prEN 18322

Inorganic fertilizers - Determination of the organic carbon content by dry combustion

This document specifies a method for the determination of total organic carbon content by elemental analysis using dry combustion. The method is applicable to inorganic fertilizers containing more than 0,1 % carbon expressed on dry mass.
NOTE   This method can also be applied to other types of fertilizers, provided the user has verified the applicability.
This document is applicable to the fertilizing products blends where a blend is a mix of at least two of the following components: inorganic fertilizers, organic fertilizers, organo-mineral fertilizers, liming materials, soil improvers, growing media, inhibitors, plant biostimulants and where the following category: inorganic fertilizer is the highest % in the blend by mass or volume, or in the case of liquid form by dry mass. If inorganic fertilizer is not the highest % in the blend, the European Standard for the highest % of the blend applies. In case a fertilizing product blend is composed of components in equal quantity, the user decides which standard to apply. Variations in analytical methods for fertilizing product blends can lead to differing results as some components or matrix interactions can affect the outcome. Validation procedures have shown that developed standard methods are robust and reliable across diverse product compositions, but possible interferences and unexpected results when analysing fertilizing product blends are possible.

Anorganische Düngemittel - Bestimmung des Gehalts an organischem Kohlenstoff durch trockene Verbrennung

In diesem Dokument wird ein Verfahren zur Bestimmung des gesamten organischen Kohlenstoffgehaltes durch Elementaranalyse mit Trockenverbrennung angegeben. Das Verfahren ist anwendbar auf anorganische Düngemittel, die mehr als 0,1 % Kohlenstoff enthalten, ausgedrückt in der Trockenmasse.
ANMERKUNG   Dieses Verfahren kann auch auf andere Arten von Düngemitteln angewendet werden, vorausgesetzt, der Anwender hat die Anwendbarkeit verifiziert.
Dieses Dokument ist anwendbar auf Düngeproduktmischungen, bei denen eine Mischung aus mindestens zwei der folgenden Komponenten besteht: Düngemittel, Kalkdünger, Bodenverbesserungsmittel, Kultursubstrate, Hemmstoffe, Biostimulanzien und wenn die Kategorie „anorganische Düngemittel“ den höchsten Prozentsatz in der Mischung bezüglich Masse oder Volumen, oder im Falle von flüssigen Formen bezüglich Trockenmasse ausmacht. Wenn das anorganische Düngemittel nicht den höchsten Prozentsatz in der Mischung ausmacht, gilt die Europäische Norm für den höchsten Prozentsatz der Mischung. Im Falle, dass die Düngeproduktmischung aus Komponenten gleicher Menge besteht, entscheidet der Anwender, welche Norm angewendet wird. Variationen in analytischen Verfahren für Düngeproduktmischungen können zu unterschiedlichen Ergebnissen führen, da einige Komponenten oder Matrixwechselwirkungen das Ergebnis beeinflussen können. Validierungen haben gezeigt, dass die entwickelten Standardverfahren robust und zuverlässig über unterschiedliche Produktzusammensetzungen hinweg sind. Jedoch sind mögliche Interferenzen und unerwartete Ergebnisse bei der Analyse von Düngeproduktmischungen möglich.

Engrais inorganiques - Détermination de la teneur en carbone organique par combustion sèche

Le présent document spécifie une méthode pour la détermination de la teneur en carbone organique total par une analyse élémentaire ayant recours à une combustion sèche. La méthode est applicable aux engrais inorganiques contenant plus de 0,1 % de carbone, exprimé en masse sèche.
NOTE   Cette méthode peut également être appliquée à d'autres types d'engrais, à condition que l'utilisateur ait vérifié son applicabilité.
Le présent document est applicable aux mélanges de fertilisants constitués d'au moins deux des composants suivants: engrais inorganiques, engrais organiques, engrais organo-minéraux, amendements minéraux basiques, amendements du sol, supports de culture, inhibiteurs, biostimulants des végétaux et dans lesquels la catégorie « engrais inorganiques » représente le pourcentage le plus élevé du mélange en masse ou en volume, ou dans le cas d'un liquide, en masse sèche. Si l'engrais inorganique ne représente pas le pourcentage le plus élevé du mélange, la Norme européenne relative au pourcentage le plus élevé du mélange s'applique. Dans le cas où le mélange de fertilisants est constitué de composants en quantités égales, l'utilisateur décide quelle norme appliquer. Les variations dans les méthodes d'analyse des mélanges de fertilisants peuvent conduire à des résultats différents, car certaines interactions de composants ou de la matrice peuvent affecter le résultat. Les procédures de validation ont montré que les méthodes normalisées développées sont robustes et fiables pour diverses compositions de produits, mais des interférences éventuelles et des résultats inattendus lors de l'analyse des mélanges de fertilisants sont possibles.

Anorganska gnojila - Določanje organskega ogljika s suhim sežigom

General Information

• Status: Not Published
• Publication Date: 28-Feb-2028
• ICS: 65.080 - Fertilizers
• Technical Committee: CEN/TC 260 - Fertilizers and liming materials
• Drafting Committee: CEN/TC 260/WG 7 - Chemical analysis
• Current Stage: 4020 - Submission to enquiry - Enquiry
• Start Date: 19-Mar-2026
• Due Date: 13-Oct-2026
• Completion Date: 19-Mar-2026
• Directive: Not Harmonized2019/1009 - Regulation (EU) 2019/1009 of the European Parliament and of the Council of 5 June 2019 laying down rules on the making available on the market of EU fertilising products and amending Regulations (EC) No 1069/2009 and (EC) No 1107/2009 and repealing Regulation (EC) No 2003/2003 (Text with EEA relevance)
• Mandate: M/564 - Fertilising products in support of Regulation (EU) 2019/1009
• Mandate: M/564 AMD 1 - amending Implementing Decision C(2020) 612 as regards certain harmonised standards and standardisation deliverables, deadlines for their adoption and the duration of the validity of the standardisation request
• Mandate: M/564 AMD 2 - Commission Implementing decision amending Implementing Decision C(2020)612 as regards harmonised standards, the deadlines for the adoption of those standards and the duration of the validity of the standardisation request to the European Committee for Standardisation as regards the EU fertilising products in support of Regulation (EU) 2019/1009 of the European Parliament and of the Council
• Ref Project: oSIST prEN 18322:2026 - Inorganic fertilizers - Determination of the organic carbon content by dry combustion

Overview

prEN 18322 is a draft European Standard published by CEN that specifies a reliable, standardized method for the determination of total organic carbon (TOC) content in inorganic fertilizers using dry combustion and elemental analysis. The method is specifically applicable to inorganic fertilizers containing more than 0.1% carbon (on dry mass basis) and can also be applied to a wide range of fertilizing product blends, including those containing organic or organo-mineral fertilizers, provided that inorganic fertilizer is the dominant component by mass or volume. The standard addresses the need for precise and consistent measurement of organic carbon to support regulatory compliance and quality assurance within the fertilizer industry.

Key Topics

• Scope and Applicability:

  • Applies to inorganic fertilizers and blends where inorganic fertilizer is the predominant component.
  • Suitable for both solid and liquid fertilizers with a carbon content above 0.1% (dry mass).
  • Can be extended to other fertilizer types if suitability is verified by the user.

• Analytical Methods:

  • Method A (Indirect): Calculates TOC by subtracting total inorganic carbon (TIC) from total carbon (TC). Each component is measured separately using dry combustion and acid digestion techniques.
  • Method B (Direct): Inorganic carbon is first removed by acid treatment, and remaining organic carbon is measured directly through combustion.
  • Detection: Common measurement methods include infrared spectrometry and thermal conductivity detection.

• Sample Handling:

  • Emphasizes the importance of representative sampling and appropriate sample preparation based on referenced EN standards.
  • Includes guidelines for procedure selection where fertilizing product blends contain equal proportions of components.

• Validation and Quality Control:

  • Encourages control measurements, calibration, and reporting of repeatability and reproducibility.
  • Notes that method performance may vary for blends due to component interactions and potential interferences.

Applications

The standardized determination of organic carbon content by dry combustion is critical for:

• Quality Assurance: Ensuring product consistency and compliance with national and EU regulations (such as Regulation (EU) 2019/1009).
• Regulatory Reporting: Accurate measurement of organic carbon is a requirement for labeling and safety documentation for fertilizer products.
• Product Development and Blending: Supports manufacturers in evaluating the composition and suitability of new fertilizer blends, including organo-mineral mixes, soil improvers, or biostimulants.
• Market Access: Harmonization of testing methods facilitates trade and regulatory acceptance of fertilizers across European countries.
• Environmental Impact Assessment: Provides data for monitoring carbon inputs to soil and supporting sustainable agricultural practices.

Related Standards

For robust analysis and compliance, the following standards and normative references are closely associated with prEN 18322:

• EN 1482-1 and EN 1482-2: Sampling and general sample preparation for fertilizers.
• EN 12944-1, EN 12944-2: Fertilizers vocabulary - general terms and specific terms.
• EN 15705: Determination of methylen-urea oligomers in inorganic fertilizers.
• ISO 8466-1: Calibration and evaluation of analytical methods (linear calibration).
• ISO 5725-2 & ISO 5725-3: Guidance on measurement accuracy, repeatability, and reproducibility.
• Regulation (EU) 2019/1009: EU rules on the marketing of fertilizing products.

By adhering to prEN 18322, laboratories and fertilizer producers can ensure their measurements of organic carbon are consistent, precise, and accepted across the European market, supporting both product quality and regulatory compliance in the fertilizer industry.

Standards Content (Sample)

SLOVENSKI STANDARD
01-april-2026
Anorganska gnojila - Določanje organskega ogljika s suhim sežigom
Inorganic fertilizers - Determination of the organic carbon content by dry combustion
Anorganische Düngemittel - Bestimmung des Gehalts an organischem Kohlenstoff durch
trockene Verbrennung
Ta slovenski standard je istoveten z: prEN 18322
ICS:
65.080 Gnojila Fertilizers
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

DRAFT
EUROPEAN STANDARD
NORME EUROPÉENNE
EUROPÄISCHE NORM
March 2026
ICS 65.080
English Version
Inorganic fertilizers - Determination of the organic carbon
content by dry combustion
Anorganische Düngemittel - Bestimmung des Gehalts
an organischem Kohlenstoff durch trockene
Verbrennung
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 260.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2026 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 18322:2026 E
worldwide for CEN national Members.

Contents Page
European foreword . 3
1 Scope . 4
2 Normative references . 4
3 Terms and definitions . 4
4 Principle . 5
4.1 Method A (indirect procedure) . 5
4.2 Method B (direct procedure) . 5
5 Interferences . 5
6 Reagents . 6
7 Equipment and consumables . 7
8 Sampling and sample preparation . 7
8.1 Sampling . 7
8.2 Sample preparation . 7
9 Procedure – Method A (indirect method) . 8
9.1 Determination . 8
9.2 Calibration . 8
9.3 Control measurements . 9
9.4 Calculation and expression of results . 9
10 Procedure – Method B (direct method) . 10
10.1 Determination . 10
10.2 Calibration . 11
10.3 Control measurements . 11
10.4 Calculation and expression of results . 12
11 Expression of results . 12
12 Precision . 12
12.1 Inter-laboratory study . 12
12.2 Repeatability . 13
12.3 Reproducibility . 13
13 Test report . 13
Annex A (informative) Results of the inter-laboratory study . 14
Bibliography . 16

European foreword
This document (prEN 18322:2026) has been prepared by Technical Committee CEN/TC 260 “Fertilizers
and liming materials”, the secretariat of which is held by DIN.
This document is currently submitted to CEN Enquiry.
This document has been prepared under a standardization request addressed to CEN by the European
Commission. The Standing Committee of the EFTA States subsequently approves these requests for its
Member States.
1 Scope
This document specifies a method for the determination of total organic carbon content by elemental
analysis using dry combustion. The method is applicable to inorganic fertilizers containing more than
0,1 % carbon expressed on dry mass.
NOTE This method can also be applied to other types of fertilizers, provided the user has verified the
applicability.
This document is applicable to the fertilizing products blends where a blend is a mix of at least two of the
following components: inorganic fertilizers, organic fertilizers, organo-mineral fertilizers, liming
materials, soil improvers, growing media, inhibitors, plant biostimulants and where the following
category: inorganic fertilizer is the highest % in the blend by mass or volume, or in the case of liquid form
by dry mass. If inorganic fertilizer is not the highest % in the blend, the European Standard for the highest
% of the blend applies. In case a fertilizing product blend is composed of components in equal quantity,
the user decides which standard to apply. Variations in analytical methods for fertilizing product blends
can lead to differing results as some components or matrix interactions can affect the outcome. Validation
procedures have shown that developed standard methods are robust and reliable across diverse product
compositions, but possible interferences and unexpected results when analysing fertilizing product
blends are possible.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 1482-2, Fertilizers, liming materials and inhibitors — Sampling and sample preparation — Part 2:
General sample preparation provisions
EN 12944-1, Fertilizers, liming materials and inhibitors — Vocabulary — Part 1: General terms
EN 12944-2, Fertilizers, liming materials and inhibitors — Vocabulary — Part 2: Terms relating to
fertilizers
3 Terms and definitions
For the purposes of this document, the terms and definitions given in EN 12944-1 and EN 12944-2 and
the following shall be applied.
ISO and IEC maintain terminology databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https://www.iso.org/obp
— IEC Electropedia: available at https://www.electropedia.org/
3.1
total organic carbon
TOC
quantity of carbon that is converted into carbon dioxide by combustion and not released as carbon
dioxide by treatment with acid
Note 1 to entry: In agreement with Regulation (EU) 2019/1009 [1], carbon derived from urea and polymers
containing urea are not considered as organic in this document.
3.2
total inorganic carbon
TIC
quantity of carbon that is released as carbon dioxide by acid treatment
Note 1 to entry: Typically, the TIC represents the carbonates present in a sample.
3.3
total carbon
TC
quantity of carbon present in the sample in the form of organic, inorganic and elemental carbon
4 Principle
4.1 Method A (indirect procedure)
In this procedure, the total organic carbon (TOC) content is obtained by the difference between the
results of the measurements of TC and TIC.
The total carbon (TC) present in the sample is converted into carbon dioxide by combustion in an oxygen-
containing gas flow free of carbon dioxide. To ensure complete combustion, catalysts and/or modifiers
can be used.
The total inorganic carbon (TIC) is determined separately from another sub-sample by means of
acidification and purging of the released carbon dioxide.
The released amount of carbon dioxide is measured e.g. by infrared spectrometry, thermal conductivity
detection, or other suitable techniques.
4.2 Method B (direct procedure)
In this procedure, the TIC present in the sample is previously removed by treating the sample with acid.
The carbon dioxide released by the following combustion step is measured by one of the techniques
mentioned in 4.1 and indicates the TOC directly.
NOTE The quality of results of Method B is dependent on experience and practice, especially regarding the
steps before the determination of TOC. Using automatic dispensing units regarding removal of TIC prior to
determination of TOC improve the performance of Method B.
5 Interferences
In the case of experience with samples containing high amounts of carbonates, the operator shall take
care to correctly eliminate all the carbonates to make sure to produce reliable TOC results.
When present, carbon from urea is determined as organic carbon using the method described in this
document. An interpretation of the measured value can therefore be problematic in cases where the
sample contains relevant levels of urea. If needed, carbon from urea shall be determined separately by
means of a suitable validated method (see EN 15705 [2]) and shall be subtracted and reported by the
laboratory.
Depending on the detection method used, different interferences occur, for instance:
— the presence of cyanide interferes with the coulometric detection of TIC by modifying the pH value
(dissolution of hydrogen cyanide (HCN));
— high content of halogenated compounds leads to an overestimation of TOC when coulometric
detection is used; in some cases, the classical silver or copper trap is insufficient to absorb all halides.
Method B leads to incorrect results in the following cases:
— volatile organic substances are lost during sample preparation, especially during the acidification. If
necessary, the carbon content resulting from volatile organic substances shall be determined
separately;
— side reactions between the sample and the acid take place (e.g. decarboxylation, volatile reaction
products).
When present, elemental carbon, carbides, cyanides, cyanates, isocyanates, isothiocyanates and
thiocyanates are determined as organic carbon using the methods described in this document. An
interpretation of the measured value is therefore problematic in cases where the sample contains
relevant levels of the above-mentioned components. If needed, these components shall be determined
separately by means of a suitable validated method and shall be subtracted and reported by the
laboratory.
6 Reagents
Use only reagents of recognized analytical grade, unless otherwise specified and distilled water or
ultrapure water, with a specific conductivity not higher than 0,2 mS/m at 25 °C, free from the elements
to be determined.
Hygroscopic substances shall be stored in a desiccator.
.
6.1 Calcium carbonate, CaCO3
6.2 Sodium carbonate, NaCO anhydrous.
6.3 Tetrasodium ethylenediamine tetraacetate-tetra-hydrate, Na EDTA⋅4H O
4 2
(C H N O Na⋅4H O), heated at 80 °C ± 1 °C for 2 h.
10 12 2 8 4 2
Other forms of Na -EDTA hydrates may be used if the water content is exactly known. In these cases, the
composition of the control mixtures shall be recalculated accordingly (see also 6.10 and 6.11).
6.4 Potassium hydrogen phthalate, C H O K.
8 5 4
6.5 Acetanilide, C H NO.
8 9
6.6 Atropine, C H NO
17 23 3.
6.7 Spectrographic graphite powder, C.
H O Na.
6.8 Sodium salicylate, C7 5 3
6.9 Aluminium oxide, Al O , neutral, granular size < 200 μm, annealed at 600 °C ± 5 °C.
2 3
6.10 Control mixture A, prepared from sodium carbonate (6.2), Na -EDTA⋅4H O (6.3) and aluminium
4 2
oxide (6.9) in a mass ratio of 2,34:1,00:7,28
The mixture shall be homogenized. It shall contain 2,5 % TIC and 2,5 % TOC (e.g. 22,06 g of sodium
carbonate; 9,41 g Na -EDTA⋅4H O; 68,53 g of aluminium oxide).
4 2
6.11 Control mixture B, prepared from sodium salicylate (6.8), calcium carbonate (6.1),
Na -EDTA·4 H O (6.3) and aluminium oxide (6.9) in a mass ratio of 1,00:4,36:1,97:8,39
4 2
The mixture shall be homogenized. It shall contain 3,3 % TIC and 6,6 % TOC (e.g. 6,36 g of sodium
salicylate; 27,78 g of calcium carbonate; 12,50 g of Na -EDTA·4H O; 53,36 g of aluminium oxide).
4 2
6.12 Inert absorbent material for determination on fluid samples.
6.13 Non-oxidizing mineral acid, used for carbon dioxide expulsion, e.g. phosphoric acid H PO
3 4
(w = 85 % [as a mass fraction]).
NOTE Due to potential corrosion by hydrochloric acid, phosphoric acid is preferred for TIC determination in
Method A (9.1.3). Due to potential formation of P4O10 during combustion, hydrochloric acid HCl (w = 37 %) is
preferred for removal of inorganic carbon in Method B (10.1.2).
6.14 Carrier gas, e.g. synthetic air, nitrogen, oxygen, helium or argon, free of carbon dioxide and organic
impurities in accordance with the manufacturer's instructions.
7 Equipment and consumables
Disposable equipment is acceptable in the same way as reusable glassware if the specifications are
similar. Ordinary laboratory equipment, and particularly the following.
7.1 Analytical scale, capable of weighing to the nearest 0,000 1 g.
7.2 Equipment for determination of carbon in solid and liquid, with relevant accessories.
7.3 Purging unit for TIC determination, for Method A only.
7.4 Vessels or crucibles, made of e.g. ceramic, silica, quartz, silver or platinum.
NOTE Tin and nickel vessels are not acid resistant. Tin vessels are suitable only for Method A.
7.5 Pasteur pipettes.
7.6 Drying system, thermostatically controlled and capable of maintaining temperature of
(105 ± 2)°C.
7.7 Desiccator, with an active drying agent such as silica gel.
7.8 Muffle furnace, thermostatically controlled.
8 Sampling and sample preparation
8.1 Sampling
Sampling is not part of the method specified in this document. Recommended sampling method are given
in EN 1482-1 [6] and EN 1482-3 [7].
It is important that the laboratory receives a sample that is representative of both the product under
consideration and the given analysis. The sample should not
...