Standard Test Method for Flash Point by the Equilibrium Method With a Closed-Cup Apparatus

SIGNIFICANCE AND USE
This test method, using a slow rate of heating, provides a uniform temperature throughout the specimen. The slow rate of heating is necessary because of the low thermal conductivity of some liquids such as paints, resins, and related products, and also because of the poor heat transfer by convection in high-viscosity products. Since the specimen is being heated at a reduced rate, the longer time interval between each determination is necessary to reestablish after each flash test the saturation concentration of vapor in the air space above the specimen.
Note 1—ISO 1523 is used in United Nations Recommendations for Transportation of Dangerous Goods and in the International Civil Aviation Organization (ICAO) regulations and for similar regulations in the International Maritime Dangerous Goods (IMDG) code. Test Method D 3941, which is similar to ISO 1523, is used in the United States Department of Transportation (USDOT) regulations. The ICAO and IMDG codes are used for transshipment of hazardous materials through the United States to other countries.
SCOPE
1.1 This test method covers the determination of the flash point of liquids in which the specimen and the air/vapor mixture above it are approximately in temperature equilibrium.
1.2 This test method is limited to a temperature range from 0 to 110°C (32 to 230°F).
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 This standard should be used to measure and describe the properties of material, products, or assemblies in response to heat and flame under controlled laboratory conditions and should not be used to describe or appraise the fire hazard or fire risk of materials, products or assemblies under actual fire conditions. However, results of this test may be used as elements of a fire risk assessment which takes into account all of the factors which are pertinent to an assessment of the fire hazard of a particular end use
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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31-May-2007
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ASTM D3941-90(2007) - Standard Test Method for Flash Point by the Equilibrium Method With a Closed-Cup Apparatus
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D3941 − 90 (Reapproved2007)
Standard Test Method for
Flash Point by the Equilibrium Method With a Closed-Cup
Apparatus
This standard is issued under the fixed designation D3941; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
INTRODUCTION
Test Methods D56 and D93 describe procedures using the Tag Closed Tester and the Pensky-
Martens Tester, respectively. Both test methods depend on a definite rate of temperature increase to
control the precision of the test method. The rate of heating may not in all cases give the accuracy
expected because of low thermal conductivity of certain materials. To reduce this effect, ISO/TC 35,
Paints and Varnishes, and ISO/TC 28, Petroleum Products and Lubricants, have issued ISO 1523 in
which the heating rate is considerably slower. This test method is similar to ISO 1523, but uses
standard ASTM cups, style, and format. Due to the slower heating rate, the time required to make a
determination of a flash point is considerably longer than for Test Methods D56 and D93 but the
accuracy is improved.
1. Scope priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use.
1.1 This test method covers the determination of the flash
point of liquids in which the specimen and the air/vapor
2. Referenced Documents
mixture above it are approximately in temperature equilibrium.
2.1 ASTM Standards:
1.2 This test method is limited to a temperature range from
D56 Test Method for Flash Point by Tag Closed Cup Tester
0 to 110°C (32 to 230°F).
D93 Test Methods for Flash Point by Pensky-Martens
Closed Cup Tester
1.3 The values stated in SI units are to be regarded as the
E1 Specification for ASTM Liquid-in-Glass Thermometers
standard. The values given in parentheses are for information
2.2 ISO Standard:
only.
ISO 1523 Paints, varnishes, petroleum, and related
1.4 This standard should be used to measure and describe
products—Determination of flash point—Closed cup
the properties of material, products, or assemblies in response
equilibrium method
to heat and flame under controlled laboratory conditions and
should not be used to describe or appraise the fire hazard or 3. Terminology
fire risk of materials, products or assemblies under actual fire
3.1 Definitions:
conditions. However, results of this test may be used as
3.1.1 flash point, n—the lowest temperature corrected to a
elements of a fire risk assessment which takes into account all
pressure of 760 mm Hg (101.3 kPa) (1013 millibars) at which
of the factors which are pertinent to an assessment of the fire
application of an ignition source causes the vapor of the
hazard of a particular end use.
specimen to ignite under specified conditions of test.
1.5 This standard does not purport to address all of the
4. Summary of Test Method
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
4.1 Aspecimen is heated in a closed cup of standard design
in a suitable liquid bath at the rate of 0.5°C (1.0°F) in not less
1 2
This test method is under the jurisdiction of ASTM Committee D01 on Paint For referenced ASTM standards, visit the ASTM website, www.astm.org, or
and Related Coatings, Materials, andApplications and is the direct responsibility of contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Subcommittee D01.21 on Chemical Analysis of Paints and Paint Materials. Standards volume information, refer to the standard’s Document Summary page on
Current edition approved June 1, 2007. Published June 2007. Originally the ASTM website.
approved in 1980. Last previous edition approved in 2001 as D3941 – 90 (2001). Available from American National Standards Institute (ANSI), 25 W. 43rd St.,
DOI: 10.1520/D3941-90R07. 4th Floor, New York, NY 10036, http://www.ansi.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D3941 − 90 (2007)
than 1.5 min so that the difference in temperature between the 7. Reagents and Materials
specimen in the cup and bath never exceeds 2.0°C (3.5°F).
7.1 Water or Mixture of Water and Ethylene Glycol (1 + 1)
Flash determinations are made at intervals of not less than 1.5
may be used as a bath liquid.
min.
8. Preparation of Sample
5. Significance and Use
8.1 Obtain a representative sample of the product under test
5.1 This test method, using a slow rate of heating, provides
and keep in an airtight container.
a uniform temperature throughout the specimen. The slow rate
ofheatingisnecessarybecauseofthelowthermalconductivity 8.2 Because of the possibility of loss of volatile constitu-
ofsomeliquidssuchaspaints,resins,andrelatedproducts,and ents, the sample should receive only the minimum treatment to
also because of the poor heat transfer by convection in ensure uniformity. After removing the specimen, immediately
close the sample container tightly to ensure that no volatile
high-viscosity products. Since the specimen is being heated at
a reduced rate, the longer time interval between each determi- flammable components escape from the container (otherwise a
new sample may be necessary if further testing is required).
nation is necessary to reestablish after each flash test the
saturation concentration of vapor in the air space above the
8.3 Do not open containers unnecessarily. Do not make
specimen.
transfers unless the sample temperature is at least 10°C (20°F)
belowtheexpectedflashpoint,exceptformaterialsthataretoo
NOTE 1—ISO 1523 is used in United Nations Recommendations for
TransportationofDangerousGoodsandintheInternationalCivilAviation viscous to be handled at that temperature. In these cases,
Organization (ICAO) regulations and for similar regulations in the
transfer the specimens at the lowest possible temperature at
International Maritime Dangerous Goods (IMDG) code. Test Method
which the material can be accurately measured into the cup.
D3941, which is similar to ISO 1523, is used in the United States
Department of Transportation (USDOT) regulations. The ICAO and
8.4 Discard samples in leaky containers.
IMDG codes are used for transshipment of hazardous materials through
8.5 Do not store samples in plastic (polyethylene, polypro-
the United States to other countries.
pylene, etc.) bottles, since volatile material may diffuse
6. Apparatus
through the walls of the bottles.
6.1 Test Cups, equipped with their lid as specified in Test
9. Preparation of Apparatus
Methods D56 (Tag) and D93 (Pensky-Martens). Remove the
test cup assembly (including lid and specimen thermometer)
9.1 Support the cup and liquid bath on a level steady table.
from the Tag and Pensky-Martens apparatus to permit either to
Unless tests are made in a draft-free room or compartment,
be used in a separate water bath.
surround the tester on three sides by the shield for protection
6.1.1 If a stirrer is fitted to the test cup used, it shall operate
from drafts. Tests made in a laboratory draft hood or near
during the heating period but must be stopped during the
ventilators are not rel
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