ASTM D2786-91(2006)

Standard Test Method for Hydrocarbon Types Analysis of Gas-Oil Saturates Fractions by High Ionizing Voltage Mass Spectrometry

SIGNIFICANCE AND USE
A knowledge of the hydrocarbon composition of process streams and petroleum products boiling within the range of 205 to 540°C (400 to 1000°F) is useful in following the effect of changes in process variables, diagnosing the source of plant upsets and in evaluating the effect of changes in composition on product performance properties.
This test method, when used together with Test Method D 3239, provides a detailed analysis of the hydrocarbon composition of such materials.
SCOPE
1.1 This test method covers the determination by high ionizing voltage mass spectrometry of seven saturated hydrocarbon types and one aromatic type in saturate petroleum fractions having average carbon numbers 16 through 32. The saturate types include alkanes (0-rings), single-ring naphthenes, and five fused naphthene types with 2, 3, 4, 5, and 6 rings. The nonsaturate type is monoaromatic. Noncondensed naphthenes are analyzed as single rings. Samples must be nonolefinic and must contain less than 5 volume % monoaromatic. Composition data are in volume percent.
1.2 The values stated in acceptable SI units are to be regarded as the standard. The values given in parentheses are provided for information purposes only.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

• Status: Historical
• Publication Date: 30-Apr-2006
• ICS: 75.080 - Petroleum products in general
• Technical Committee: D02 - Petroleum Products, Liquid Fuels, and Lubricants
• Drafting Committee: D02.04.0M - Mass Spectrometry

Relations

• Replaces: ASTM D2786-91(2001)e1 - Standard Test Method for Hydrocarbon Types Analysis of Gas-Oil Saturates Fractions by High Ionizing Voltage Mass Spectrometry
• Effective Date: 01-May-2006
• Replaced By: ASTM D2786-91(2011) - Standard Test Method for Hydrocarbon Types Analysis of Gas-Oil Saturates Fractions by High Ionizing Voltage Mass Spectrometry
• Effective Date: 01-Oct-2011
• Referred By: ASTM D2549-23 - Standard Test Method for Separation of Representative Aromatics and Nonaromatics Fractions of High-Boiling Oils by Elution Chromatography
• Effective Date: 01-May-2006

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D2786–91(Reapproved 2006)
Standard Test Method for
Hydrocarbon Types Analysis of Gas-Oil Saturates Fractions
by High Ionizing Voltage Mass Spectrometry
This standard is issued under the fixed designation D2786; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope Quantitative Analysis from a Batch Inlet
1.1 This test method covers the determination by high
3. Terminology
ionizing voltage mass spectrometry of seven saturated hydro-
3.1 Definitions of Terms Specific to This Standard:
carbon types and one aromatic type in saturate petroleum
3.1.1 Characteristic Mass Groupings:
fractions having average carbon numbers 16 through 32. The
3.1.1.1
saturate types include alkanes (0-rings), single-ring naph-
( 71 5 71 1 85 1 99 1 113 ~alkanes!. (1)
thenes, and five fused naphthene types with 2, 3, 4, 5, and 6
rings. The nonsaturate type is monoaromatic. Noncondensed
3.1.1.2
naphthenes are analyzed as single rings. Samples must be
( 69 5 69 1 83 1 97 1 111 1 125 1 139 ~12ring!. (2)
nonolefinic and must contain less than 5 volume % monoaro-
3.1.1.3
matic. Composition data are in volume percent.
1.2 The values stated in acceptable SI units are to be
( 109 5 109 1 123 1 137 1 151 1 165 1 179 1 193 ~22ring!.
(3)
regarded as the standard. The values given in parentheses are
provided for information purposes only.
3.1.1.4
1.3 This standard does not purport to address all of the
( 149 5 149 1 163 1 177 1 191 1 205 1 219 1 233 1 247 ~32ring!.
safety concerns, if any, associated with its use. It is the
(4)
responsibility of the user of this standard to establish appro-
3.1.1.5
priate safety and health practices and determine the applica-
( 189 5 189 1 203 1 217 1 231 1 245 1 259 1 273 1 287
bility of regulatory limitations prior to use.
1 301 ~42ring!. (5)
2. Referenced Documents
3.1.1.6
2.1 ASTM Standards:
( 229 5 229 1 243 1 257 1 271 1 285 1 299 1 313 1 327 1 341
D2549 Test Method for Separation of Representative Aro-
1 355 ~52ring!. (6)
matics and Nonaromatics Fractions of High-Boiling Oils
3.1.1.7
by Elution Chromatography
( 269 5 269 1 283 1 297 1 311 1 325 1 339 1 353 1 367 1 381
D3239 Test Method for Aromatic Types Analysis of Gas-
1 395 1 409 ~62ring!. (7)
Oil Aromatic Fractions by High Ionizing Voltage Mass
Spectrometry
3.1.1.8
E137 Practice for Evaluation of Mass Spectrometers for
( 91 5 91 1 105 1 117 1 119 1 129 1 131 1 133 1 143 1 145
1 147 1 157 1 159 1 171 ~monoaromatic!. (8)
4. Summary of Test Method
This test method is under the jurisdiction of ASTM Committee D02 on
Petroleum Products and Lubricants and is the direct responsibility of Subcommittee
4.1 The relative abundance of alkanes (0-ring), 1-ring,
D02.04 on Hydrocarbon Analysis.
2-ring, 3-ring, 4-ring, 5-ring, and 6-ring naphthenes in petro-
Current edition approved May 1, 2006. Published June 2006. Originally
´1
approved in 1969. Last previous edition approved in 2001 as D2786 – 91 (2001) .
leum saturate fractions is determined by mass spectrometry
DOI: 10.1520/D2786-91R06.
using a summation of mass fragment groups most characteris-
Hood, A., and O’Neal, M. J., Advances in Mass Spectrometry, AMSPA,
tic of each molecular type. Calculations are carried out by the
Waldron, 1959, p. 175.
use of inverted matrices (derived from ion intensity calibration
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. Withdrawn.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
D2786–91 (2006)
sensitivities) that are specific for any average carbon number. 6.2 Sample Inlet System—Any inlet system may be used
The saturate fraction is obtained by liquid elution chromatog- that permits the introduction of the sample without loss,
raphy, see Test Method D2549.
contamination, or change in composition. The system must
function in the range from 125 to 350°C to provide an
5. Significance and Use
appropriate sampling device.
5.1 Aknowledgeofthehydrocarboncompositionofprocess
6.3 Microburet or Constant-Volume Pipet.
streamsandpetroleumproductsboilingwithintherangeof205
to 540°C (400 to 1000°F) is useful in following the effect of
7. Reagents
changes in process variables, diagnosing the source of plant
upsets and in evaluating the effect of changes in composition
7.1 n-Hexadecane.(Warning—Combustible. Vapor harm-
on product performance properties.
ful.)
5.2 This test method, when used together with Test Method
D3239, provides a detailed analysis of the hydrocarbon com-
8. Calibration
position of such materials.
8.1 Calibration matrix inverses are attached in Table 1
6. Apparatus
which may be used directly provided the following procedures
6.1 Mass Spectrometer—The suitability of the mass spec- are followed.
trometer to be used with this method shall be proven by
performance tests described both herein and in Practice E137.
TABLE 1 Calibration Matrix Inverses
(71 ( 69 ( 109 ( 149 ( 189 ( 229 ( 269 (91
C Inverse
n-Alkanes
0 Ring 0.5344 −0.0292 −0.0066 0.0215 0.0299 . . −0.0151
1 Ring −0.0610 0.3403 −0.2146 −0.1162 −0.0362 . . −0.0112
2 Ring −0.0039 0.0170 0.8491 −0.6968 −0.3420 . . −0.0048
3 Ring 0.0000 −0.0004 + 0.0115 1.7220 −1.3545 . . 0.0152
4 Ring 0.0001 0.0004 0.0039 −0.0138 3.2594 . . −0.0485
MA −0.0007 −0.0029 −0.0237 −0.1566 −0.3494 . . 0.3521
Isoalkanes
0 Ring 0.6543 −0.0358 −0.0081 0.0264 0.0366 . . −0.0185
1 Ring −0.0866 0.3416 −0.2143 −0.1171 −0.0377 . . −0.0101
2 Ring −0.0053 0.0172 0.8492 −0.6968 −0.3420 . . −0.0046
3 Ring 0.0001 −0.0004 0.0115 1.7220 −1.3545 . . 0.0152
4 Ring 0.0000 0.0004 0.0039 −0.0138 3.2594 . . −0.0485
MA 0.0001 −0.0029 −0.0237 −0.1565 −0.3493 . . 0.3521
C Inverse
n-Alkanes
0 Ring 0.5243 −0.0311 −0.0075 0.0227 0.0322 . . −0.0163
1 Ring −0.0660 0.3403 −0.2130 −0.1164 −0.0385 . . −0.0121
2 Ring −0.0038 0.0154 0.8375 −0.6826 −0.3318 . . −0.0052
3 Ring 0.0000 −0.0004 0.0095 1.6824 −1.3111 . . 0.0166
4 Ring 0.0001 0.0004 0.0039 −0.0147 3.1247 . . −0.0527
MA −0.0007 −0.0027 −0.0220 −0.1514 −0.3331 . . 0.3612
Isoalkanes
0 Ring 0.6435 −0.0382 −0.0092 0.0279 0.0395 . . −0.0200
1 Ring −0.0942 0.3418 −0.2125 −0.1176 −0.0403 . . −0.0112
2 Ring −0.0054 0.0155 0.8375 −0.6826 −0.3319 . . −0.0052
3 Ring 0.0000 −0.0002 0.0090 1.6825 −1.3111 . . 0.0166
4 Ring 0.0000 0.0004 0.0040 −0.0147 3.1247 . . −0.0527
MA 0.0000 −0.0027 −0.0220 −0.1514 −0.3331 . . 0.3612
C Inverse
n-Alkanes
0 Ring 0.5175 −0.0338 −0.0085 0.0234 0.0344 . . −0.0178
1 Ring −0.0720 0.3404 −0.2091 −0.1183 −0.0404 . . −0.0136
2 Ring −0.0039 0.0138 0.8183 −0.6626 −0.3213 . . −0.0057
3 Ring 0.0000 −0.0003 0.0062 1.6426 −1.2784 . . 0.0179
4 Ring 0.0001 0.0004 0.0040 −0.0158 3.0158 . . −0.0567
MA −0.0007 −0.0025 −0.0206 −0.1445 −0.3010 . . 0.3677
Isoalkanes
0 Ring 0.6335 −0.0414 −0.0103 0.0286 0.0422 . . −0.0215
1 Ring −0.1016 0.3424 −0.2086 −0.1197 −0.0424 . . −0.0126
2 Ring −0.0054 0.0140 0.8184 −0.6626 −0.3214 . . −0.0056
3 Ring 0.0000 −0.0003 0.0062 1.6426 −1.2784 . . 0.0179
4 Ring 0.0000 0.0004 0.0040 −0.0158 3.0158 . . −0.0566
MA −0.0002 −0.0025 −0.0206 −0.1445 −0.3200 . . 0.3677
D2786–91 (2006)
TABLE 1 Continued
(71 ( 69 ( 109 ( 149 ( 189 ( 229 ( 269 (91
C Inverse
n-Alkanes
0 Ring 0.5109 −0.0363 −0.0094 0.0202 0.0404 . . −0.0190
1 Ring −0.0773 0.3396 −0.2080 −0.1161 −0.0413 . . −0.0154
2 Ring −0.0038 0.0118 0.8076 −0.6491 −0.3184 . . −0.0061
3 Ring 0.0000 −0.0003 0.0032 1.6068 −1.2432 . . 0.0193
4 Ring 0.0001 0.0004 0.0041 −0.0179 2.9192 . . −0.0614
MA −0.0008 −0.0023 −0.0192 −0.1369 −0.2980 . . 0.3764
Isoalkanes
0 Ring 0.6239 −0.0443 −0.0115 0.0246 0.0494 . . −0.0232
1 Ring −0.1079 0.3418 −0.2073 −0.1173 −0.0438 . . −0.0142
2 Ring −0.0053 0.0120 0.8077 −0.6493 −0.3184 . . −0.0061
3 Ring 0.0000 −0.0002 0.0030 1.6068 −1.2432 . . 0.0193
4 Ring 0.0001 0.0004 0.0041 −0.0179 2.9192 . . −0.0614
MA −0.0004 −0.0023 −0.0192 −0.1369 −0.2980 . . 0.3764
C Inverse
n-Alkanes
0 Ring 0.5099 −0.0397 0.0105 0.0183 0.0458 0.0412 . −0.0223
1 Ring −0.0835 0.3403 −0.2066 −0.1137 −0.0418 0.0375 . −0.0190
2 Ring −0.0036 0.0097 0.7972 −0.6412 −0.3106 −0.1542 . 0.0000
3 Ring 0.0000 −0.0003 −0.0014 1.5634 −1.2179 −0.5944 . 0.0468
4 Ring 0.0000 0.0000 0.0012 −0.0409 2.7690 −1.4656 . −0.0029
5 Ring 0.0004 0.001 0.0085 0.0630 0.0996 4.2055 . −0.1831
MA −0.0008 −0.0022 −0.0188 −0.1382 −0.2910 −0.4521 . 0.4049
Isoalkanes
0 Ring 0.6188 −0.0481 −0.0127 0.0222 0.0555 0.0499 . −0.0270
1 Ring −0.1151 0.3427 −0.2059 −0.1149 −0.0446 0.0350 . −0.0176
2 Ring −0.0051 0.0098 0.7972 −0.6412 −0.3107 −0.1544 . 0.0001
3 Ring 0.0001 −0.0003 −0.0014 1.5634 −1.2179 −0.5944 . 0.0468
4 Ring 0.0000 0.0000 0.0012 −0.0409 2.7690 −1.4656 . −0.0029
5 Ring 0.0003 0.0010 0.0085 0.0630 0.0996 4.2054 . −0.1831
MA −0.0007 −0.0022 −0.0188 −0.1382 −0.2910 −0.4521 . 0.4049
C Inverse
n-Alkanes
0 Ring 0.5077 −0.0431 −0.0119 0.0195 0.0454 0.0441 . −0.0242
1 Ring −0.0888 0.3393 −0.2025 −0.1147 −0.0429 0.0334 . −0.0212
2 Ring −0.0033 0.0074 0.7808 −0.6176 −0.3082 −0.1470 . −0.0003
3 Ring −0.0001 −0.0002 −0.0037 1.5192 −1.1698 −0.5596 . 0.0483
4 Ring 0.0000 0.0000 0.0014 −0.0416 2.6715 −1.4243 . −0.0056
5 Ring 0.0004 0.0009 0.0078 0.0592 0.0898 3.9781 . −0.1851
MA −0.0009 −0.0020 −0.0173 −0.1308 −0.2717 −0.4172 . −0.4123
Isoalkanes
0 Ring 0.6140 −0.0522 −0.0144 0.0235 0.0550 0.0533 . −0.0292
1 Ring −0.1216 0.3421 −0.2016 −0.1158 −0.0458 0.0305 . −0.0196
2 Ring −0.0048 0.0076 0.7811 −0.6176 −0.3082 −0.1472 . −0.0001
3 Ring −0.0001 −0.0002 −0.0037 1.5192 −1.1698 −0.5596 . 0.0483
4 Ring 0.0000 0.0000 0.0014 −0.0416 2.6715 −1.4232 . −0.0056
5 Ring 0.0005 0.0009 0.0078 0.0592 0.0893 3.9781 . −0.1851
MA −0.0010 −0.0020 −0.0173 −0.1308 −0.2717 −0.4172 . 0.4123
C Inverse
n-Alkanes
0 Ring 0.5084 −0.0474 −0.0133 0.0210 0.0435 0.0484 . −0.0263
1 Ring −0.0946 0.3397 −0.1995 −0.1145 −0.0440 0.0307 . −0.0240
2 Ring −0.0030 0.0050 0.7661 −0.6016 −0.3016 −0.1444 . −0.0005
3 Ring −0.0002 0.0000 −0.0072 1.4778 −1.1214 −0.5559 . 0.0517
4 Ring 0.0000 0.0000 0.0018 −0.0411 2.5629 −1.3179 . −0.0117
5 Ring 0.0004 0.0008 0.0072 0.0564 0.0829 3.7619 . −0.1890
MA −0.0010 −0.0018 −0.0161 −0.1252 −0.2574 −0.3897 . 0.4237
Isoalkanes
0 Ring 0.6096 0.0568 −0.0160 0.0252 0.0521 0.0580 . −0.0316
1 Ring −0.1267 0.3427 −0.1986 −0.1158 −0.0468 0.0277 . −0.0223
2 Ring −0.0044 0.0053 0.7662 −0.6016 −0.3018 −0.1445 . −0.0004
3 Ring −0.0003 0.0000 −0.0072 1.4778 −1.1213 −0.5559 . 0.0517
4 Ring 0.0001 0.0000 0.0018 −0.0411 2.5629 −1.3179 . −0.0177
5 Ring 0.0007 0.0008 0.0072 0.0564 0.0829 3.7619 . −0.1890
MA −0.0015 −0.0018 −0.0161 −0.1253 −0.2574 −0.3897 . 0.4238
D2786–91 (2006)
TABLE 1 Continued
(71 ( 69 ( 109 ( 149 ( 189 ( 229 ( 269 (91
C Inverse
n-Alkanes
0 Ring 0.5093 −0.0518 −0.0153 0.0226 0.0407 0.0521 . −0.0285
1 Ring −0.1003 0.3404 −0.1976 −0.1142 −0.0446 0.0282 . −0.0269
2 Ring −0.0024 0.0021 0.7580 −0.5880 −0.3011 −0.1405 . −0.0008
3 Ring −0.0002 0.0001 −0.0103 1.4393 −1.0839 −0.5414 . 0.0542
4 Ring 0.0001 0.0000 0.0020 −0.0425 2.4806 −1.2840 . −0.0149
5 Ring 0.0005 0.0007 0.0066 0.0539 0.0750 3.6015 . −0.1927
MA −0.0011 −0.0017 −0.0148 −0.1189 −0.2409 −0.3560 . 0.4300
Isoalkanes
0 Ring 0.6093 −0.0619 −0.0183 0.0270 0.0487 0.0624 . −0.0341
1 Ring −0.1338 0.3439 −0.1965 −0.1156 −0.0473 0.0248 . −0.0250
2 Ring −0.0038 0.0023 0.7580 −0.5882 −0.3013 −0.1406 . −0.0008
3 Ring −0.0004 0.0001 −0.0103 1.4393 −1.0839 −0.5415 . 0.0542
4 Ring 0.0001 0.0000 0.0020 −0.0426 2.4806 −1.2840 . −0.0149
5 Ring 0.0009 0.0007 0.0066 0.0539 0.0750 3.6016 . −0.1927
MA −0.0190 −0.0016 −0.0148 −0.1189 −0.2410 −0.3561 . 0.4300
C Inverse
n-Alkanes
0 Ring 0.5105 −0.0566 −0.0174 0.0249 0.0434 0.0528 0.0372 −0.0324
1 Ring −0.1061 0.3414 −0.1960 −0.1128 −0.0420 0.0288 0.0761 −0.0337
2 Ring −0.0016 −0.0011 0.7505 −0.5807 −0.2908 −0.1418 0.0047 −0.0011
3 Ring −0.0003 0.0004 −0.0146 1.4098 −1.0564 −0.5371 −0.2987 0.0706
4 Ring 0.0000 −0.0001 0.0014 −0.0506 2.3673 −1.2328 −0.6560 0.0085
5 Ring 0.0004 0.0005 0.0048 0.0407 0.0457 3.3827 −0.9376 −0.1544
6 Ring 0.0005 0.0006 0.0055 0.0457 0.0911 0.1138 3.9809 −0.1763
MA −0.0012 −0.0015 −0.0143 −0.1190 −0.2369 −0.3388 −0.4136 0.4594
Isoalkanes
0 Ring 0.6094 −0.0675 −0.0208 0.0297 0.0518 0.0631 0.0444 −0.0397
1 Ring −0.1403 0.3451 −0.1948 −0.1145 −0.0449 0.0253 0.0736 −0.0315
2 Ring −0.0032 −0.0009 0.7506 −0.5808 −0.2910 −0.1420 0.0045 −0.0010
3 Ring −0.0006 0.0004 −0.0145 1.4098 −1.0564 −0.5352 −0.2986 0.0706
4 Ring 0.0000 −0.0001 0.0014 −0.0506 2.3673 −1.2328 −0.6560 0.0085
5 Ring 0.0009 0.0005 0.0048 0.0407 0.0457 3.3828 −0.9376 −0.1544
6 Ring 0.0010 0.0005 0.0055 0.0457 0.0911 0.1139 3.9809 −0.1764
MA −0.0026 −0.0014 −0.0142 −0.1190 −0.2370 −0.3389 −0.4137 0.4595
C Inverse
n-Alkanes
0 Ring 0.5132 −0.0621 −0.0196 0.0262 0.0471 0.0493 0.0383 −0.0344
1 Ring −0.1115 0.3425 −0.1930 −0.1133 −0.0435 0.0302 0.0753 −0.0380
2 Ring −0.0009 −0.0040 0.7378 −0.5623 −0.2821 −0.1450 −0.0032 −0.0005
3 Ring −0.0005 0.0006 −0.0185 1.3763 −1.0229 −0.5229 −0.2858 0.0741
4 Ring 0.0000 −0.0001 0.0019 −0.0520 2.2834 −1.1777 −0.6213 0.0034
5 Ring 0.0005 0.0005 0.0043 0.0389 0.0409 3.2347 −0.8915 −0.1577
6 Ring 0.0005 0.0005 0.0048 0.0424 0.0836 0.1304 3.7174 −0.1753
MA −0.0013 −0.0014 −0.0128 −0.1125 −0.2213 −0.3157 −0.3738 0.4652
Isoalkanes
0 Ring 0.6096 −0.0738 −0.0233 0.0311 0.0559 0.0586 0.0455 −0.0409
1 Ring −0.1449 0.3465 −0.1918 −0.1150 −0.0461 0.0256 0.0727 −0.0358
2 Ring −0.0023 −0.0039 0.7378 −0.5624 −0.2821 −0.1452 −0.0032 −0.0005
3 Ring −0.0008 0.0007 −0.0185 1.3762 −1.0229 −0.5229 −0.2857 0.0741
4 Ring 0.0000 −0.0001 0.0019 −0.0520 2.2834 −1.1777 −0.6213 0.0034
5 Ring 0.0011 0.0004 0.0043 0.0389 0.0410 3.2347 −0.8914 −0.1578
6 Ring 0.0012 0.0004 0.0048 0.0424 0.0836 0.1034 3.7175 −0.1754
MA −0.0032 −0.0012 −0.0127 −0.1126 −0.2215 −0.3159 −0.3740 0.4653
C Inverse
n-Alkanes
0 Ring 0.5161 −0.0679 −0.0225 0.0282 0.0500 0.0496 0.0388 −0.0369
1 Ring −0.1166 0.3429 −0.1912 −0.1146 −0.0445 0.0291 0.0764 −0.0425
2 Ring 0.0003 −0.0080 0.7313 −0.5486 −0.2776 −0.1391 −0.0096 −0.0006
3 Ring −0.0005 0.0010 −0.0225 1.344
...