EN 12177:1998/AC:2000
(Corrigendum)Liquid petroleum products - Unleaded petrol - Determination of benzene content by gas chromatography
Liquid petroleum products - Unleaded petrol - Determination of benzene content by gas chromatography
TC - Technical change in Clause 9
Flüssige Mineralölerzeugnisse - Unverbleite Ottokraftstoffe - Bestimmung des Benzolgehaltes mittels Gaschromatographie
Produits pétroliers liquides - Essence sans plomb - Détermination de la teneur en benzène par chromatographie en phase gazeuse
Tekoči naftni proizvodi - Neosvinčeni motorni bencini - Določevanje benzena s plinsko kromatografijo
General Information
Relations
Standards Content (Sample)
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Flüssige Mineralölerzeugnisse - Unverbleite Ottokraftstoffe - Bestimmung desBenzolgehaltes mittels GaschromatographieProduits pétroliers liquides - Essence sans plomb - Détermination de la teneur en benzene par chromatographie en phase gazeuseLiq
...
This May Also Interest You
This document specifies requirements and test methods for marketed and delivered high FAME (B20 and B30) diesel fuel for use in diesel engine vehicles designed or subsequently adapted to run on such fuel. High FAME diesel fuel is a mixture of up to 20 % (V/V) in total and up to 30 % (V/V) in total respectively fatty acid methyl esters (commonly known as FAME) complying with EN 14214 and automotive diesel fuel complying with EN 590.
For maintenance and control reasons high FAME (B20 and B30) diesel fuel is to be used in captive fleets that are intended to have an appropriate fuel management (see Clause 4).
NOTE 1 These products are allowed in Europe [4], but national legislation can set additional requirements or rules concerning, or even prohibiting, marketing or delivering of the product.
NOTE 2 For the purposes of this document, the terms “% (m/m)” and “% (V/V)” are used to represent respectively the mass fraction and the volume fraction.
NOTE 3 In this document, A-deviations apply (see Annex A).
- Draft16 pagesEnglish languagesale 10% offe-Library read for×1 day
This document specifies an energy dispersive X-ray fluorescence (EDXRF) test method for the determination of sulfur content in automotive fuels. This document is applicable to:
— gasoline containing up to 3,7 % oxygen by mass (including those blended with ethanol up to 10 % by volume) having sulfur contents in the range of 6,9 mg/kg to 56,7 mg/kg,
— diesel fuels including those containing up to about 30 % fatty acid methyl ester (FAME) by volume, paraffinic diesel fuel, and neat FAME, having sulfur contents in the range of 5,0 mg/kg to 60,2 mg/kg.
The sulfur content in other products can be determined according to the test method specified in this document; however, no precision data for products other than automotive fuels and for results outside the specified range have been established for this document.
For reasons of spectral overlap, this document is not applicable to leaded automotive gasoline, gasoline having a content of greater than 8 mg/kg lead or to product and feedstock containing lead, silicon, phosphorus, calcium, potassium or halides at concentrations greater than one tenth of the concentration of sulfur measured, or more than 10 mg/kg, whichever is the greater.
- Standard22 pagesEnglish languagesale 10% offe-Library read for×1 day
This test method is a standard procedure for the determination of saturates, olefins, aromatics and oxygenates in unleaded petrol using gas chromatography and vacuum ultraviolet detection (GC-VUV).
Concentrations of compound classes and certain individual compounds are determined by mass fraction % (m/m) or volume fraction % (V/V). The concentration ranges for which the method is applicable are given in Table 1.
NOTE For the purposes of this document, the terms “% (m/m)” and “% (V/V)” are used to represent respectively the mass fraction and the volume fraction, respectively.
This test method has been tested for unleaded petrol according EN 228 [1]; Although specifically developed for the analysis of automotive motor gasoline including those that contain oxygenates this test method applies to other hydrocarbon streams having similar boiling ranges, such as naphthas and reformates.
The method is found to be applicable to petrol containing other oxygenates than indicated in Table 1, such as isopropanol, iso-butanol, tert-butanol, n-propanol, acetone, tert-pentanol and di-isopropyl ether (DIPE), however precision has not been determined.
Table 1 —Application ranges
Compound or group Units Concentration range
Saturates % (V/V) 21,48 to 80,87
Olefins % (V/V) 0,22 to 41,90
Aromatics % (V/V) 2,35 to 64,55
Benzene % (V/V) 0,20 to 2,54
Toluene % (V/V) 0,87 to 30,97
Ethylbenzene % (V/V) 0,20 to 3,45
Xylenes % (V/V) 0,49 to 18,59
Methanol % (V/V) 0,07 to 15,30
Ethanol % (V/V) 0,08 to 24,96
MTBE % (V/V) 0,22 to 22,21
ETBE % (V/V) 0,13 to 23,44
TAME % (V/V) 0,24 to 21,96
TAEE % (V/V) 0,24 to 8,60
Total oxygen content % (m/m) 0,52 to 12,19
Individual hydrocarbon components are typically not baseline-separated by the procedure described in this test method. The coelutions are resolved at the detector using VUV absorbance spectra (Annex A) and deconvolution algorithms.
While this test method reports by mass fraction % (m/m) or volume fraction % (V/V) for several specific components that can be present in unleaded petrol, it does not attempt to speciate all possible components that can occur in unleaded petrol. In particular, this test method is not intended as a type of detailed hydrocarbon analysis (DHA).
WARNING — The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this document to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.
- Standard27 pagesEnglish languagesale 10% offe-Library read for×1 day
This document specifies a method for the determination of the air saturated vapour pressure (ASVP) (total vapour pressure), exerted in vacuo, by volatile, low viscosity petroleum products, components, ethanol blends up to 85 % (V/V), and feedstocks containing air. A dry vapour pressure equivalent (DVPE) can be calculated from the air containing vapour pressure (ASVP) measurement.
The conditions used in the test described in this document are a vapour-to-liquid ratio of 4:1 and a test temperature of 37,8 °C.
The equipment is not wetted with water during the test, and the method described is therefore suitable for testing samples with or without oxygenates; no account is taken of dissolved water in the sample.
The method described is suitable for testing air saturated samples with a DVPE between 15,5 kPa and 106,0 kPa; vapour pressures outside this range can be measured, but the precision has not been determined.
This document is applicable to fuels containing oxygenated compounds up to the limits stated in the relevant Council Directive 85/536/EEC [10], and for ethanol-fuel blends up to 85 % (V/V) ethanol.
NOTE For the purposes of this document, the terms “% (m/m)” and “% (V/V)” are used to represent the mass and volume fractions, respectively.
WARNING - The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of users of this document to take appropriate measures to ensure the safety and health of personnel prior to application of the document, and to determine the applicability of any other restrictions for this purpose.
- Standard18 pagesEnglish languagesale 10% offe-Library read for×1 day
This document specifies a method for the determination of the content of undissolved substances, referred to as total contamination, in neat fatty acid methyl esters (FAME). The working range is from 5 mg/kg to 27 mg/kg and it was established in an interlaboratory study by applying EN ISO 4259-1 [1].
This document in general is applicable to FAME having a kinematic viscosity not exceeding 8 mm2/s at 20 °C, or 5 mm2/s at 40 °C, e.g. as specified in EN 14214 [2].
This test method can be used for FAME having a kinematic viscosity exceeding 8 mm2/s at 20 °C, or 5 mm2/s at 40 °C, however in such cases the precision of the test method has not been determined.
NOTE For the purposes of this document, the term “% (V/V)” is used to represent the volume fraction, φ, of a material.
WARNING - The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this document to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard13 pagesEnglish languagesale 10% offe-Library read for×1 day
This document specifies a method for the determination of the content of undissolved substances, referred to as total contamination, in middle distillates, in diesel fuels containing up to 30 % (V/V) fatty acid methyl esters (FAME). The working range is from 12 mg/kg to 26 mg/kg and it was established in an interlaboratory study by applying EN ISO 4259-1 [4].
This document in general is applicable to products having a kinematic viscosity not exceeding 8 mm2/s at 20 °C, or 5 mm2/s at 40 °C.
This test method can be used for paraffinic diesel fuels as specified in EN 15940, for diesel fuels containing more than 30 % (V/V) FAME and for petroleum products having a kinematic viscosity exceeding 8 mm2/s at 20 °C, or 5 mm2/s at 40 °C, however in such cases the precision of the test method has not been determined.
NOTE For the purposes of this document, the term “% (V/V)” is used to represent the volume fraction, φ, of a material.
WARNING - The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this document to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard13 pagesEnglish languagesale 10% offe-Library read for×1 day
This document specifies requirements and test methods for marketed and delivered automotive LPG (commonly known as low pressure gas or liquefied petroleum gas).
This document is applicable to automotive LPG for use in LPG engine vehicles designed to run on automotive LPG.
NOTE For the purposes of this European Standard, the terms “% (m/m)” and “% (V/V)” are used to represent respectively the mass fraction, µ, and the volume fraction, φ.
WARNING - Attention is drawn to the risk of fire and explosion when handling LPG and to the hazard to health arising through inhalation of excessive amounts of LPG.
LPG is a highly volatile hydrocarbon liquid which is normally stored under pressure. If the pressure is released large volumes of gas will be produced which form flammable mixtures with air over the range of approximately 2 % (V/V) to 10 % (V/V). This European Standard involves the sampling, handling and testing of LPG. Naked flames, unprotected electrical equipment electrostatic hazards etc. are sources of ignition for LPG.
LPG in liquid form can cause cold burns to the skin. National health and safety regulations can apply.
LPG is heavier than air and accumulates in cavities. There is a danger of suffocation when inhaling high concentrations of LPG.
CAUTION - One of the tests described in this document involves the operator inhaling a mixture of air and LPG vapour. Particular attention is drawn to the cautionary statement provided in A.1, where this method is referred to.
- Standard16 pagesEnglish languagesale 10% offe-Library read for×1 day
This document explains the requirements and test methods for paraffinic diesel fuel from synthesis or hydrotreatment. Synthesis refers to XTL processes where X refers to various feedstocks for example Gas (G), Biomass (B) or Coal (C) and TL stands for To-Liquid. Hydrotreatment of vegetable oils and animal fats yield Hydrotreated Vegetable Oil (HVO). Paraffinic diesel fuel can be blended with up to 7,0 % (V/V) fatty acid methyl ester (FAME). This document provides background information to the final text of EN 15940 [1] and gives guidance and explanations to the producers, blenders, marketers and users of paraffinic automotive diesel fuel.
Paraffinic diesel fuel is a high quality, clean burning fuel with virtually no sulfur and aromatics. Paraffinic diesel fuel can be used in diesel engines, also to reduce regulated emissions. In order to have the greatest possible emissions reduction, a specific calibration is needed. Some types of paraffinic diesel fuel, at present notably HVO, can also offer a meaningful contribution to the target of increased non-crude derived and/or renewable content in the transportation fuel pool.
For general diesel engine operation, durability and warranty, paraffinic automotive diesel fuel needs a validation step to confirm the compatibility of the fuel with the vehicle, which for some existing engines still needs to be done. The vehicle manufacturer needs to be consulted before use.
NOTE 1 This document is directly related to EN 15940 and will be updated once further publications take place.
NOTE 2 Paraffinic diesel fuel is also used as a blending component in automotive diesel fuel. In that case, composition and properties of the final blends are defined by relevant fuel specification standards.
NOTE 3 For the purposes of this document, the terms "% (m/m)" and "% (V/V)" are used to represent respectively the mass fraction and the volume fraction.
- Technical report51 pagesEnglish languagesale 10% offe-Library read for×1 day
This document specifies a laboratory method for the determination of the distillation characteristics of light and middle distillates derived from petroleum and related products of synthetic or biological origin with initial boiling points above 20 °C and end-points below approximately 400 °C, at atmospheric pressure utilizing an automatic micro distillation apparatus.
This test method is applicable to such products as light and middle distillates, automotive spark-ignition engine fuels, automotive spark-ignition engine fuels containing up to 20 % (V/V) ethanol, aviation gasolines, aviation turbine fuels, (paraffinic) diesel fuels, FAME (B100), diesel blends up to 30 % (V/V) fatty acid methyl esters (FAME), special petroleum spirits, naphtha’s, white spirits, kerosene’s, burner fuels, and marine fuels.
The test method is also applicable to hydrocarbons with a narrow boiling range, like organic solvents or oxygenated compounds.
The test method is designed for the analysis of distillate products; it is not applicable to products containing appreciable quantities of residual material.
WARNING - The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of user of this document to take appropriate measures to ensure the safety and health of personnel prior to application of the document, and to fulfil statutory and regulatory requirements for this purpose.
NOTE For the purpose of this document, the expression "% (V/V)" is used to represent the volume fraction.
- Standard25 pagesEnglish languagesale 10% offe-Library read for×1 day
This document specifies a test method for the determination of cetane numbers ("CN") of diesel fuels, using a standard single cylinder, four-stroke cycle, indirect injection engine. The cetane number provides a measure of the ignition characteristics of diesel fuels in compression ignition engines. The cetane number is determined at constant speed in a compression ignition test engine equipped with a swirl chamber.
The cetane number scale covers the range from 0 to 100, but typical testing is performed in the CN range from about 40 to about 75. The precision of this test method covers the CN range from 44 to about 66.
This document is applicable to distillate as well as paraffinic diesel fuels intended for use in diesel engines, including those containing up to a volume fraction of 10 % fatty-acid methyl esters (FAME), ignition-improvers or other diesel fuel additives.
When this engine test procedure is used for other fuels such as synthetics and vegetable oils, samples with fuel properties that interfere with the gravity-based pre-supply pressure to the fuel pump e.g. due to high viscosity can only be used to a limited extent. Precision data for such fuels are not available at this stage.
NOTE The test method is also suitable for determining cetane numbers outside the range of the scope; however, the precision statement only applies for fuels in the specified range.
WARNING - The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this document to take appropriate measures to ensure the safety and health of personnel prior to application of the document, and fulfil statutory and regulatory requirements for this purpose.
- Standard20 pagesEnglish languagesale 10% offe-Library read for×1 day
Questions, Comments and Discussion
Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.