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ASTM D4209-07

(Practice)

Standard Practice for Determining Volatile and Nonvolatile Content of Cellulosics, Emulsions, Resin Solutions, Shellac, and Varnishes

Standard Practice for Determining Volatile and Nonvolatile Content of Cellulosics, Emulsions, Resin Solutions, Shellac, and Varnishes

SIGNIFICANCE AND USE
The nonvolatile content of raw materials may be used to determine the total nonvolatile content (solids) of paint and related coatings. Such information may be useful to coatings producers and users for the determination of the total solids available for film formation and for the estimation of the volatile organic content.
SCOPE
1.1 This practice is intended to serve as a guide to the selection of the proper ASTM test method for determining the volatile and nonvolatile content of cellulosics, emulsions, resin solutions, shellac, and varnishes. Note 1 - Standards for determining the composition of the volatile fraction are not covered by this practice.
1.2 The standards referenced in the practice are as follows:ClassificationSectionASTM StandardCellulosicsD 871 D 914D 1347EmulsionsD 2369Resin SolutionsD 1259 D 1490ShellacD 29 D 1650VarnishesD 115 D 1644
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

General Information

Status
Historical
Publication Date
30-Jun-2007
ICS
87.060.20 - Binders
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.21 - Chemical Analysis of Paints and Paint Materials
Current Stage
Ref Project

Relations

Replaces
ASTM D4209-82(2002) - Standard Practice for Determining Volatile and Nonvolatile Content of Cellulosics, Emulsions, Resin Solutions, Shellac, and Varnishes
Effective Date
01-Jul-2007
Referred By
ASTM D16-23 - Standard Terminology for Paint, Related Coatings, Materials, and Applications
Effective Date
01-Jul-2007

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ASTM D4209-07 - Standard Practice for Determining Volatile and Nonvolatile Content of Cellulosics, Emulsions, Resin Solutions, Shellac, and VarnishesASTM D4209-07 - Standard Practice for Determining Volatile and Nonvolatile Content of Cellulosics, Emulsions, Resin Solutions, Shellac, and Varnishes
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ASTM D4209-07 - Standard Practice for Determining Volatile and Nonvolatile Content of Cellulosics, Emulsions, Resin Solutions, Shellac, and Varnishes
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D4209 − 07
StandardPractice for
Determining Volatile and Nonvolatile Content of Cellulosics,
1
Emulsions, Resin Solutions, Shellac, and Varnishes
This standard is issued under the fixed designation D4209; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* D871 Test Methods of Testing Cellulose Acetate
D914 Test Methods for Ethylcellulose
1.1 This practice is intended to serve as a guide to the
D1259 Test Methods for Nonvolatile Content of Resin
selection of the proper ASTM test method for determining the
Solutions
volatile and nonvolatile content of cellulosics, emulsions, resin
D1347 Test Methods for Methylcellulose (Withdrawn
solutions, shellac, and varnishes.
3
2003)
NOTE 1—Standards for determining the composition of the volatile
D1490 Test Method for Nonvolatile Content of Urea-
fraction are not covered by this practice.
Formaldehyde Resin Solutions
1.2 The standards referenced in the practice are as follows:
D1644 Test Methods for Nonvolatile Content of Varnishes
Classification Section ASTM Standard
D1650 Test Methods for Sampling and Testing Shellac
Cellulosics 5.1 D871
3
Varnish (Withdrawn 1997)
D914
D2369 Test Method for Volatile Content of Coatings
D1347
Emulsions 5.2 D2369
D4758 Test Method for Nonvolatile Content of Latexes
Resin Solutions 5.3 D1259
3
(Withdrawn 2007)
D1490
Shellac 5.4 D29
D1650
3. Terminology
Varnishes 5.5 D115
D1644
3.1 Definitions:
1.3 The values stated in SI units are to be regarded as the
3.1.1 The definitions contained in Terminology D16 are
standard. The values given in parentheses are for information
applicable to this practice.
only.
3.1.2 cellulose ester, n—derivatives of cellulose in which
one or more of the hydroxyl hydrogens have been replaced by
2. Referenced Documents
acyl groups.
2
2.1 ASTM Standards:
3.1.3 cellulose ether, n—derivatives of cellulose in which
D16 TerminologyforPaint,RelatedCoatings,Materials,and
one or more of the hydroxyl hydrogens have been replaced by
Applications
alkyl groups.
D29 Test Methods for Sampling and Testing Lac Resins
3
(Withdrawn 2005)
3.1.4 cellulose nitrate (nitrocellulose), n—derivatives of
D115 Test Methods for Testing Solvent Containing Var-
cellulose in which one or more of the hydroxyl hydrogens have
nishes Used for Electrical Insulation
been replaced by nitrate groups.
D360 Specification for Shellac Varnishes (Withdrawn
3
3.1.5 emulsion vehicle, n—an emulsion of binder in water.
2010)
The binder may be oil, oleoresinous varnish, resin, or other
emulsifiable liquid.
1
This practice is under the jurisdiction of ASTM Committee D01 on Paint and
3.1.6 latex, n—a stable aqueous dispersion of synthetic
Related Coatings, Materials, and Applications and is the direct responsibility of
Subcommittee D01.21 on Chemical Analysis of Paints and Paint Materials.
resin, produced by emulsion polymerization, as the principal
Current edition approved July 1, 2007. Published August 2007. Originally
constituent of the binder.
approved in 1982. Last previous edition approved in 2002 as D4209 - 82 (2002).
DOI: 10.1520/D4209-07.
3.1.7 shellac varnish, n—a solution or “cut” of a specified
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
type and grade of dry lac resin in a suitable alcohol.
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
3.1.8 varnish, n—a liquid composition that is converted by
the ASTM website.
3
oxidation or thermal cross-linking to a transparent or translu-
The last approved version of this historical standard is referenced on
www.astm.org. cent solid film after application as a thin layer.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D4209 − 07
4. Significance and Use of resin solution is spread under pressure between two weighed
sheets of aluminum foil, which are then separated and dried at
4.1 The nonvolatile content of raw materials may be used to
105°C. The method is unique in that it provides for drying of
determine the total nonvolatile content (solids) of paint and
very thin films of resin, minimizing chances for volatiles to be
related coatings. Such information may be useful to coatings
trapped.
producers and users for the determination of the total solids
available for film formation and for the estimation of the 5.4 Shellac:
volatile organic content. 5.4.1 Sections 14 and 15
...

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