Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete

ABSTRACT
This specification covers coal fly ash and raw or calcined natural pozzolan for use in concrete where cementitious or pozzolanic action, or both, is desired, or where other properties normally attributed to fly ash or pozzolans may be desired, or where both objectives are to be achieved. Fly ash and natural pozzolans shall conform to the prescribed chemical composition requirements and physical requirements. The materials shall be tested for fineness, strength activity index, water requirement, soundness, and autoclave expansion or contraction.
SCOPE
1.1 This specification covers coal fly ash and raw or calcined natural pozzolan for use in concrete where cementitious or pozzolanic action, or both, is desired, or where other properties normally attributed to fly ash or pozzolans may be desired, or where both objectives are to be achieved.  
Note 1: Finely divided materials may tend to reduce the entrained air content of concrete. Hence, if a fly ash or natural pozzolan is added to any concrete for which entrainment of air is specified, provision should be made to ensure that the specified air content is maintained by air content tests and by use of additional air-entraining admixture or use of an air-entraining admixture in combination with air-entraining hydraulic cement. (A) The use of Class F pozzolan containing up to 12.0 % loss on ignition may be approved by the user if either acceptable performance records or laboratory test results are made available.  (A) The strength activity index with portland cement is not to be considered a measure of the compressive strength of concrete containing the fly ash or natural pozzolan. The mass of fly ash or natural pozzolan specified for the test to determine the strength activity index with portland cement is not considered to be the proportion recommended for the concrete to be used in the work. The optimum amount of fly ash or natural pozzolan for any specific project is determined by the required properties of the concrete and other constituents of the concrete and is to be established by testing. Strength  activity index with portland cement is a measure of reactivity with a given cement and is subject to variation depending on the source of both the fly ash or natural pozzolan and the cement.(B) Meeting the 7 day or 28 day strength activity index will indicate specification compliance.(C) If the fly ash or natural pozzolan will constitute more than 20 % by mass of the cementitious material in the project mixture, the test specimens for autoclave expansion shall contain that anticipated percentage. Excessive autoclave expansion is highly significant in cases where water to cementitious material ratios are low, for example, in block or shotcrete mixtures.  (A) Determination of compliance or noncompliance with the requirement relating to increase in drying shrinkage will be made only at the request of the purchaser.(B) Fly ash or natural pozzolan shall be considered effective only when the fly ash or natural pozzolan is used at percentages, by mass, of the total cementitious material within 2 % of those that are successful in the test mixtures or between two percentages that are successful, and when the C3A content of the project cement is less than, or equal to, that which was used in the test mixtures. See Appendix X2 of Test Method C311/C311M.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 The text of this standard references notes and footnotes, which provide explanatory information. These notes and footnotes (excluding those in tables and figures) shall not be considered as requirements of the standard.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Tra...

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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:C618 −17
Standard Specification for
Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use
1
in Concrete
This standard is issued under the fixed designation C618; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope* C311/C311M Test Methods for Sampling and Testing Fly
Ash or Natural Pozzolans for Use in Portland-Cement
1.1 This specification covers coal fly ash and raw or
Concrete
calcined natural pozzolan for use in concrete where cementi-
C1778 Guide for Reducing the Risk of Deleterious Alkali-
tious or pozzolanic action, or both, is desired, or where other
Aggregate Reaction in Concrete
properties normally attributed to fly ash or pozzolans may be
desired, or where both objectives are to be achieved.
3. Terminology
NOTE 1—Finely divided materials may tend to reduce the entrained air
content of concrete. Hence, if a fly ash or natural pozzolan is added to any 3.1 Definitions:
concrete for which entrainment of air is specified, provision should be
3.1.1 The terms used in this specification are defined in
made to ensure that the specified air content is maintained by air content
Terminology C125.
tests and by use of additional air-entraining admixture or use of an
air-entraining admixture in combination with air-entraining hydraulic
3.1.2 fly ash—thefinelydividedresiduethatresultsfromthe
cement.
process of combustion of ground or powdered coal and that is
1.2 The values stated in SI units are to be regarded as transported by flue gasses.
standard. No other units of measurement are included in this
NOTE 2—This definition of fly ash does not include, among other
standard.
things, the residue resulting from: (1) fluidized bed combustion ash, (2)
the burning of municipal solid waste or any other refuse with coal, or (3)
1.3 The text of this standard references notes and footnotes,
the burning of industrial or municipal solid waste in incinerators com-
which provide explanatory information. These notes and foot-
monly known as “incinerator ash.”
notes (excluding those in tables and figures) shall not be
considered as requirements of the standard.
4. Classification
1.4 This international standard was developed in accor-
4.1 Class N—Raw or calcined natural pozzolans that com-
dance with internationally recognized principles on standard-
ization established in the Decision on Principles for the ply with the applicable requirements for the class as given
herein, such as some diatomaceous earths; opaline cherts and
Development of International Standards, Guides and Recom-
mendations issued by the World Trade Organization Technical shales; tuffs and volcanic ashes or pumicites, calcined or
Barriers to Trade (TBT) Committee. uncalcined; and various materials requiring calcination to
induce satisfactory properties, such as some clays and shales.
2. Referenced Documents
4.2 Class F—Fly ash that meets the applicable requirements
2
2.1 ASTM Standards:
for this class as given herein. This class of fly ash has
C125 Terminology Relating to Concrete and Concrete Ag-
pozzolanic properties.
gregates
4.3 Class C—Flyashthatmeetstheapplicablerequirements
for this class as given herein. This class of fly ash, in addition
1
This specification is under the jurisdiction of ASTM Committee C09 on
to having pozzolanic properties, also has some cementitious
Concrete and Concrete Aggregatesand is the direct responsibility of Subcommittee
properties.
C09.24 on Supplementary Cementitious Materials.
Current edition approved Oct. 1, 2017. Published October 2017. Originally
NOTE 3—Class F fly ash is typically produced from burning anthracite
approved in 1968. Last previous edition approved in 2015 as C618–15. DOI:
or bituminous coal, but may also be produced from subbituminous coal
10.1520/C0618-17.
2 andfromlignite.ClassCflyashistypicallyproducedfromburninglignite
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
or subbituminous coal, and may also be produced from anthracite or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on bituminous coal. Class C fly ashes typically have total calcium contents,
the ASTM website. expressed as calcium oxide (CaO), that are higher than Class F fly ashes.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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C61
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: C618 − 15 C618 − 17
Standard Specification for
Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use
1
in Concrete
This standard is issued under the fixed designation C618; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope*
1.1 This specification covers coal fly ash and raw or calcined natural pozzolan for use in concrete where cementitious or
pozzolanic action, or both, is desired, or where other properties normally attributed to fly ash or pozzolans may be desired, or where
both objectives are to be achieved.
NOTE 1—Finely divided materials may tend to reduce the entrained air content of concrete. Hence, if a fly ash or natural pozzolan is added to any
concrete for which entrainment of air is specified, provision should be made to ensure that the specified air content is maintained by air content tests and
by use of additional air-entraining admixture or use of an air-entraining admixture in combination with air-entraining hydraulic cement.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 The text of this standard references notes and footnotes, which provide explanatory information. These notes and footnotes
(excluding those in tables and figures) shall not be considered as requirements of the standard.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
C125 Terminology Relating to Concrete and Concrete Aggregates
C311C311/C311M Test Methods for Sampling and Testing Fly Ash or Natural Pozzolans for Use in Portland-Cement Concrete
C1778 Guide for Reducing the Risk of Deleterious Alkali-Aggregate Reaction in Concrete
3. Terminology
3.1 Definitions:
3.1.1 The terms used in this specification are defined in Terminology C125.
3.1.2 fly ash—the finely divided residue that results from the process of combustion of ground or powdered coal and that is
transported by flue gasses.
NOTE 2—This definition of fly ash does not include, among other things, the residue resulting from: (1) fluidized bed combustion ash, (2) the burning
of municipal solid waste or any other refuse with coal, or (3) the burning of industrial or municipal solid waste in incinerators commonly known as
“incinerator ash.”
4. Classification
4.1 Class N—Raw or calcined natural pozzolans that comply with the applicable requirements for the class as given herein, such
as some diatomaceous earths; opaline cherts and shales; tuffs and volcanic ashes or pumicites, calcined or uncalcined; and various
materials requiring calcination to induce satisfactory properties, such as some clays and shales.
1
This specification is under the jurisdiction of ASTM Committee C09 on Concrete and Concrete Aggregatesand is the direct responsibility of Subcommittee C09.24 on
Supplementary Cementitious Materials.
Current edition approved Aug. 1, 2015Oct. 1, 2017. Published September 2015October 2017. Originally approved in 1968. Last previous edition approved in 20122015
as C618–12a.–15. DOI: 10.1520/C0618-15.10.1520/C0618-17.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
C618 − 17
TABLE 1 Chemical Requirements
Class
N F C
Silicon dioxide (SiO ) plus aluminum oxide (Al O ) plus iron oxide (Fe O ), 70.0 70.0 50.0
2 2 3 2 3
min, %
Sulfur trioxide (SO ), max, % 4.0 5.0 5.0
3
Moisture content, max, % 3.0 3.0 3.0
A
Loss on ignition, max, % 10.0 6.0 6.0
A
The use of Class F pozzolan containing up to 12.0 % loss on ignition may be approved by the user if either acceptable performan
...

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