Standard Guide for Pore-Liquid Sampling from the Vadose Zone

SIGNIFICANCE AND USE
5.1 Sampling from the vadose zone may be an important component of some groundwater monitoring strategies. It can provide information regarding contaminant transport and attenuation in the vadose zone. This information can be used for mitigating potential problems prior to degradation of a groundwater resource (1).3  
5.2 The choice of appropriate sampling devices for a particular location is dependent on various criteria. Specific guidelines for designing vadose zone monitoring programs have been discussed by Morrison (1), Wilson (2), Wilson (3), Everett (4), Wilson (5), Everett, et al (6), Wilson (7), Everett, et al (8), Everett, et al (9), Robbins, et al (10), Merry and Palmer (11), U.S. EPA (12), Ball (13), and Wilson (14). In general, it is prudent to combine various unsaturated and free drainage samplers into a program, so that the different flow regimes may be monitored.  
5.3 This guide does not attempt to present details of installation and use of the equipment discussed. However, an effort has been made to present those references in which the specific techniques may be found.
Note 1: The quality of the result produced by this standard is dependent on the competence of the personnel performing it and the suitability of the equipment and facility used. Agencies that meet the criteria of Practice D3740 are generally considered capable of competent and objective testing/sampling/observation/ and the like. Users of this standard are cautioned that compliance with Practice D3740 does not itself guarantee reliable results. Reliable results depend on many factors; D3740 provides a means of evaluating some of those factors.
SCOPE
1.1 This guide covers the equipment and procedures used for sampling pore-liquid from the vadose zone (unsaturated zone). The guide is limited to in situ techniques and does not include soil core collection and extraction methods for obtaining samples.  
1.2 The term “pore-liquid” is applicable for liquids from aqueous pore-liquid to oil. However, the samplers described in this guide were designed, and are used to sample aqueous pore-liquids only. The abilities of these samplers to collect other pore-liquids may be quite different than those described.  
1.3 Some of the samplers described in this guide are not currently commercially available. These samplers are presented because they may have been available in the past, and may be encountered at sites with established vadose zone monitoring programs. In addition, some of these designs are particularly suited to specific situations. If needed, these samplers could be fabricated.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This guide offers an organized collection of information or a series of options and does not recommend a specific course of action. This document cannot replace education or experience and should be used in conjunction with professional judgment. Not all aspects of this guide may be applicable in all circumstances. This ASTM standard is not intended to represent or replace the standard of care by which the adequacy of a given professional service must be judged, nor should this document be applied without consideration of a project's many unique aspects. The word “Standard” in the title of this document means only that the document has been approved through the ASTM consensus process.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guid...

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ASTM D4696-18 - Standard Guide for Pore-Liquid Sampling from the Vadose Zone
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D4696 − 18
Standard Guide for
1
Pore-Liquid Sampling from the Vadose Zone
This standard is issued under the fixed designation D4696; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* unique aspects. The word “Standard” in the title of this
document means only that the document has been approved
1.1 This guide covers the equipment and procedures used
through the ASTM consensus process.
for sampling pore-liquid from the vadose zone (unsaturated
zone). The guide is limited to in situ techniques and does not 1.7 This international standard was developed in accor-
include soil core collection and extraction methods for obtain- dance with internationally recognized principles on standard-
ing samples. ization established in the Decision on Principles for the
Development of International Standards, Guides and Recom-
1.2 The term “pore-liquid” is applicable for liquids from
mendations issued by the World Trade Organization Technical
aqueous pore-liquid to oil. However, the samplers described in
Barriers to Trade (TBT) Committee.
this guide were designed, and are used to sample aqueous
pore-liquids only. The abilities of these samplers to collect
2. Referenced Documents
other pore-liquids may be quite different than those described.
2
2.1 ASTM Standards:
1.3 Some of the samplers described in this guide are not
D653Terminology Relating to Soil, Rock, and Contained
currently commercially available. These samplers are pre-
Fluids
sented because they may have been available in the past, and
D3740Practice for Minimum Requirements for Agencies
may be encountered at sites with established vadose zone
Engaged in Testing and/or Inspection of Soil and Rock as
monitoring programs. In addition, some of these designs are
Used in Engineering Design and Construction
particularly suited to specific situations. If needed, these
samplers could be fabricated.
3. Terminology
1.4 The values stated in SI units are to be regarded as
3.1 Definitions—
standard. No other units of measurement are included in this
3.1.1 Forcommondefinitionsoftermsinthisstandard,refer
standard.
to Terminology D653.
1.5 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the 3.2 Definitions of Terms Specific to This Standard:
responsibility of the user of this standard to establish appro- 3.2.1 air entry value, n—in vadose zone,theappliedsuction
priate safety, health, and environmental practices and deter- at which water menisci of the porous segment of a suction
mine the applicability of regulatory limitations prior to use. sampler break down, and air enters.
1.6 This guide offers an organized collection of information
3.2.2 bubbling pressure, n—in vadose zone, the applied air
or a series of options and does not recommend a specific
pressure at which water menisci of the porous segment of a
course of action. This document cannot replace education or
suction sampler break down, and air exits.
experienceandshouldbeusedinconjunctionwithprofessional
3.2.3 cascading water, n—in groundwater, perched ground-
judgment. Not all aspects of this guide may be applicable in all
water that enters a well casing via cracks or uncovered
circumstances. This ASTM standard is not intended to repre-
perforations, trickling, or pouring down the inside of the
sent or replace the standard of care by which the adequacy of
casing.
a given professional service must be judged, nor should this
3.2.4 hydrophobicity, n—in vadose zone, the property that
document be applied without consideration of a project’s many
defines a material as being water repellent. Water exhibits an
obtuse contact angle with hydrophobic materials.
1
ThisguideisunderthejurisdictionofASTMCommitteeD18onSoilandRock
and is the direct responsibility of Subcommittee D18.21 on Groundwater and
Vadose Zone Investigations.
2
Current edition approved Nov. 15, 2018. Published November 2018. Originally For referenced ASTM standards, visit the ASTM website, www.astm.org, or
approved in 1992. Last previous edition approved in 2008 as D4696–92(2008), contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
which was withdrawn January 2017 and reinstated in November 2018. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D4696-18. the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International,
...

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