CEN/TR 16468:2013

Food analysis - Determination of pesticide residues by GC-MS - Retention times, mass spectrometric parameters and detector response information

This Technical Report lists mass spectrometric parameters which are useful for the application of European Standards for the determination of pesticide residues in foods that use GC-MS, such as the following standards:
-   EN 1528 (all parts), Fatty food - Determination of pesticides and polychlorinated biphenyls (PCBs);
-   EN 12393 (all parts), Foods of plant origin - Multiresidue methods for the gas chromatographic determination of pesticide residues;
-   EN 15662, Foods of plant origin - Determination of pesticide residues using GC-MS and/or LC-MS/MS following acetonitrile extraction/partitioning and clean-up by dispersive SPE - QuEChERS-method.
To facilitate the determination of pesticides and/or metabolites using GC-MS, Table 1 specifies the diagnostic ions suitable for quantification, which can be used.

Lebensmitteluntersuchung - Bestimmung von Pestizidrückständen mit GC-MS - Retentionszeiten, Parameter für die Massenspektrometrie und Detektionsempfindlichkeit

Analyse des produits alimentaires - Détermination des résidus de pesticides par CG-SM - Temps de rétention, paramètres de spectrométrie de masse et information sur la réponse des détecteurs

Le présent rapport technique répertorie des paramètres de spectrométrie de masse qui sont utiles pour l'application de normes européennes relatives à la détermination de résidus de pesticides dans les produits alimentaires par CG-SM, telles que les normes suivantes :
-   EN 1528 (toutes les parties), Aliments gras — Dosage des pesticides et des polychlorobiphényles (PCB).
-   EN 12393 (toutes les parties), Aliments d'origine végétale — Méthodes multirésidus de détermination par chromatographie en phase gazeuse de résidus de pesticides.
-   EN 15662, Aliments d'origine végétale — Méthode de détermination des résidus de pesticides par CG-SM et CL-SM/SM suite à l’extraction/partition à l'acétonitrile et à la purification sur EPS dispersés — Méthode QuEChERS.
Pour faciliter la détermination des pesticides et/ou des métabolites par CG-SM, le tableau 1 spécifie les ions diagnostiques appropriés pour la quantification, qu'il est possible d'utiliser.

Analiza živil - Določevanje ostankov pesticidov z uporabo GC-MS - Retenzijski časi, parametri masne spektrometrije in informacije odziva detektorja

To tehnično poročilo navaja parametre masne spektrometrije, ki so uporabni za evropske standarde za določevanje ostankov pesticidov v živilih z uporabo GC-MS, kot so naslednji standardi: – EN 1528 (vsi deli), Živila, ki vsebujejo maščobe – Določevanje pesticidov in polikloriranih bifenilov (PCB); – EN 12393 (vsi deli), Živila brez maščob – Multirezidualne metode za določevanje ostankov pesticidov s plinsko kromatografijo; – EN 15662, Hrana rastlinskega izvora – Določanje ostankov pesticidov z uporabo GC-MS in/ali LC-MS(/MS) po delitvi in izpiranju acetonitrila z disperzivno SPE – Metoda QuEChERS. Za lažje določevanje pesticidov in/ali metabolitov z uporabo GC-MS so v preglednici 1 navedeni diagnostični ioni, primerni za kvantifikacijo, ki jih je mogoče uporabiti.

General Information

• Status: Published
• Publication Date: 12-Mar-2013
• ICS: 65.100.01 - Pesticides and other agrochemicals in general
• ICS: 67.050 - General methods of tests and analysis for food products
• Technical Committee: CEN/TC 275 - Food analysis - Horizontal methods
• Drafting Committee: CEN/TC 275/WG 3 - Pesticides and PCB's in foods of animal origin
• Current Stage: 6060 - Definitive text made available (DAV) - Publishing
• Start Date: 13-Mar-2013
• Due Date: 24-Apr-2013
• Completion Date: 13-Mar-2013
• Ref Project: SIST-TP CEN/TR 16468:2013 - Food analysis - Determination of pesticide residues by GC-MS - Retention times, mass spectrometric parameters and detector response information

Standards Content (Sample)

SLOVENSKI STANDARD
SIST-TP CEN/TR 16468:2013
01-junij-2013
$QDOL]DåLYLO'RORþHYDQMHRVWDQNRYSHVWLFLGRY]XSRUDER*&065HWHQ]LMVNL
þDVLSDUDPHWULPDVQHVSHNWURPHWULMHLQLQIRUPDFLMHRG]LYDGHWHNWRUMD
Food analysis - Determination of pesticide residues by GC-MS - Retention times, mass
spectrometric parameters and detector response information
Lebensmitteluntersuchung - Bestimmung von Pestizidrückständen mit GC-MS -
Retentionszeiten, Parameter für die Massenspektrometrie und Detektionsempfindlichkeit
Analyse des produits alimentaires - Détermination des résidus de pesticides par CG-SM
- Temps de rétention, paramètres de spectrométrie de masse et information sur la
réponse des détecteurs
Ta slovenski standard je istoveten z: CEN/TR 16468:2013
ICS:
65.100.01 Pesticidi in druge Pesticides and other
agrokemikalije na splošno agrochemicals in general
67.050 Splošne preskusne in General methods of tests and
analizne metode za živilske analysis for food products
proizvode
SIST-TP CEN/TR 16468:2013 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------

SIST-TP CEN/TR 16468:2013

---------------------- Page: 2 ----------------------

SIST-TP CEN/TR 16468:2013


TECHNICAL REPORT
CEN/TR 16468

RAPPORT TECHNIQUE

TECHNISCHER BERICHT
March 2013
ICS 65.100.01; 67.050
English Version
Food analysis - Determination of pesticide residues by GC-MS -
Retention times, mass spectrometric parameters and detector
response information
Analyse des produits alimentaires - Détermination des Lebensmitteluntersuchung - Bestimmung von
résidus de pesticides par CG-SM - Temps de rétention, Pestizidrückständen mit GC-MS - Retentionszeiten,
paramètres de spectrométrie de masse et information sur Parameter für die Massenspektrometrie und
la réponse des détecteurs Detektionsempfindlichkeit


This Technical Report was approved by CEN on 3 December 2012. It has been drawn up by the Technical Committee CEN/TC 275.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2013 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TR 16468:2013: E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------

SIST-TP CEN/TR 16468:2013
CEN/TR 16468:2013 (E)
Contents Page
Foreword . 3
Introduction . 4
1 Scope . 5
2 Analyte specific parameters for gas chromatographic determination of pesticides . 5
2.1 General . 5
2.2 GC-MS, GC-ECD and GC-NPD Parameters . 5
2.3 Analyte specific retention times and MS parameters . 6
Bibliography. 24

2

---------------------- Page: 4 ----------------------

SIST-TP CEN/TR 16468:2013
CEN/TR 16468:2013 (E)
Foreword
This document (CEN/TR 16468:2013) has been prepared by Technical Committee CEN/TC 275 “Food
analysis - Horizontal methods”, the secretariat of which is held by DIN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.

3

---------------------- Page: 5 ----------------------

SIST-TP CEN/TR 16468:2013
CEN/TR 16468:2013 (E)
Introduction
Pesticide residue analysis employs multiple methods involving extraction of residues from foods and clean-up
of the extract to obtain as many analytes as possible in the purified extracts. Afterwards the extracts can be
analysed by different kinds of instruments.
The hyphenatio
...