CEN/TS 17197:2018
(Main)Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in digests and eluates - Analysis by Inductively Coupled Plasma - Optical Emission Spectrometry (ICP-OES)
Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in digests and eluates - Analysis by Inductively Coupled Plasma - Optical Emission Spectrometry (ICP-OES)
This Technical Specification specifies the method for the determination of major, minor and trace elements in aqua regia and nitric acid digests and in eluates of construction products by Inductively Coupled Plasma - Optical Emission Spectrometry (ICP-OES). It refers to the following 44 elements: Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), lanthanum (La), lead (Pb), lithium (Li), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium (Nd), nickel (Ni), phosphorus (P), potassium (K), praseodymium (Pr), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulphur (S), tellurium (Te), thallium (Tl), thorium (Th), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium (V), zinc (Zn), and zirconium (Zr).
For the determination of low levels of As, Se and Sb, hydride generation may be applied. This method is described in Annex D.
NOTE Construction products include e.g. mineral-based products (S); bituminous products (B); metals (M); wood-based products (W); plastics and rubbers (P); sealants and adhesives (A); paints and coatings (C), see also CEN/TR 16045 [1].
The method in this Technical Specification is applicable to construction products and validated for the product types listed in Annex D.
Bauprodukte - Beurteilung der Freisetzung von gefährlichen Stoffen - Analyse von anorganischen Stoffen in Aufschlusslösungen und Eluaten - Analyse mit optischer Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-OES)
Diese Technische Spezifikation legt die Verfahren zur Bestimmung der Haupt-, Neben- und Spurenelemente in Königswasser- oder Salpetersäure-Aufschlusslösungen sowie in Eluaten von Bauprodukten mittels optischer Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-OES) fest. Sie bezieht sich auf die folgenden 44 Elemente:
Aluminium (Al), Antimon (Sb), Arsen (As), Barium (Ba), Beryllium (Be), Wismut (Bi), Bor (B), Cadmium (Cd), Calcium (Ca), Cer (Ce), Chrom (Cr), Kobalt (Co), Kupfer (Cu), Eisen (Fe), Lanthan (La), Blei (Pb), Lithium (Li), Magnesium (Mg), Mangan (Mn), Quecksilber (Hg), Molybdän (Mo), Neodym (Nd), Nickel (Ni), Phosphor (P), Kalium (K), Praseodym (Pr), Samarium (Sm), Scandium (Sc), Selen (Se), Silicium (Si), Silber (Ag), Natrium (Na), Strontium (Sr), Schwefel (S), Tellur (Te), Thallium (Tl), Thorium (Th), Zinn (Sn), Titan (Ti), Wolfram (W), Uran (U), Vanadium (V), Zink (Zn) und Zirconium (Zr).
Zur Bestimmung geringer Gehalte von As, Se und Sb kann die Hydridbildung verwendet werden. Dieses Verfahren wird in Anhang D beschrieben.
ANMERKUNG Bauprodukte umfassen z. B. mineralische Produkte (S); bituminöse Produkte (B); Metalle (M); Holzprodukte (W); Kunststoff und Gummi (P); Dichtstoffe und Kleber (A); Farben und Beschichtungen (C), siehe auch CEN/TR 16045 [1].
Das Verfahren in dieser Technischen Spezifikation ist für Bauprodukte anwendbar und für die in Anhang D aufgeführten Produkttypen validiert.
Produits de construction: Évaluation des émissions de substances dangereuses - Analyse des substances inorganiques dans les digestats et les éluats - Partie 1: Analyse par plasma inductif couplé – Spectrométrie d'émission optique (ICP‐OES)
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza anorganskih snovi po razklopu in v izlužkih - Analiza z optično emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP/OES)
Ta tehnična dokumentacija podaja metodo za določanje glavnih in stranskih elementov ter elementov v sledovih v zlatotopki in izvlečku dušikove kisline ter v izlužkih gradbenih proizvodov z optično emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP/OES). Sklicuje se na naslednjih 44 elementov: aluminij (Al), antimon (Sb), arzen (As), barij (Ba), berilij (Be), bizmut (Bi), bor (B), kadmij (Cd), kalcij (Ca), cerij (Ce), krom (Cr), kobalt (Co), baker (Cu), železo (Fe), lantan (La), svinec (Pb), litij (Li), magnezij (Mg), mangan (Mn), živo srebro (Hg), molibden (Mo), neodim (Nd), nikelj (Ni), fosfor (P), kalij (K), prazeodim (Pr), samarij (Sm), skandij (Sc), selen (Se), silicij (Si), srebro (Ag), natrij (Na), stroncij (Sr), žveplo (S), telurij (Te), talij (Tl), torij (Th), kositer (Sn), titan (Ti), volfram (W), uran (U), vanadij (V), cink (Zn) in cirkonij (Zr).
Za določanje nizke ravni As, Se in Sb je mogoče uporabiti hidridno tehniko. Ta metoda je opisana v dodatku D.
OPOMBA: Gradbeni proizvodi vključujejo npr. mineralne proizvode (S), bitumenske proizvode (B), kovine (M), lesne proizvode (W), plastične mase in gume (P), tesnila in lepila (A), barve in premaze (C), glej tudi CEN/TR 16045 [1].
Metoda v tej tehnični specifikaciji se uporablja pri gradbenih proizvodih in je potrjena za vrste proizvodov, navedene v dodatku D.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-januar-2019
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Construction products - Assessment of release of dangerous substances - Analysis of
inorganic substances in digests and eluates - Analysis by Inductively Coupled Plasma -
Optical Emission Spectrometry (ICP-OES)
Bauprodukte - Beurteilung der Freisetzung von gefährlichen Stoffen - Analyse von
anorganischen Stoffen in Aufschlusslösungen und Eluaten - Analyse mit induktiv
gekoppeltem Plasma - Optische Emissionsspektralanalyse (ICP-OES)
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Ta slovenski standard je istoveten z: CEN/TS 17197:2018
ICS:
13.020.99 Drugi standardi v zvezi z Other standards related to
varstvom okolja environmental protection
91.100.01 Gradbeni materiali na Construction materials in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
CEN/TS 17197
TECHNICAL SPECIFICATION
SPÉCIFICATION TECHNIQUE
July 2018
TECHNISCHE SPEZIFIKATION
ICS 91.100.01
English Version
Construction products: Assessment of release of
dangerous substances - Analysis of inorganic substances in
digests and eluates - Analysis by Inductively Coupled
Plasma - Optical Emission Spectrometry (ICP-OES)
Produits de construction: Évaluation des émissions de Bauprodukte - Beurteilung der Freisetzung von
substances dangereuses - Analyse des substances gefährlichen Stoffen - Analyse von anorganischen
inorganiques dans les digestats et les éluats - Partie 1: Stoffen in Aufschlusslösungen und Eluaten - Analyse
Analyse par plasma inductif couplé - Spectrométrie mit induktiv gekoppeltem Plasma - Optische
d'émission optique (ICP-OES) Emissionsspektralanalyse (ICP-OES)
This Technical Specification (CEN/TS) was approved by CEN on 2 April 2018 for provisional application.
The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to
submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.
CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS
available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in
parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 17197:2018 E
worldwide for CEN national Members.
Contents Page
European foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 6
3 Terms and definitions . 6
4 Symbols and abbreviations . 8
5 Principle . 8
6 Interferences . 9
7 Reagents . 10
8 Apparatus . 12
9 Procedure. 12
9.1 Test sample . 12
9.2 Test portion . 13
9.3 Instrument set up . 13
9.3.1 General requirements . 13
9.3.2 Inter-element correction . 13
9.3.3 Internal standard . 13
9.3.4 Instrument performance check . 13
9.4 Calibration . 14
9.4.1 Linear calibration function . 14
9.4.2 Non-linear calibration function . 14
9.4.3 Standard addition calibration . 14
9.5 Sample measurement . 14
10 Calculation . 15
10.1 Calculation for digests of construction products . 15
10.2 Calculation for eluates of construction products . 15
11 Expression of results . 15
12 Performers characteristics . 16
12.1 General . 16
12.2 Blank . 16
12.3 Calibration check . 16
12.4 Interference . 16
12.5 Recovery . 16
12.6 Precision . 16
13 Test report . 17
Annex A (informative) Wavelengths, spectral interferences and estimated method
detection limits . 19
Annex B (informative) Method detection limit (MDL) and precision data for soil, sludge
and biowaste . 23
Annex C (informative) Inter element correction (IEC) . 27
Annex D (normative) Determination of arsenic, antimony and selenium using hydride-
generation ICP-OES . 29
D.1 Scope . 29
D.2 Principle . 29
D.3 Apparatus . 29
D.4 Reagents and solutions . 30
D.5 Procedure . 31
Bibliography . 33
European foreword
This document (CEN/TS 17197:2018) has been prepared by Technical Committee CEN/TC 351
“Construction Products - Assessment of release of dangerous substances”, the secretariat of which is
held by NEN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
Two similar documents have been developed for drinking water, surface water and waste water and
different types of waste respectively, see Annex B.
According to the CEN/CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Introduction
Following an extended evaluation of available methods for content and eluate analysis in construction
products (CEN/TR 16045 [1]) it was concluded that multi element analysis methods have preference
over methods developed for single elements or small groups of elements. This implies that for inorganic
substances ICP methods are preferred for the analysis of extracts obtained from digestion or eluates
obtained from leaching.
This document has been adopted from the work carried out in the context of CEN/TC 400
(project HORIZONTAL) and is very similar to EN 16170:2016, Sludge, treated biowaste and soil -
Determination of elements using inductively coupled plasma optical emission spectrometry (ICP-OES) [2].
This Technical Specification is part of a modular horizontal approach which was adopted
in CEN/TC 351. 'Horizontal' means that the methods can be used for a wide range of materials
and products with certain properties. 'Modular' means that a test standard developed in this approach
concerns a specific step in assessing a property and not the whole chain of measurement
(from sampling to analyses). Beneficial features of this approach are that modules can be replaced
by better ones without jeopardizing the standard chain and duplication of work of in different
Technical Committees for Products can be avoided as far as possible.
The modules that relate to the standards developed in CEN/TC 351 are specified
in CEN/TR 16220:2011, Construction products: Assessment of release of dangerous substances –
Complement to sampling [3] which distinguishes between the modules. This Technical Specification
belongs to the analytical step.
The use of modular horizontal standards implies the drawing of test schemes as well. Before executing
a test on a certain construction product to determine certain characte
...
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