordance with PFC 1 (C) (II) as specified in the Regulation (EU)
2019/1009 [1].
Inorganic micronutrient materials for this purpose are micronutrient salts or oxide and hydroxides, or
micronutrient chelates or complexes and mixtures of them, in powder or granular form, aqueous or
suspension preparation.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 1482-1:2007, Fertilizers and liming materials - Sampling and sample preparation - Part 1: Sampling
EN 1482-2:2007, Fertilizers and liming materials - Sampling and sample preparation - Part 2: Sample
preparation
EN 12944-1:1999, Fertilizers and liming materials and soil improvers - Vocabulary - Part 1: General terms
EN 12944-2:1999, Fertilizers and liming materials and soil improvers - Vocabulary - Part 2: Terms relating
to fertilizers
EN 13368-1:2014, Fertilizers - Determination of chelating agents in fertil
...

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