D16.02 - Oxygenated Aromatics

SIGNIFICANCE AND USE
4.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can affect the PET quality (such as contribute to fiber breaks), the polymerization process, and 4-CBA imparts coloration to the polymer due to thermal instability.  
4.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control tool where these products are produced or are used.
SCOPE
1.1 This test method covers the determination of the 4-Carboxybenzaldehyde (4-CBA) and p-Toluic acid (p-TOL) in purified terephthalic acid (PTA) by reverse phase high performance liquid chromatography (HPLC). This method is applicable for 4-CBA and p- TOL with an upper limit of 500 mg/kg, respectively, but may be applicable to a wider range.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.For specific hazard statements, see Section 7.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is suitable for the general quantitative analysis of commercial tar acid mixtures. It may be used as a tool for quality control and specification purposes by producers and users.
SCOPE
1.1 This test method covers the quantitative determination of phenol and certain homologues of phenol in tar acid and cresylic acid mixtures using capillary gas chromatography. It is a normalization test method that determines homolog distribution but is not an absolute assay since it does not account for water or other compounds not detected by a flame ionization detector.  
1.2 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 Iron may increase the color of bisphenol A and affect other properties of end-use products.  
5.2 High purity bisphenol A typically has less than 1 mg/kg of iron.
SCOPE
1.1 This test method covers the determination of the iron content of bisphenol A (4,4′-isopropylidenediphenol).  
1.2 This test method has a lower detection limit of 0.1 mg/kg, and an upper limit of 10 mg/kg of iron in bisphenol A. If the iron (Fe) content is higher, it may be necessary to dilute the sample. A longer path length cell can also be used for better accuracy at lower Fe levels, as well as calibration within the range expected (for example, 0 mg/kg to 1 mg/kg versus 0 mg/kg to 10 mg/kg for samples expected to be in the 0 mg/kg to 1 mg/kg range.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limits prior to use.  For a specific hazard statement, see Section 9.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SCOPE
1.1 This specification covers purified terephthalic acid (PTA) for use in the production of polyesters for superfine denier fiber.  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off to the nearest unit in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 Consult current OSHA regulations, supplier’s Safety Data Sheets, and local regulations for all materials used in this specification.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The pyridine base content of cresylic acids is important in certain applications. This test method may be used as a tool for quality control and specification purposes by producers and users.
SCOPE
1.1 This test method covers the determination of pyridine and other basic nitrogen impurities in crude and refined cresylic acids streams, including mixtures.  
1.2 This test method is applicable for pyridine base levels of 0.001 % to 0.5 %.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is suitable for setting specifications on phenol and for use as an internal quality control tool where phenol is produced or is used in a manufacturing process. It may also be used in development or research work involving phenol. It is generally applied to determining those commonly occurring impurities such as mesityl oxide, cumene, hydroxyacetone, acetone, α-methylstyrene, 2-methylbenzofuran, and acetophenone.  
5.2 Purity is commonly reported by subtracting the determined expected impurities from 100.00. However, a gas chromatographic analysis cannot determine absolute purity if water is present or unknown components are contained within the material being examined.
SCOPE
1.1 This test method covers the determination of known impurities in phenol by gas chromatography (GC). It is generally meant for the analysis of phenol of 99.9 % or greater purity.  
1.2 This test method has been found applicable over impurity concentrations up to 70 mg/kg. Users of this method believe it is linear over a wider range. The limit of detection (LOD) is 1.7 mg/kg and the limit of quantitation (LOQ) is 5.8 mg/kg.
Note 1: LOD is defined in 7.1 as part of the method setup. The values above were calculated based on the ILS data for acetone, acetophenone, α-methylstyrene, and 2-methylbenzofuran in Table 3.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Color is caused by impurities in the bisphenol A. The acceptable amount of color depends on the end-use of the bisphenol A.  
4.2 This test method can be used for internal quality control. This method provides the information required to set specifications.
SCOPE
1.1 This test method covers the procedure for determination of the Platinum-Cobalt Color of bisphenol A (4,4′-Isopropylidenediphenol) dissolved in methanol.  
1.2 This test method has been found applicable for the determination of solution color of bisphenol A to 20 Pt–Co color units.  
1.3 The following applies for the purposes of determining the conformance of the test results using this test method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process, and 4-CBA is also imparting coloration to the polymer due to thermal instability.  
4.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and could be used as an internal quality control tool where these products are produced or are used.
SCOPE
1.1 This test method2 covers the determination of the 4-Carboxybenzaldehyde (4-CBA) and p-Toluic acid (p-TOL) in purified terephthalic acid (PTA) by weak anion exchange high performance liquid chromatography (HPLC). This method is applicable for 4-CBA from 2 to 500 mg/kg and for p-TOL from 10 to 500 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process; and 4-CBA is also imparting coloration to the polymer due to thermal instability.  
5.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control where these products are produced or used.  
5.3 This test method is intended as an alternative to the HPLC method for determination of 4-CBA and p-TOL in PTA. The major benefits of CE are speed, simplicity, reduced reagent consumption and operating costs.
SCOPE
1.1 This test method covers the determination of 4-carboxybenzaldehyde (4-CBA) and p-toluic acid (p-TOL) in purified terephthalic acid (PTA) by capillary electrophoresis (CE) with normal voltage mode and UV detection. It is applicable for 4-CBA from 5 to 400 mg/kg and for p-TOL from 10 to 400 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process; and 4-CBA is also imparting coloration to the polymer due to thermal instability.  
5.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control where these products are produced or used.  
5.3 This test method is intended as an alternative to the HPLC method for the determination of 4-CBA and p-TOL in PTA. The major benefits of CE are speed, simplicity, reduced reagent consumption, and operating costs.
SCOPE
1.1 This test method2 covers the determination of 4-carboxybenzaldehyde (4-CBA) and p-toluic acid (p-TOL) in purified terephthalic acid (PTA) by capillary electrophoresis (CE) with reverse voltage mode and UV detection. It is applicable for 4-CBA from 3 to 400 mg/kg and for p-TOL from 8 to 400 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 An estimate of TA purity can be determined by titrating with KOH. As an index of TA purity, the acid number can be used as a guide in the quality control of TA production.
SCOPE
1.1 This test method covers the determination of acid number of terephthalic acid (TA) by color-indicator titration. Acid number of TA product is usually within 674 to 676 mg KOH/g.  
1.2 In determining the conformance of the test results using this method, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The solidification point of bisphenol A is a direct indication of its purity, although it gives no information as to the nature of any impurities present.  
5.2 High purity bisphenol A has a solidification point of approximately 157°C.  
5.3 This test method can be used for internal quality control or for setting specifications.
SCOPE
1.1 This test method describes the procedure for determination of the solidification point of bisphenol A (4,4′-isopropylidene diphenol).  
1.2 The test method has been found applicable for determination of the solidification point between 150 and 157°C.  
1.3 In determining conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 Warning—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use caution when handling mercury and mercury-containing products. See the applicable product Safety Data Sheet (SDS) for additional information. The potential exists that selling mercury or mercury-containing products, or both, is prohibited by local or national law. Users must determine legality of sales in their location.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers refined phenol. The refined phenol shall conform to the required water content, solidification point, appearance and molten color when sampled and tested.
SCOPE
1.1 This specification covers refined phenol.  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 Consult current OSHA regulations and supplier’s Safety Data Sheets, and local regulations for all materials listed in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification establishes requirements for purified terephthalic acid (PTA) used in the manufacturing of polymers, including the production of polyesters for fiber, filament, yarn, film, coating, bottle and resin applications. For purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off to the nearest unit in the last right-hand digit used in expressing the specification limit. This specification covers properties and sampling of the material.
SCOPE
1.1 This specification covers purified terephthalic acid (PTA) for use in the manufacturing of polymers. Some examples include the production of polyesters for fiber, filament, yarn, film, coating, bottle and resin applications.  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off to the nearest unit in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 Consult current OSHA regulations, supplier’s Safety Data Sheets, and local regulations for all materials used in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Bisphenol A is used for production of polycarbonate or epoxy resin. The presence of impurities in bisphenol A is undesirable because they may slow down the polymerization and be impurities in the final product.  
4.2 Determination of the trace impurities, such as isomer of bisphenol A and the unreacted raw material, is often required. This test method is suitable for setting specifications and for using as an internal quality control where these products are produced or used.  
4.3 Purity is commonly reported by subtracting the determined expected impurities and water from 100 %. However, a HPLC analysis cannot determine absolute purity if unknown components are contained within the material being examined.
SCOPE
1.1 This test method covers the determination of trace impurities in bisphenol A (4,4′-Isopropylidenediphenol) by reverse-phase gradient high performance liquid chromatography (HPLC). It is generally meant for the analysis of bisphenol A of 99.5 % or greater.  
1.2 This method is applicable to bisphenol A samples containing impurity concentration between 2 and 400 mg/kg. Users of this method believe it is linear over a wider range.  
1.3 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see Section 8.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Color by this test method is a measure of color-producing impurities present in the thermally stable solids. This test method is suitable for setting specifications and for use as an internal quality control tool.
SCOPE
1.1 This test method covers the visual measurement of the color of thermally stable solids melting below 150°C. It is applicable only to materials in which the color-producing bodies present have light absorption characteristics quite similar to those of the standards used. The scope of this method covers the range of calibration which is 0 to 100 Pt-Co color.  
1.2 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. Weight% should be used rather than Mass%.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements see Sections 7 and 9.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is particularly useful for determining small amounts of water in hygroscopic materials. This test method is suitable for setting specifications on materials referenced in the scope. It may also be used as an internal quality control tool and in development or research work.
SCOPE
1.1 This test method covers the determination of water in phenol and related materials such as cresols, xylenols, naphthalene, pyridine, and quinoline.  
1.2 This test method has been found applicable to a variety of materials varying in water content from 100 mg/kg to solutions containing a relatively high percent of water.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The color of maleic anhydride can be an indication of the purity of these materials. High colors normally indicate contamination or decomposition. This test method is suitable for setting specifications and for use as an internal quality control tool.
SCOPE
1.1 This test method covers the determination of the visual measurement of the color of maleic anhydride melt before and after prolonged heating under specified conditions of time and temperature. Color values are expressed in terms of platinum-cobalt standards.  
1.2 This test method covers the range 0 to 100 color standard numbers.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements see Sections 7, 10.2.1, and 10.4.2.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The color of maleic anhydride can be an indication of the purity of these materials. A high color after heating normally indicates contamination or decomposition.  
4.2 This standard is suitable for process quality control and determining if the product meets specifications.
SCOPE
1.1 This test method covers an instrumental method for the CIE (Commission International de l’Eclairage) tristimulus measurement of the color of maleic anhydride melt before and after prolonged heating under specified conditions of time and temperature. The measurement is converted to color values in the platinum-cobalt system.  
1.2 This test method covers the range 0 to100 Pt-Co color.  
1.3 In determining the conformance of the test results using this method to applicable specification, results shall be rounded in accordance with the rounding off methods of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Sections 7, 10.3, and 10.6.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The presence of water in PTA used for the production of polyester is undesirable because it reduces the purity of the PTA.  
4.2 Determining the amount of water content remaining from the manufacture of PTA is often required. This test method is suitable for setting product specifications and for use as an internal quality control tool where these products are produced or are used.
SCOPE
1.1 This test method covers the determination of water in purified terephthalic acid (PTA) between 0.01 and 1.00 % (w/w) by Volumetric Karl Fischer Titration.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The presence of metals in PTA used for the production of polyester is undesirable because they may speed up or slow down the reaction and be impurities in the final product.  
4.2 Determination of the metals in PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control where these products are produced or used.  
4.3 This test method covers the determination of sodium, chromium, cobalt, aluminum, titanium, potassium, magnesium, manganese, iron, nickel, molybdenum and calcium.
SCOPE
1.1 This test method covers the determination of metal elements in purified terephthalic acid (PTA) by inductively coupled plasma atomic emission spectrometry (ICP-AES).This method is applicable to PTA samples containing sodium, chromium, cobalt, aluminum, titanium, potassium, magnesium, manganese, iron, nickel, molybdenum and calcium over 0.055 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 An estimate of TA purity can be determined by titrating with KOH. As an index of TA purity, the acid number can be used as a guide in the quality control of TA production.
SCOPE
1.1 This test method covers the determination of acid number in terephthalic acid (TA) by automatic potentiometric titration. As the index of TA purity, acid number is usually within 674 to 676 mg KOH/g.  
1.2 In determining the conformance of the test results using this method, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
4.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can affect the PET quality (such as contribute to fiber breaks), the polymerization process, and 4-CBA imparts coloration to the polymer due to thermal instability.  
4.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control tool where these products are produced or are used.
SCOPE
1.1 This test method covers the determination of the 4-Carboxybenzaldehyde (4-CBA) and p-Toluic acid (p-TOL) in purified terephthalic acid (PTA) by reverse phase high performance liquid chromatography (HPLC). This method is applicable for 4-CBA and p- TOL with an upper limit of 500 mg/kg, respectively, but may be applicable to a wider range.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.For specific hazard statements, see Section 7.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SCOPE
1.1 This specification covers purified terephthalic acid (PTA) for use in the production of polyesters for superfine denier fiber.  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off to the nearest unit in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 Consult current OSHA regulations, supplier’s Safety Data Sheets, and local regulations for all materials used in this specification.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SCOPE
1.1 This specification covers purified terephthalic acid (PTA) for use in the production of polyesters for superfine denier fiber.  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off to the nearest unit in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 Consult current OSHA regulations, supplier’s Safety Data Sheets, and local regulations for all materials used in this specification.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process; and 4-CBA is also imparting coloration to the polymer due to thermal instability.  
5.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control where these products are produced or used.  
5.3 This test method is intended as an alternative to the HPLC method for the determination of 4-CBA and p-TOL in PTA. The major benefits of CE are speed, simplicity, reduced reagent consumption, and operating costs.
SCOPE
1.1 This test method2 covers the determination of 4-carboxybenzaldehyde (4-CBA) and p-toluic acid (p-TOL) in purified terephthalic acid (PTA) by capillary electrophoresis (CE) with reverse voltage mode and UV detection. It is applicable for 4-CBA from 3 to 400 mg/kg and for p-TOL from 8 to 400 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Color is caused by impurities in the bisphenol A. The acceptable amount of color depends on the end-use of the bisphenol A.  
4.2 This test method can be used for internal quality control. This method provides the information required to set specifications.
SCOPE
1.1 This test method covers the procedure for determination of the Platinum-Cobalt Color of bisphenol A (4,4′-Isopropylidenediphenol) dissolved in methanol.  
1.2 This test method has been found applicable for the determination of solution color of bisphenol A to 20 Pt–Co color units.  
1.3 The following applies for the purposes of determining the conformance of the test results using this test method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process and 4-CBA imparts coloration to the polymer due to thermal instability.  
4.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control tool where these products are produced or are used.
SCOPE
1.1 This test method covers the determination of the 4-Carboxybenzaldehyde (4-CBA) and p-Toluic acid (p-TOL) in purified terephthalic acid (PTA) by reverse phase high performance liquid chromatography (HPLC). This method is applicable for 4-CBA from 2 to 500 mg/kg and for p-TOL from 10 to 500 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process and 4-CBA imparts coloration to the polymer due to thermal instability.  
4.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control tool where these products are produced or are used.
SCOPE
1.1 This test method covers the determination of the 4-Carboxybenzaldehyde (4-CBA) and p-Toluic acid (p-TOL) in purified terephthalic acid (PTA) by reverse phase high performance liquid chromatography (HPLC). This method is applicable for 4-CBA from 2 to 500 mg/kg and for p-TOL from 10 to 500 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process, and 4-CBA is also imparting coloration to the polymer due to thermal instability.  
4.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and could be used as an internal quality control tool where these products are produced or are used.
SCOPE
1.1 This test method2 covers the determination of the 4-Carboxybenzaldehyde (4-CBA) and p-Toluic acid (p-TOL) in purified terephthalic acid (PTA) by weak anion exchange high performance liquid chromatography (HPLC). This method is applicable for 4-CBA from 2 to 500 mg/kg and for p-TOL from 10 to 500 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process; and 4-CBA is also imparting coloration to the polymer due to thermal instability.  
5.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control where these products are produced or used.  
5.3 This test method is intended as an alternative to the HPLC method for determination of 4-CBA and p-TOL in PTA. The major benefits of CE are speed, simplicity, reduced reagent consumption and operating costs.
SCOPE
1.1 This test method covers the determination of 4-carboxybenzaldehyde (4-CBA) and p-toluic acid (p-TOL) in purified terephthalic acid (PTA) by capillary electrophoresis (CE) with normal voltage mode and UV detection. It is applicable for 4-CBA from 5 to 400 mg/kg and for p-TOL from 10 to 400 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process; and 4-CBA is also imparting coloration to the polymer due to thermal instability.  
5.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control where these products are produced or used.  
5.3 This test method is intended as an alternative to the HPLC method for the determination of 4-CBA and p-TOL in PTA. The major benefits of CE are speed, simplicity, reduced reagent consumption, and operating costs.
SCOPE
1.1 This test method2 covers the determination of 4-carboxybenzaldehyde (4-CBA) and p-toluic acid (p-TOL) in purified terephthalic acid (PTA) by capillary electrophoresis (CE) with reverse voltage mode and UV detection. It is applicable for 4-CBA from 3 to 400 mg/kg and for p-TOL from 8 to 400 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SCOPE
1.1 This specification covers purified terephthalic acid (PTA) for use in the production of polyesters for superfine denier fiber.  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off to the nearest unit in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 Consult current OSHA regulations, supplier’s Safety Data Sheets, and local regulations for all materials used in this specification.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is suitable for the general quantitative analysis of commercial tar acid mixtures. It may be used as a tool for quality control and specification purposes by producers and users.
SCOPE
1.1 This test method covers the quantitative determination of phenol and certain homologues of phenol in tar acid and cresylic acid mixtures using capillary gas chromatography. It is a normalization test method that determines homolog distribution but is not an absolute assay since it does not account for water or other compounds not detected by a flame ionization detector.  
1.2 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 Iron may increase the color of bisphenol A and affect other properties of end-use products.  
5.2 High purity bisphenol A typically has less than 1 mg/kg of iron.
SCOPE
1.1 This test method covers the procedure to determine the iron content of bisphenol A (4,4′-isopropylidenediphenol).  
1.2 This test method has a lower detection limit of 0.1 mg/kg, and an upper limit of 10 mg/kg of iron in bisphenol A. If the iron content is higher, it may be necessary to dilute the sample. A longer path length cell can also be used for better accuracy at lower Fe levels, as well as calibration within the range expected (for example, 0 to 1 mg/kg versus 0 to 10 mg/kg for samples expected to be in the 0 to 1 mg/kg range.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limits prior to use.  For a specific hazard statement, see Section 9.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The pyridine base content of cresylic acids is important in certain applications. This test method may be used as a tool for quality control and specification purposes by producers and users.
SCOPE
1.1 This test method covers the determination of pyridine and other basic nitrogen impurities in crude and refined cresylic acids streams, including mixtures.  
1.2 This test method is applicable for pyridine base levels of 0.001 % to 0.5 %.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is suitable for setting specifications on phenol and for use as an internal quality control tool where phenol is produced or is used in a manufacturing process. It may also be used in development or research work involving phenol. It is generally applied to determining those commonly occurring impurities such as mesityl oxide, cumene, hydroxyacetone, acetone, alpha-methylstyrene, 2-methylbenzofuran, and acetophenone.  
5.2 Purity is commonly reported by subtracting the determined expected impurities from 100.00. However, a gas chromatographic analysis cannot determine absolute purity if water is present or unknown components are contained within the material being examined.
SCOPE
1.1 This test method covers the determination of known impurities in phenol by gas chromatography (GC). It is generally meant for the analysis of phenol of 99.9 % or greater purity.  
1.2 This test method has been found applicable over impurity concentrations of 15 to 70 mg/kg. Users of this method believe it is linear over a wider range.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.

ABSTRACT
This specification covers refined phenol. The refined phenol shall conform to the required water content, solidification point, appearance and molten color when sampled and tested.
SCOPE
1.1 This specification covers refined phenol.  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 Consult current OSHA regulations and supplier’s Safety Data Sheets, and local regulations for all materials listed in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
5.1 The solidification point of bisphenol A is a direct indication of its purity, although it gives no information as to the nature of any impurities present.  
5.2 High purity bisphenol A has a solidification point of approximately 157°C.  
5.3 This test method can be used for internal quality control or for setting specifications.
SCOPE
1.1 This test method describes the procedure for determination of the solidification point of bisphenol A (4,4′-isopropylidene diphenol).  
1.2 The test method has been found applicable for determination of the solidification point between 150 and 157°C.  
1.3 In determining conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.

SIGNIFICANCE AND USE
5.1 An estimate of TA purity can be determined by titrating with KOH. As an index of TA purity, the acid number can be used as a guide in the quality control of TA production.
SCOPE
1.1 This test method covers the determination of acid number of terephthalic acid (TA) by color-indicator titration. Acid number of TA product is usually within 674 to 676 mg KOH/g.  
1.2 In determining the conformance of the test results using this method, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification establishes requirements for purified terephthalic acid (PTA) used in the manufacturing of polymers, including the production of polyesters for fiber, filament, yarn, film, coating, bottle and resin applications. For purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off to the nearest unit in the last right-hand digit used in expressing the specification limit. This specification covers properties and sampling of the material.
SCOPE
1.1 This specification covers purified terephthalic acid (PTA) for use in the manufacturing of polymers. Some examples include the production of polyesters for fiber, filament, yarn, film, coating, bottle and resin applications.  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off to the nearest unit in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 Consult current OSHA regulations, supplier’s Safety Data Sheets, and local regulations for all materials used in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
5.1 This test method is suitable for the general quantitative analysis of commercial tar acid mixtures. It may be used as a tool for quality control and specification purposes by producers and users.
SCOPE
1.1 This test method covers the quantitative determination of phenol and certain homologues of phenol in tar acid and cresylic acid mixtures using capillary gas chromatography. It is a normalization test method that determines homolog distribution but is not an absolute assay since it does not account for water or other compounds not detected by a flame ionization detector.  
1.2 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.

SIGNIFICANCE AND USE
5.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process; and 4-CBA is also imparting coloration to the polymer due to thermal instability.  
5.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control where these products are produced or used.  
5.3 This test method is intended as an alternative to the HPLC method for the determination of 4-CBA and p-TOL in PTA. The major benefits of CE are speed, simplicity, reduced reagent consumption, and operating costs.
SCOPE
1.1 This test method2 covers the determination of 4-carboxybenzaldehyde (4-CBA) and p-toluic acid (p-TOL) in purified terephthalic acid (PTA) by capillary electrophoresis (CE) with reverse voltage mode and UV detection. It is applicable for 4-CBA from 3 to 400 mg/kg and for p-TOL from 8 to 400 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
5.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process; and 4-CBA is also imparting coloration to the polymer due to thermal instability.  
5.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control where these products are produced or used.  
5.3 This test method is intended as an alternative to the HPLC method for determination of 4-CBA and p-TOL in PTA. The major benefits of CE are speed, simplicity, reduced reagent consumption and operating costs.
SCOPE
1.1 This test method covers the determination of 4-carboxybenzaldehyde (4-CBA) and p-toluic acid (p-TOL) in purified terephthalic acid (PTA) by capillary electrophoresis (CE) with normal voltage mode and UV detection. It is applicable for 4-CBA from 5 to 400 mg/kg and for p-TOL from 10 to 400 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
4.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process and 4-CBA imparts coloration to the polymer due to thermal instability.  
4.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control tool where these products are produced or are used.
SCOPE
1.1 This test method covers the determination of the 4-Carboxybenzaldehyde (4-CBA) and p-Toluic acid (p-TOL) in purified terephthalic acid (PTA) by reverse phase high performance liquid chromatography (HPLC). This method is applicable for 4-CBA from 2 to 500 mg/kg and for p-TOL from 10 to 500 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
4.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process, and 4-CBA is also imparting coloration to the polymer due to thermal instability.  
4.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and could be used as an internal quality control tool where these products are produced or are used.
SCOPE
1.1 This test method2 covers the determination of the 4-Carboxybenzaldehyde (4-CBA) and p-Toluic acid (p-TOL) in purified terephthalic acid (PTA) by weak anion exchange high performance liquid chromatography (HPLC). This method is applicable for 4-CBA from 2 to 500 mg/kg and for p-TOL from 10 to 500 mg/kg, respectively.  
1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
5.1 Iron may increase the color of bisphenol A and affect other properties of end-use products.  
5.2 High purity bisphenol A typically has less than 1 mg/kg of iron.
SCOPE
1.1 This test method covers the procedure to determine the iron content of bisphenol A (4,4′-isopropylidenediphenol).  
1.2 This test method has a lower detection limit of 0.1 mg/kg, and an upper limit of 10 mg/kg of iron in bisphenol A. If the iron content is higher, it may be necessary to dilute the sample. A longer path length cell can also be used for better accuracy at lower Fe levels, as well as calibration within the range expected (for example, 0 to 1 mg/kg versus 0 to 10 mg/kg for samples expected to be in the 0 to 1 mg/kg range.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limits prior to use.  For a specific hazard statement, see Section 9.

SIGNIFICANCE AND USE
4.1 Color is caused by impurities in the bisphenol A. The acceptable amount of color depends on the end-use of the bisphenol A.  
4.2 This test method can be used for internal quality control or for setting specifications.
SCOPE
1.1 This test method describes the procedure for determination of the Platinum-Cobalt Color of bisphenol A (4,4′-Isopropylidenediphenol) dissolved in methanol.  
1.2 This test method has been found applicable for the determination of Platinum-Cobalt color of bisphenol A between 20 and 100 color units.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.

SIGNIFICANCE AND USE
5.1 The solidification point of bisphenol A is a direct indication of its purity, although it gives no information as to the nature of any impurities present.  
5.2 High purity bisphenol A has a solidification point of approximately 157°C.  
5.3 This test method can be used for internal quality control or for setting specifications.
SCOPE
1.1 This test method describes the procedure for determination of the solidification point of bisphenol A (4,4′-isopropylidene diphenol).  
1.2 The test method has been found applicable for determination of the solidification point between 150 and 157°C.  
1.3 In determining conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.

SIGNIFICANCE AND USE
5.1 This test method is suitable for setting specifications on phenol and for use as an internal quality control tool where phenol is produced or is used in a manufacturing process. It may also be used in development or research work involving phenol. It is generally applied to determining those commonly occurring impurities such as mesityl oxide, cumene, hydroxyacetone, acetone, alpha-methylstyrene, 2-methylbenzofuran, and acetophenone.  
5.2 Purity is commonly reported by subtracting the determined expected impurities from 100.00. However, a gas chromatographic analysis cannot determine absolute purity if water is present or unknown components are contained within the material being examined.
SCOPE
1.1 This test method covers the determination of known impurities in phenol by gas chromatography (GC). It is generally meant for the analysis of phenol of 99.9 % or greater purity.  
1.2 This test method has been found applicable over impurity concentrations of 15 to 70 mg/kg. Users of this method believe it is linear over a wider range.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.