Standard Practice for Calculation and Adjustment of the Langelier Saturation Index for Reverse Osmosis (Withdrawn 2019)

SIGNIFICANCE AND USE
In the design and operation of reverse osmosis installations, it is important to predict the calcium carbonate scaling properties of the concentrate stream. Because of the increase in total dissolved solids in the concentrate stream and the difference in passages for calcium ion, bicarbonate ion, and free CO2, the calcium carbonate scaling properties of the concentrate stream will generally be quite different from those of the feed solution. This practice permits the calculation of the Langelier Saturation Index for the concentrate stream from the feed water analyses and the reverse osmosis operating parameters.
A positive Langelier Saturation Index indicates the tendency to form a calcium carbonate scale, which can be damaging to reverse osmosis performance. This practice gives various procedures for the adjustment of the Langelier saturation index.
The tendency to form CaCo3 scale can be suppressed by the addition of antiscalents or crystal modifiers. Suppliers of antisealents and crystal modifiers can provide information on the scale inhibition peformance of these types of chemical. Their use may be appropriate for reducing scale formation in RO systems. The RO system supplier should be consulted prior to the use of antisealents and crystal modifiers to ensure they will not have a negative impact on the RO system.
SCOPE
1.1 This practice covers the calculation and adjustment of the Langelier saturation index for the concentrate stream of a reverse osmosis device. This index is used to determine the need for calcium carbonate scale control in the operation and design of reverse osmosis installations. This practice is applicable for concentrate streams containing xx 10 to 10 000 mg/L of total dissolved solids. For concentrate containing over 10 000 mg/L see Practice D4582.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
WITHDRAWN RATIONALE
This practice covers the calculation and adjustment of the Langelier saturation index for the concentrate stream of a reverse osmosis device.
Formerly under the jurisdiction of Committee D19 on Water, this practice was withdrawn in January 2019 in accordance with section 10.6.3 of the Regulations Governing ASTM Technical Committees, which requires that standards shall be updated by the end of the eighth year since the last approval date.

General Information

Status
Historical
Publication Date
30-Apr-2010
Withdrawal Date
13-Jan-2019
Technical Committee
Current Stage
Ref Project

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ASTM D3739-06(2010) - Standard Practice for Calculation and Adjustment of the Langelier Saturation Index for Reverse Osmosis (Withdrawn 2019)
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D3739 − 06 (Reapproved 2010)
Standard Practice for
Calculation and Adjustment of the Langelier Saturation
1
Index for Reverse Osmosis
This standard is issued under the fixed designation D3739; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D4582 Practice for Calculation and Adjustment of the Stiff
and Davis Stability Index for Reverse Osmosis
1.1 This practice covers the calculation and adjustment of
D6161 Terminology Used for Microfiltration, Ultrafiltration,
the Langelier saturation index for the concentrate stream of a
Nanofiltration and Reverse Osmosis Membrane Processes
reverse osmosis device. This index is used to determine the
need for calcium carbonate scale control in the operation and
3. Terminology
design of reverse osmosis installations. This practice is appli-
3.1 Defintions—For definitions of terms used in this
cable for concentrate streams containing xx 10 to 10 000 mg⁄L
practice, refer toTerminology D1129 andTerminology D6161.
of total dissolved solids. For concentrate containing over
3.2 Definitions of Terms Specific to This Standard:
10 000 mg⁄L see Practice D4582.
3.2.1 For descriptions of terms relating to reverse osmosis,
1.2 The values stated in SI units are to be regarded as
refer to Test Methods D4194.
standard. No other units of measurement are included in this
3.2.2 Langelier Saturation Index—an index calculated from
standard.
total dissolved solids, calcium concentration, total alkalinity,
1.3 This standard does not purport to address all of the
pH, and solution temperature that shows the tendency of a
safety concerns, if any, associated with its use. It is the
water solution to precipitate or dissolve calcium carbonate.
responsibility of the user of this standard to establish appro-
priate safety and health practices and determine the applica- 4. Summary of Practice
bility of regulatory limitations prior to use.
4.1 This practice consists of calculating the Langelier Satu-
ration Index for a reverse osmosis concentrate stream from the
2. Referenced Documents
total dissolved solids, calcium ion content, total alkalinity, pH,
2
2.1 ASTM Standards:
and temperature of the feed solution, and the recovery of the
D511 Test Methods for Calcium and Magnesium In Water reverse osmosis system.
D1067 Test Methods for Acidity or Alkalinity of Water
4.2 This practice also presents techniques to lower the
D1129 Terminology Relating to Water
Langelier Saturation Index by decreasing the recovery, by
D1293 Test Methods for pH of Water
decreasing the calcium content of the feedwater, or by chang-
D1888 MethodsOfTestforParticulateandDissolvedMatter
ing the ratio of total alkalinity to free carbon dioxide in the
3
in Water (Withdrawn 1989)
feedwater.
D4194 Test Methods for Operating Characteristics of Re-
verse Osmosis and Nanofiltration Devices 5. Significance and Use
D4195 Guide for Water Analysis for Reverse Osmosis and
5.1 In the design and operation of reverse osmosis
Nanofiltration Application
installations, it is important to predict the calcium carbonate
scaling properties of the concentrate stream. Because of the
increase in total dissolved solids in the concentrate stream and
1
This practice is under the jurisdiction of ASTM Committee D19 on Water and
the difference in passages for calcium ion, bicarbonate ion, and
is the direct responsibility of Subcommittee D19.08 on Membranes and Ion
free CO , the calcium carbonate scaling properties of the
2
Exchange Materials.
concentrate stream will generally be quite different from those
Current edition approved May 1, 2010. Published May 2010. Originally
approved in 1978. Last previous edition approved in 2006 as D3739 – 06. DOI:
ofthefeedsolution.Thispracticepermitsthecalculationofthe
10.1520/D3739-06R10.
Langelier Saturation Index for the concentrate stream from the
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
feed water analyses and the reverse osmosis operating param-
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on eters.
the ASTM website.
3
5.2 A positive Langelier Saturation Index indicates the
The last approved version of this historical standard is referenced on
www.astm.org. tendency to form a calcium carbonate scale, which can be
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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D3739 − 06 (2010)
osmosis system. For most reverse osmosis devices SP can be consider
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