ASTM D5011-17
(Practice)Standard Practices for Calibration of Ozone Monitors Using Transfer Standards
Standard Practices for Calibration of Ozone Monitors Using Transfer Standards
SIGNIFICANCE AND USE
5.1 The reactivity and instability of O3 precludes the storage of O3 concentration standards for any practical length of time, and precludes direct certification of O3 concentrations as SRM's. Moreover, there is no available SRM that can be readily and directly adapted to the generation of O3 standards analogous to permeation devices and standard gas cylinders for sulfur dioxide and nitrogen oxides. Dynamic generation of O3 concentrations is relatively easy with a source of ultraviolet (UV) radiation. However, accurately certifying an O3 concentration as a primary standard requires assay of the concentration by a comprehensively specified analytical procedure, which must be performed every time a standard is needed.
5.2 The primary UV standard photometers, which are usually used at a fixed location under controlled conditions, are used to certify transfer standards that are then transported to the field sites where the ambient ozone monitors are being used. See Practice D5110.
5.3 The advantages of this procedure are:
5.3.1 All O3 monitors in a given network or region may be traced to a single primary standard.
5.3.2 The primary standard is used at only one location, under controlled conditions.
5.3.3 Transfer standards are more rugged and more easily portable than primary standards.
5.3.4 Transfer standards may be used to intercompare various primary standards.
SCOPE
1.1 These practices describe means for calibrating ambient, workplace or indoor ozone monitors, using transfer standards.
1.2 These practices describe five types of transfer standards:
Practice A—Analytical instruments,
Practice B—Boric acid potassium iodide (BAKI) manual analytical procedure,
Practice C—Gas phase titration with excess nitric oxide,
Practice D—Gas phase titration with excess ozone, and
Practice E—Ozone generator device.
1.3 These practices describe procedures to establish the authority of transfer standards: qualification, certification, and periodic recertification.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See Section 8 for specific precautionary statements.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
Relations
Buy Standard
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D5011 − 17
Standard Practices for
1
Calibration of Ozone Monitors Using Transfer Standards
This standard is issued under the fixed designation D5011; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D1193Specification for Reagent Water
D1356Terminology Relating to Sampling and Analysis of
1.1 These practices describe means for calibrating ambient,
Atmospheres
workplace or indoor ozone monitors, using transfer standards.
D3195Practice for Rotameter Calibration
1.2 Thesepracticesdescribefivetypesoftransferstandards:
D3249Practice for General Ambient Air Analyzer Proce-
Practice A—Analytical instruments,
dures
Practice B—Boric acid potassium iodide (BAKI) manual
D3631Test Methods for Measuring Surface Atmospheric
analytical procedure,
Pressure
Practice C—Gas phase titration with excess nitric oxide,
D3824Test Methods for Continuous Measurement of Ox-
Practice D—Gas phase titration with excess ozone, and
idesofNitrogenintheAmbientorWorkplaceAtmosphere
Practice E—Ozone generator device.
by the Chemiluminescent Method
D4230Test Method of Measuring Humidity with Cooled-
1.3 These practices describe procedures to establish the
authority of transfer standards: qualification, certification, and Surface Condensation (Dew-Point) Hygrometer
D5110Practice for Calibration of Ozone Monitors and
periodic recertification.
CertificationofOzoneTransferStandardsUsingUltravio-
1.4 The values stated in SI units are to be regarded as
let Photometry
standard. No other units of measurement are included in this
E591Practice for Safety and Health Requirements Relating
standard.
3
to Occupational Exposure to Ozone (Withdrawn 1990)
1.5 This standard does not purport to address all of the
2.2 Other Documents:
safety concerns, if any, associated with its use. It is the
40 CFR Part 50Environmental Protection Agency Regula-
4
responsibility of the user of this standard to establish appro-
tions on Ambient Air Monitoring Reference Methods
priate safety, health, and environmental practices and deter-
3. Terminology
mine the applicability of regulatory limitations prior to use.
See Section 8 for specific precautionary statements.
3.1 Definitions—For definitions of terms used in this
1.6 This international standard was developed in accor-
standard, see Terminology D1356.
dance with internationally recognized principles on standard-
3.2 Definitions of Terms Specific to This Standard:
ization established in the Decision on Principles for the
3.2.1 primary standard, n—a standard directly defined and
Development of International Standards, Guides and Recom-
established by some authority, against which all secondary
mendations issued by the World Trade Organization Technical
standards are compared.
Barriers to Trade (TBT) Committee.
3.2.2 secondary standard, n—a standard used as a means of
2. Referenced Documents
comparison, but checked against a primary standard.
2
2.1 ASTM Standards:
3.2.3 standard, n—an accepted reference sample or device
D1071Test Methods for Volumetric Measurement of Gas-
used for establishing measurement of a physical quantity.
eous Fuel Samples
3.2.4 transfer standard, n—a type of secondary standard. It
is a transportable device or apparatus, which, together with
1 operational procedures, is capable of reproducing pollutant
These practices are under the jurisdiction of ASTM Committee D22 on Air
Quality and are the direct responsibility of Subcommittee D22.03 on Ambient concentration or producing acceptable assays of pollutant
Atmospheres and Source Emissions.
concentrations.
Current edition approved Oct. 1, 2017. Published October 2017. Originally
approved in 1989. Last previous edition approved in 2009 as D5011–92 (2009).
3
DOI: 10.1520/D5011-17. The last approved version of this historical standard is referenced on
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or www.astm.org.
4
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Available from U.S. Government Printing Office, Superintendent of
Standards volume information, refer to the standard’s Document Summary page on Documents, 732 N. Capitol St., NW, Washington, DC 20401-0001, http://
the ASTM website. www.access.gpo.gov.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
---------------------- Page: 1 ----------------------
D5011 − 17
3.2.5 zero air, n—purified air that does not con
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D5011 − 92 (Reapproved 2009) D5011 − 17
Standard Practices for
1
Calibration of Ozone Monitors Using Transfer Standards
This standard is issued under the fixed designation D5011; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 These practices describe means for calibrating ambient, workplace or indoor ozone monitors, using transfer standards.
1.2 These practices describe five types of transfer standards:
(A) Analytical instruments
Practice A—Analytical instruments,
Practice B—Boric acid potassium iodide (BAKI) manual analytical procedure,
Practice C—Gas phase titration with excess nitric oxide,
Practice D—Gas phase titration with excess ozone, and
Practice E—Ozone generator device.
(B) Boric acid potassium iodide (BAKI) manual analytical procedure
(C) Gas phase titration with excess nitric oxide
(D) Gas phase titration with excess ozone
(E) Ozone generator device.
1.3 These practices describe procedures to establish the authority of transfer standards: qualification, certification, and periodic
recertification.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use. See Section 8 for specific precautionary statements.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D1071 Test Methods for Volumetric Measurement of Gaseous Fuel Samples
D1193 Specification for Reagent Water
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
D3195 Practice for Rotameter Calibration
D3249 Practice for General Ambient Air Analyzer Procedures
D3631 Test Methods for Measuring Surface Atmospheric Pressure
D3824 Test Methods for Continuous Measurement of Oxides of Nitrogen in the Ambient or Workplace Atmosphere by the
Chemiluminescent Method
D4230 Test Method of Measuring Humidity with Cooled-Surface Condensation (Dew-Point) Hygrometer
D5110 Practice for Calibration of Ozone Monitors and Certification of Ozone Transfer Standards Using Ultraviolet Photometry
3
E591 Practice for Safety and Health Requirements Relating to Occupational Exposure to Ozone (Withdrawn 1990)
1
These practices are under the jurisdiction of ASTM Committee D22 on Air Quality and are the direct responsibility of Subcommittee D22.03 on Ambient Atmospheres
and Source Emissions.
Current edition approved March 1, 2009Oct. 1, 2017. Published March 2009October 2017. Originally approved in 1989. Last previous edition approved in 20032009 as
D5011 – 92 (2003).(2009). DOI: 10.1520/D5011-92R09.10.1520/D5011-17.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
The last approved version of this historical standard is referenced on www.astm.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
---------------------- Page: 1 ----------------------
D5011 − 17
2.2 Other Documents:
4
40 CFR Part 50 CFR Part 50, Environmental Protection Agency Regulations on Ambient Air Monitoring Reference Methods
3. Terminology
3.1 Definitions—For definitions of terms used in this standard, see Terminology D1356.
3.2 Definitions of Terms Specific to This Standard:
3.2.1 primary standard—standard, n—a standard directly defined and established by some authority, against which all
secondary standards are compared.
3.2.2 secondary standard—standard, n—a standard used as a means of comparison, but checked against a primary standard.
3.2.3 standard—standard, n—an accepted reference sample or device used for establishing measureme
...
Questions, Comments and Discussion
Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.