Fertilizers - Determination of urea condensates using high-performance liquid chromatography (HPLC) - Isobutylidenediurea and crotonylidenediurea (method A) and methylene-urea oligomers (method B)

This European Standard specifies methods for the determination of isobutylidenediurea (IBDU), crotonylidenediurea (CDU) (method A) and methylene-urea oligomers (MU) (method B) in fertilizers using high-performance liquid chromatography (HPLC). The method is applicable to all fertilizers which do not contain interfering organic compounds.

Düngemittel - Bestimmung von Harnstoffkondensaten mit Hochleistungs-Flüssigchromatographie (HPLC) - Isobutylidendiharnstoff und Crotonylidendiharnstoff (Verfahren A) und Methylenharnstoff-Oligomere (Verfahren B)

Diese Europäische Norm legt Verfahren für die Bestimmung von Isobutylidendiharnstoff (IBDU), Crotony-lidendiharnstoff (CDU) (Verfahren A) und Methylenharnstoff-Oligomere (MU) (Verfahren B) in Düngemitteln mit Hochleistungs-Flüssigchromatographie (HPLC) fest.
Das Verfahren gilt für alle Düngemittel, die keine störenden organischen Verbindungen enthalten.

Engrais - Dosage des condensats d'urée par chromatographie liquide haute performance (HPLC) - Isobutylidène diurée et crotonylidène diurée (méthode A) et oligomères de méthylene-urée (méthode B)

La présente Norme européenne spécifie les méthodes de dosage de l’isobutylidène diurée (IBDU), de la crotonylidène diurée (CDU) (méthode A) et des oligomères de méthylène-urée (MU) (méthode B) dans les engrais par chromatographie liquide haute performance (HPLC).
La méthode est applicable à tous les engrais qui ne contiennent pas de composés organiques interférents.

Gnojila - Določevanje kondenzatov sečnine s tekočinsko kromatografijo visoke ločljivosti (HPLC) - Izobutilidendiurea in krotonilidendiurea (metoda A) in oligomeri metilenuree (metoda B)

Ta evropski standard določa metode za določevanje izobutilidendiura(IBDU), krotonilidendiurea(CDU) (metoda A) ter oligomeri metilenuree (MU) (metoda B) v gnojilih s tekočinsko kromatografijo visoke ločljivosti (HPLC). Metoda se uporablja za vsa gnojila, ki ne vsebujejo motečih organskih spojin.

General Information

Status
Published
Public Enquiry End Date
19-Dec-2009
Publication Date
14-Sep-2010
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
10-Sep-2010
Due Date
15-Nov-2010
Completion Date
15-Sep-2010

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2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Düngemittel - Bestimmung von Harnstoffkondensaten mit Hochleistungs-Flüssigchromatographie (HPLC) - Isobutylidendiharnstoff und Crotonylidendiharnstoff (Verfahren A) und Methylenharnstoff-Oligomere (Verfahren B)Engrais - Dosage des condensats d'urée par chromatographie liquide haute performance (HPLC) - Isobutylidène diurée et crotonylidène diurée (méthode A) et oligomères de méthylene-urée (méthode B)Fertilizers - Determination of urea condensates using high-performance liquid chromatography (HPLC) - Isobutylidenediurea and crotonylidenediurea (method A) and methylene-urea oligomers (method B)65.080GnojilaFertilizersICS:Ta slovenski standard je istoveten z:EN 15705:2010SIST EN 15705:2010en,fr,de01-oktober-2010SIST EN 15705:2010SLOVENSKI
STANDARDSIST-TS CEN/TS 15705:20091DGRPHãþD



SIST EN 15705:2010



EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 15705
March 2010 ICS 65.080 Supersedes CEN/TS 15705:2009English Version
Fertilizers - Determination of urea condensates using high-performance liquid chromatography (HPLC) - Isobutylidenediurea and crotonylidenediurea (method A) and methylen-urea oligomers (method B)
Engrais - Dosage des condensats d'urée par chromatographie liquide haute performance (HPLC) - Isobutylidène diurée et crotonylidène diurée (méthode A) et oligomères de méthylène-urée (méthode B)
Düngemittel - Bestimmung von Harnstoffkondensaten mit Hochleistungs-Flüssigchromatographie (HPLC) - Isobutylidendiharnstoff und Crotonylidendiharnstoff (Verfahren A) und Methylenharnstoff-Oligomere (Verfahren B) This European Standard was approved by CEN on 21 February 2010.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15705:2010: ESIST EN 15705:2010



EN 15705:2010 (E) 2 Contents Page Foreword .3Introduction .41Scope .52Normative references .53Terms and definitions .54Sampling and sample preparation .55Method A: Determination of CDU and IBDU .56Method B: Determination of methylen-urea oligomers (MU) .87Precision method A and method B . 138Test report . 14Annex A (informative)
Results of the inter-laboratory tests . 15Annex B (informative)
Chromatogram and calibration curves method A . 17Annex C (informative)
Chromatogram and calibration curves method B . 19Bibliography .
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