EN ISO 11890-2:2006
(Main)Paints and varnishes - Determination of volatile organic compound (VOC) content - Part 2: Gas-chromatographic method (ISO 11890-2:2006)
Paints and varnishes - Determination of volatile organic compound (VOC) content - Part 2: Gas-chromatographic method (ISO 11890-2:2006)
ISO 11890-2:2006 is one of a series of standards dealing with the sampling and testing of paints, varnishes and related products.
It specifies a method for the determination of the volatile organic compound (VOC) content of paints, varnishes and their raw materials. ISO 11890-2 is preferred if the expected VOC content is greater than 0,1 % by mass and less than about 15 % by mass. When the VOC content is greater than about 15 % by mass, the less complicated method given in ISO 11890-1 may be used.
This method assumes that the volatile matter is either water or organic. However, other volatile inorganic compounds can be present and might need to be quantified by another suitable method and allowed for in the calculations.
Beschichtungsstoffe - Bestimmung des Gehaltes an flüchtigen organischen Verbindungen (VOC-Gehalt) - Teil 2: Gaschromatographisches Verfahren (ISO 11890-2:2006)
Dieser Teil von ISO 11890 gehört zu einer Reihe von Normen, welche die Probenahme und Prüfung von Beschichtungsstoffen und ähnlichen Produkten behandelt.
Er legt ein Verfahren zum Bestimmen des Gehaltes an flüchtigen organischen Verbindungen (VOC Gehalt) in Beschichtungsstoffen und deren Rohstoffen fest. Dieser Teil darf angewendet werden, wenn der erwartete VOC-Gehalt über 0,1 % (Massenanteil) und unter 15 % (Massenanteil) liegt. Wenn der VOC-Gehalt über 15 % (Massenanteil) liegt, sollte das weniger komplizierte Verfahren nach ISO 11890-1 angewendet werden.
Dieses Verfahren geht davon aus, dass es sich bei den flüchtigen Anteilen entweder um Wasser oder um organische Verbindungen handelt. Es können jedoch andere flüchtige anorganische Verbindungen anwesend sein, die durch ein anderes geeignetes Verfahren bestimmt und in den Berechnungen berücksichtigt werden dürfen.
Peintures et vernis - Détermination de la teneur en composés organiques volatils (COV) - Partie 2: Méthode par chromatographie en phase gazeuse (ISO 11890-2:2006)
L'ISO 11890-2:2006 fait partie d'une série de normes qui traitent de l'échantillonnage et des essais relatifs aux peintures, vernis et produits assimilés.
Elle spécifie une méthode de détermination de la teneur en composés organiques volatils (COV) des peintures, vernis et de leurs matières premières. Cette méthode est à utiliser de préférence si la teneur escomptée en COV est comprise entre 0,1 % en masse et environ 15 % en masse. Si la teneur en COV est supérieure à environ 15 % en masse, la méthode plus simple préconisée dans l'ISO 11890-1 peut être utilisée.
Cette méthode suppose que la matière volatile est de l'eau ou une matière organique. Toutefois, d'autres composés inorganiques volatils peuvent être présents; il pourrait être nécessaire de les quantifier selon une autre méthode et d'en tenir compte dans les calculs.
Barve in laki - Določevanje hlapnih organskih spojin (VOC) – 2. del: Metoda plinske kromatografije (ISO 11890-2:2006)
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-marec-2007
%DUYHLQODNL'RORþHYDQMHKODSQLKRUJDQVNLKVSRMLQ 92& ±GHO 0HWRGDSOLQVNH
NURPDWRJUDILMH ,62
Paints and varnishes - Determination of volatile organic compound (VOC) content - Part
2: Gas-chromatographic method (ISO 11890-2:2006)
Beschichtungsstoffe - Bestimmung des Gehaltes an flüchtigen organischen
Verbindungen (VOC-Gehalt) - Teil 2: Gaschromatographisches Verfahren (ISO 11890-
2:2006)
Peintures et vernis - Détermination de la teneur en composés organiques volatils (COV)
- Partie 2: Méthode par chromatographie en phase gazeuse (ISO 11890-2:2006)
Ta slovenski standard je istoveten z: EN ISO 11890-2:2006
ICS:
87.040 Barve in laki Paints and varnishes
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EUROPEAN STANDARD
EN ISO 11890-2
NORME EUROPÉENNE
EUROPÄISCHE NORM
November 2006
ICS 87.040 Supersedes EN ISO 11890-2:2001
English Version
Paints and varnishes - Determination of volatile organic
compound (VOC) content - Part 2: Gas-chromatographic
method (ISO 11890-2:2006)
Peintures et vernis - Détermination de la teneur en Beschichtungsstoffe - Bestimmung des Gehaltes an
composés organiques volatils (COV) - Partie 2: Méthode flüchtigen organischen Verbindungen (VOC-Gehalt) - Teil
par chromatographie en phase gazeuse (ISO 11890- 2: Gaschromatographisches Verfahren (ISO 11890-2:2006)
2:2006)
This European Standard was approved by CEN on 11 November 2006.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,
Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
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COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36 B-1050 Brussels
© 2006 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 11890-2:2006: E
worldwide for CEN national Members.
Foreword
This document (EN ISO 11890-2:2006) has been prepared by Technical Committee ISO/TC 35
"Paints and varnishes" in collaboration with Technical Committee CEN/TC 139 "Paints and
varnishes", the secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of
an identical text or by endorsement, at the latest by May 2007, and conflicting national standards
shall be withdrawn at the latest by May 2007.
This document supersedes EN ISO 11890-2:2001.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of
the following countries are bound to implement this European Standard: Austria, Belgium,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary,
Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
Endorsement notice
The text of ISO 11890-2:2006 has been approved by CEN as EN ISO 11890-2:2006 without any
modifications.
INTERNATIONAL ISO
STANDARD 11890-2
Second edition
2006-11-15
Paints and varnishes — Determination of
volatile organic compound (VOC)
content —
Part 2:
Gas-chromatographic method
Peintures et vernis — Détermination de la teneur en composés
organiques volatils (COV) —
Partie 2: Méthode par chromatographie en phase gazeuse
Reference number
ISO 11890-2:2006(E)
©
ISO 2006
ISO 11890-2:2006(E)
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ii © ISO 2006 – All rights reserved
ISO 11890-2:2006(E)
Contents Page
Foreword. iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions. 2
4 Principle. 2
5 Required supplementary information. 3
6 Apparatus . 3
7 Reagents. 5
8 Sampling. 6
9 Procedure . 6
10 Calculation. 8
11 Expression of results . 9
12 Precision. 10
13 Test report . 10
Annex A (normative) Required supplementary information. 12
Annex B (informative) Examples of gas-chromatographic conditions. 13
ISO 11890-2:2006(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 11890-2 was prepared by Technical Committee ISO/TC 35, Paints and varnishes.
This second edition cancels and replaces the first edition (ISO 11890-2:2000), which has been technically
revised. The main changes are:
⎯ the method has been modified to allow the determination of the VOC content when the term refers to
compounds with a well-defined boiling point;
⎯ the calculation of the VOC content of a product “ready for use” less water and less exempt compounds
(see 10.5) has been modified to make it clear that only those components that are not exempt
compounds are considered.
ISO 11890 consists of the following parts, under the general title Paints and varnishes — Determination of
volatile organic compound (VOC) content:
⎯ Part 1: Difference method
⎯ Part 2: Gas-chromatographic method
iv © ISO 2006 – All rights reserved
INTERNATIONAL STANDARD ISO 11890-2:2006(E)
Paints and varnishes — Determination of volatile organic
compound (VOC) content —
Part 2:
Gas-chromatographic method
1 Scope
This part of ISO 11890 is one of a series of standards dealing with the sampling and testing of paints,
varnishes and related products.
It specifies a method for the determination of the volatile organic compound (VOC) content of paints,
varnishes and their raw materials. This part is preferred if the expected VOC content is greater than 0,1 % by
mass and less than about 15 % by mass. When the VOC content is greater than about 15 % by mass, the
less complicated method given in ISO 11890-1 may be used.
This method assumes that the volatile matter is either water or organic. However, other volatile inorganic
compounds can be present and might need to be quantified by another suitable method and allowed for in the
calculations.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.
ISO 760, Determination of water — Karl Fischer method (General method)
ISO 1513, Paints and varnishes — Examination and preparation of samples for testing
ISO 2811-1, Paints and varnishes — Determination of density — Part 1: Pyknometer method
ISO 2811-2, Paints and varnishes — Determination of density — Part 2: Immersed body (plummet) method
ISO 2811-3, Paints and varnishes — Determination of density — Part 3: Oscillation method
ISO 2811-4, Paints and varnishes — Determination of density — Part 4: Pressure cup method
ISO 15528, Paints, varnishes and raw materials for paints and varnishes — Sampling
ISO 11890-2:2006(E)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
3.1
volatile organic compound
VOC
any organic liquid and/or solid that evaporates spontaneously at the prevailing temperature and pressure of
the atmosphere with which it is in contact
NOTE 1 As to current usage of the term VOC in the field of coating materials, see volatile organic compound content
(VOC content).
NOTE 2 Under U.S. government legislation, the term VOC is restricted solely to those compounds that are
photochemically active in the atmosphere (see ASTM D 3960). Any other compound is then defined as being an exempt
compound.
[ISO 4618:2006]
NOTE 3 Under European legislation, EU Directive 2004/42/EC, the term VOC refers to volatile organic compounds with
boiling points up to 250 °C, measured at a standard pressure of 101,3 kPa.
3.2
volatile organic compound content
VOC content
mass of the volatile organic compounds present in a coating material, as determined under specified
conditions
NOTE 1 The properties and the amounts of the compounds to be taken into account will depend on the field of
application of the coating material. For each field of application, the limiting values and the methods of determination or
calculation are stipulated by regulations or by agreement.
[ISO 4618:2006]
NOTE 2 If the term VOC refers to compounds with a defined maximum boiling point (see Note 3 to 3.1), the
compounds considered to be part of the VOC content are those with boiling points below that limit and compounds with
higher boiling points are considered to be non-volatile organic compounds.
3.3
exempt compound
organic compound that does not participate in atmospheric photochemical reactions
NOTE See Notes 2 and 3 to 3.1.
3.4
ready for use
state of a product when it is mixed in accordance with the manufacturer's instructions in the correct
proportions and thinned if required using the correct thinners so that it is ready for application by the approved
method
4 Principle
After preparation of the sample, the VOCs are separated by a gas-chromatographic technique. E
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