ASTM D6161-98
(Terminology)Standard Terminology Used for Crossflow Microfiltration, Ultrafiltration, Nanofiltration, and Reverse Osmosis Membrane Processes
Standard Terminology Used for Crossflow Microfiltration, Ultrafiltration, Nanofiltration, and Reverse Osmosis Membrane Processes
SCOPE
1.1 This terminology covers the use of crossflow microfiltration, ultrafiltration, nanofiltration and reverse osmosis for membrane separation processes.
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An American National Standard
Designation: D 6161 â 98
Standard Terminology
Used for CrossďŹow MicroďŹltration, UltraďŹltration,
NanoďŹltration and Reverse Osmosis Membrane Processes
This standard is issued under the ďŹxed designation D6161; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope the assumed or accepted true value, and includes both
precision and bias.
1.1 This terminology covers the use of crossďŹow microďŹl-
acetylationâsubstitution of an acetyl radical for an active
tration, ultraďŹltration, nanoďŹltration and reverse osmosis for
hydrogen. SpeciďŹcally, formation of cellulose acetate from
membrane separation processes.
cellulose.
2. Referenced Documents acidityâthe quantitative capacity of aqueous media to react
with hydroxyl ions.
2.1 ASTM Standards:
activated carbonâgranulated or powdered activated carbon
D1129 Terminology Relating to Water
usedtoremovetastes,odor,chlorine,chloramines,andsome
D2035 Practice for Coagulation-Flocculation Jar Test of
organics from water. A family of carbonaceous substances
Water
manufactured by processes that develop adsorptive proper-
3. SigniďŹcance and Use
ties.
adsorptionâthe holding of a substance onto the surface of a
3.1 The need to understand the relationships found in
solid by chemical surface forces, without forming new
membraneunitprocessesforwatertreatmentincreaseswiththe
chemical bonds.
continuing demand for these separation systems. DeďŹning the
aerobic bacteriaâbacteria that require oxygen for growth.
terms common to crossďŹow microďŹltration, ultraďŹltration,
See bacteria, aerobes.
nanoďŹltration and reverse osmosis processes assist the manu-
aggregateâgranular material such as sand, gravel, crushed
facturer, consultant and end-user in eliminating inter-process
stone.
terminology confusion.
air scourâdistributing air over the entire ďŹlter area at the
4. Terminology
bottom of a ďŹlter media ďŹowing upward to improve the
effectiveness of backwashing or to permit the use of lower
4.1 DeďŹnitions:
backwash water ďŹow rate, or both.
absorptionâthe holding of a substance within a solid by
algaeâany of a group of chieďŹy aquatic mono cellular plants
cohesive or capillary forces.
with chlorophyll often masked by a brown or red pigment.
accumulatorâa pulsation dampener installed on the suction
alkalinityâthequantitativecapacityofaqueousmediatoreact
and/or discharge lines of pumps, generally plunger type, to
with hydrogen ions. âMâ alkalinity is that which will react
minimize pressure surges and provide uniformity of ďŹow.
with acid as the pH of the sample is reduced to the
accuracyâthe closeness of agreement between an observed
methylorange endpoint of about 4.5. âPâ alkalinity is that
value and an accepted reference value. Where an accepted
which reacts with acid as the pH of the sample is reduced to
reference value is not available, a measure of the degree of
the phenolphthalein end point of 8.3.â Mâ is the total
conformity of a value generated by a speciďŹc procedure to
alkalinity which is the sum of hydroxide plus carbonate plus
bicarbonate contents, âPâ includes all the hydroxyl and half
the carbonate content.
alumâaluminum sulfate, AL (SO ) XH O (X = 14-18), a
2 4 3 2
This terminology is under the jurisdiction ofASTM Committee D-19 onWater
coagulant.
and is the direct responsibility of Subcommittee D19.08 on Membranes and Ion
Exchange Materials.
ambient temperatureâthe temperature of the surroundings,
CurrenteditionapprovedMarch10,1998.PublishedDecember1998.Originally
typically 20°â 25°C.
published as D 6161 â 97. Last previous edition D 6161â97.
2 amorphousânon crystalline, devoid of regular cohesive
Annual Book of ASTM Standards, Vol 11.01.
Annual Book of ASTM Standards, Vol 11.02. structure.
Copyright ŠASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA19428-2959, United States.
D6161â98
anaerobicbacteriaâbacteria that do not use oxygen. Oxygen dispersed in soil, water, organic matter, and the bodies of
is toxic to them. See bacteria, anaerobes. plants and animals. Either autotrophic (self-sustaining, self-
amphotericâcapable of acting as an acid or a base. generative), saprophytic (derives nutrition from non-living
â10 â4
angstrom (A)âa unit of length equaling 10 metres, 10 Âľ organic material already present in the environment), or
â8 â9
metres, 10 centimetres and 3.937 3 10 in. The symbol parasitic (deriving nutrition from another living organism).
is Ă
, A or A.U. . Often symbiotic (advantageous) in man, but sometimes
anionânegatively charged ion. pathogenic.
anion exchange materialâa material capable of the revers- bactericideâagent capable of killing bacteria.
ible exchange of negatively charged ions. bacteriostatâsubstance that prevents bacterial growth and
anisotropic membraneâa nonuniform structure in cross- metabolism but does not necessarily kill them.
section; typically the support substructure has pores much bankâa grouping of devices. See array, block, train.
2 2
larger than the barrier layer. See asymmetric membranes. barâunitofpressure;14.50lbs/in. ,1.020kg/cm ,0.987atm,
anodeâpositive electrode. 0.1 MPa.
anionic polyelectrolyteâusually acrylamide and acrylamide BATâbest available technology.
â˘
and acrylic copolymers, negatively charged, used for baume scale,Beâa measure of the density of a solution
coagulation/ďŹocculation, see Polyelectrolytes. relative to water.
anthraciteâa granular hard coal used as a ďŹltration media,
â˘
BE 5145 2
commonly used as the coarser layer in dual and multimedia
speciďŹcgravity*
ďŹlters.
United States for densities greater than unity.
antifoulantâsee antiscalant.
antiscalantâa compound added to a water which inhibits the â˘
BE 5 2130
speciďŹcgravity*
precipitation of sparingly soluble inorganic salts.
anti-telescoping deviceâa plastic or metal device attached to For densities less than unity.
the ends of a spiral wound cartridge to prevent movement of *60°F/60°F
the cartridge leaves in the feed ďŹow direction, due to high bed depthâthe depth of the ďŹlter medium or ion exchange
feed ďŹows. resin in a vessel.
AOCâassimilable organic carbon. bed expansionâthe depth increase of ďŹlter medium or ion
aquiferâa water-bearing geological formation that provides a exchange resin that occurs during backwashing.
ground water reservoir. bindersâin reference to cartridge ďŹlters, chemicals used to
aramidâa fully aromatic polyamide. hold, or 8bindâ, short ďŹbers together in a ďŹlter.
arrayâanarrangementofdevicesconnectedtocommonfeed, biocideâa substance that kills all living organisms.
product and reject headers; that is, a 2:1 array. biologicaldepositsâthedebrisleftbyorganismsasaresultof
asymmetric membraneâmembrane which has a change in their life processes.
pore structure with depth. See anisotropic membranes. biomassâany material which is or was a living organism or
ATDâsee anti-telescoping device.
excreted from a micro-organism.
atomicweightâthe relative mass of an atom based on a scale biostatâa substance that inhibits biological growth.
in which a speciďŹc carbon atom (carbon 12) is assigned a
bindingâin surface ďŹltration, a build-up of particulates on the
mass value of 12. ďŹlter, restricting ďŹuid ďŹow through the ďŹlter at normal
ATPâadenosine triphosphate. pressures.
autopsyâthe dissection of a membrane module or element to blockâa grouping of devices in a single unit having common
investigate causes of unsatisfactory performance. control. See array, bank, train.
availabilityâtheon-streamtimeorratedoperatingcapacityof BOD (biochemical oxygen demand)âthe amount of dis-
a water treatment system. solved oxygen utilized by natural agencies in water in
a-valueâmembrane water permeability coefficient. The coef- stabilizing organic matter at speciďŹed test conditions.
ďŹcient is deďŹned as the amount of water produced per unit body feedâthe continuous addition of ďŹlter medium (for
area of membrane when net driving pressure (NDP) is unity, example, diatomaceous earth) to sustain the efficacy of the
3 2
a unit of measurement is m /hr/m /kPa. ďŹlter.
AWWAâAmerican Water Works Association. BOOâbuild, own, operate.
AWWARFâAmerican Water Works Association Research BOOTâbuild, own, operate and transfer.
Foundation. boundary layerâa thin layer at the membrane surface where
backwashâreverse the ďŹow of water with/without air either water velocities deviate signiďŹcantly less than those in the
across or through a medium or membrane designed to bulk ďŹow.
remove the collected foreign material from the bed or brackish waterâwater with an approximate concentration of
membranes.
totaldissolvedsolidsrangingfrom1000to10000mg/L.See
bacteriaâany of a class of microscopic single-celled organ- high brackish water, sea water.
isms reproducing by ďŹssion or by spores. Characterized by
breakpoint chlorinationâthe point at which the water chlo-
round, rod-like spiral or ďŹlamentous bodies, often aggre- rine demand is satisďŹed and any further chlorine is the
gated into colonies or mobile by means of ďŹagella. Widely chlorine residual, the âfreeâ chlorine species.
D6161â98
breaktankâa storage device used for hydraulic isolation and cathodeânegative electrode.
surge protection. cationâpositively charged ion.
brineâthe concentrate (reject) stream from a crossďŹow mem- cation exchange materialâa material capable of the revers-
brane device performing desalination. Portion of the feed ible exchange of positively charged ions.
stream which does not pass through the membrane. cationic polyelectrolyteâa polymer containing positively
brine(concentrate)sealâa rubber lip seal on the outside of a charged groups used for coagulation/ďŹocculation, usually
spiral wound cartridge which prevents feed by-pass between dimethyl - aminoethyl methacrylate or dimethyl-aminoethyl
the cartridge and the inside pressure vessel wall. acrylate. See polyelectrolyte.
brine seal carrierâsee ATD. celluloseâan amorphous carbohydrate (C H O ) that is the
6 10 5
brine system stagingâa process in which the concentrate, principal constituent of wood and plants.
under pressure, of a group of membrane devices is fed cellulose acetate (CA)âin the broad sense, any of several
directly to another set of membrane devices to improve the esters of cellulose and acetic acid.
efficiency of the water separation. celsius (°C)âthe designation of the degree on the Interna-
bubble point pressureâthe pressure necessary to displace a tional Practical Temperature Scale. Formerly called centi-
liquid held by surface tension forces from the largest grade,°C=K minus 273.15. K = Kelvin.
equivalent capillaries in a membrane ďŹlter. centigradeâsince 1948, now called Celsius, a temperature
bubblepointtestâa nondestructive membrane ďŹlter test used scale.
to assess ďŹlter integrity and proper installation. ceramic membraneâgenerally a glass, silica, alumina, or
bundleâageneraltermforacollectionofparallelďŹlamentsor carbon based membrane. Generally used in micro and
ďŹbres. ultraďŹltration.They tend to withstand high temperatures and
B-valueâsalt diffusion coefficientâ The coefficient is de- widepHrangesandbemorechemicallyinertthanpolymeric
ďŹned as the amount of salt transferred per unit area of membranes.
membrane when the difference in salt concentration across CFUâcolony forming unit; unit used in the measure of total
the membrane is unity. A unit of measurement is m/h. bacteria count (TBC).
BWROâbrackish water reverse osmosis. channelingâunequal ďŹow distribution in the desalination
CACâcombined available chlorine. bundle or ďŹlter bed.
calciumcarbonateequivalents(mg/LasCaCO )âamethod chelatingagentsâasequesteringorcomplexingagentthat,in
for expressing mg/L as ion in terms of calcium carbonate. aqueous solution, renders a metallic ion inactive through the
Concentrationincalciumcarbonateequivalentsiscalculated formation of an inner ring structure with the ion.
by multiplying concentration in mg/L of the ion by the chemical feed pumpâa pump used to meter chemicals, such
equivalentweightofcalciumcarbonate(50)anddividingby as chlorine of polyphosphate, into a feed water supply.
the equivalent weight of the ion. (See Table 1). chloramineâacombinationofchlorineandammoniainwater
carbonate hardnessâthe hardness in a water caused by which has bactericidal qualities for a longer time than does
carbonatesandbicarbonatesofcalciumandmagnesium.The free chlorine.
amount of hardness equivalent to the alkalinity formed and chlorineâchemical used for its qualities as a bleaching or
deposited when water is boiled. In boilers, carbonate hard- oxidizing agent and disinfectant in water puriďŹcation.
ness is readily removed by blowdown. chlorinedemandâtheamountofchlorineusedupbyreacting
calcium hypochloriteâCa (HCIO) , a disinfection agent. with oxidizable substances in water before chlorine residual
cartridgeâsee spiral-wound cartridge. can be measured.
catalystâa substance whose presence initiates or changes the chlorine, residualâthe amount of available chlorine present
rate of a chemical reaction, but does not itself enter into the in water at any speciďŹed time.
reaction. chlorine,freeavailableâthechlorine(Cl ),hypochloriteions
A,B
TABLE 1 Conversion Factors
mg/l mg/l Clark or Grain per French German EPM Atomic
as Ion as CaCO English Degree US Gallon Degree Degree MEQ/L Weight
Ca++ 2.495 0.175 0.0583 0.250 0.140 0.0499 40.08
Mg++ 4.112 0.288 0.0583 0.411 0.231 0.0823 24.32
Na+ 2.175 0.152 0.0583 0.218 0.122 0.0435 22.99
K+ 1.279 0.089 0.0583 0.128 0.072 0.0256 39.10
Sr++ 1.141 0.080 0.0583 0.114 0.064 0.0288 87.63
Ba++ 0.728 0.051 0.0583 0.073 0.041 0.0146 137.36
Fe++ 1.791 0.125 0.0583 0.179 0.101 0.0358 55.85
â
HCO3 0.819 0.057 0.0583 0.082 0.046 0.0164 61.02
SO 1.041 0.073 0.0583 0.104 0.058 0.0208 96.07
4â
â
Cl 1.410 0.098 0.0583 0.141 0.079 0.0282 35.46
â
F 2.632 0.184 0.0583 0.263 0.148 0.0526 19.00
â
NO 0.806 0.056 0.0583 0.081 0.045 0.0161 62.00
ââ
CO 1.666 0.117 0.0583 0.167 0.094 0.0323 60.01
âââ
PO 1.579 0.110 0.0583 0.158 0.089 0.0316 94.98
A
To convert from mg/l as ion to any other unit multiply by factor.
B
To convert to mg/l as ion from any other unit divide by factor.
D6161â98
â
C ~brinewater concentration!
(OCl ), hypochlorous acid (HOCl) or the combination
B
CF 5
C ~feedwater concentration!
thereof present in water. F
chlorine, total availableâthe sum of free available chlorine
plus chloramines present in water.
5 ~approximation!
1 2conversion
CIPâcleaning-in-place.
concentration polarizationâthe increase of the
...
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