Textiles and textile products - Determination of dimethylfumarate (DMFu), method using gas chromatography

This Technical Specification gives a test method for determining the amounts of dimethyl fumarate (DMFu) in materials of textile products, desiccant sachets and other commodities.
The test method is not applicable to metal parts. The materials to which it is applicable are given in CEN/TR 16741:2015, Table 1.
NOTE In Europe, DMFu is prohibited in biocidal products as per Directive 98/8/EC. The substance must be used with caution to avoid any health problems in the chemistry laboratory. More recently, EU Commission Decision 2009/251/EC requires EU member states to ensure that products containing the biocide DMFu are not placed or made available on the market in the European Union. Decision 2009/251/EC establishes a maximum concentration of DMFu in products and parts of products of 0,1 mg/kg.

Textilien und textile Erzeugnisse - Bestimmung von Dimethylfumarat (DMFu), Verfahren mittels Gaschromatographie

Dieses Dokument legt ein Prüfverfahren zur Bestimmung der Mengen an Dimethylfumarat (DMFu) in textilen Materialien und textilen Erzeugnissen fest. Es umfasst außerdem Trockenmittelbeutel, die vorhanden sein können.
Das Prüfverfahren ist nicht anzuwenden für Metallteile. Die Werkstoffe, für die das Dokument anzuwenden ist, sind in CEN/TR 16741:2015, Tabelle 1 und Tabelle 3, angegeben.

Textiles et produits textiles - Détermination du diméthylfumarate (DMFu), méthode par chromatographie en phase gazeuse

Le présent document fournit une méthode d’essai visant à déterminer les quantités de diméthylfumarate (DMFu) présentes dans les matériaux textiles et articles textiles. Il inclut également les sachets anti-humidité pouvant être présents.
Cette méthode d’essai ne s’applique pas aux parties métalliques. Les matériaux auxquels elle s’applique sont indiqués dans le CEN/TR 16741:2015, Tableaux 1 et 3.

Tekstilije in tekstilni izdelki - Določevanje dimetilfumarata (DMFu), metoda z uporabo plinske kromatografije

Ta tehnična specifikacija opisuje preskusno metodo za ugotavljanje količin dimetilfumarata (DMFu) v tekstilnih izdelkih, vrečkah s sušilnim sredstvom in drugih proizvodih.
Preskusna metoda se ne uporablja za kovinske dele. Materiali, za katere se uporablja, so navedeni v preglednici 1 standarda CEN/TR 16741:2015.
OPOMBA: V Evropi je DMFu v biocidnih pripravkih prepovedan v skladu z Direktivo 98/8/ES. Snov je treba uporabljati previdno, da se izognete zdravstvenim težavam v kemijskem laboratoriju. Od nedavno Odločba Evropske komisije 2009/251/ES od držav članic EU zahteva, da zagotovijo, da se proizvodi, ki vsebujejo biocid DMFu, ne dajejo na trg ali dajejo na voljo v promet v Evropski uniji. Odločba 2009/251/ES določa 0,1 mg/kg kot najvišjo koncentracijo biocida DMFu v izdelkih in delih izdelkov.

General Information

Status
Published
Public Enquiry End Date
01-Apr-2018
Publication Date
11-Aug-2019
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
29-Jul-2019
Due Date
03-Oct-2019
Completion Date
12-Aug-2019

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SLOVENSKI STANDARD
SIST EN 17130:2019
01-september-2019
Tekstilije in tekstilni izdelki - Določevanje dimetilfumarata (DMFu), metoda z
uporabo plinske kromatografije

Textiles and textile products - Determination of dimethylfumarate (DMFu), method using

gas chromatography

Textilien und textile Erzeugnisse - Bestimmung von Dimethylfumarat (DMFu), Verfahren

mittels Gaschromatographie

Textiles et produits textiles - Détermination du diméthylfumarate (DMFu), méthode par

chromatographie en phase gazeuse
Ta slovenski standard je istoveten z: EN 17130:2019
ICS:
59.080.01 Tekstilije na splošno Textiles in general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN 17130:2019 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN 17130:2019
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SIST EN 17130:2019
EN 17130
EUROPEAN STANDARD
NORME EUROPÉENNE
July 2019
EUROPÄISCHE NORM
ICS 59.080.01
English Version
Textiles and textile products - Determination of
dimethylfumarate (DMFu), method using gas
chromatography

Textiles et produits textiles - Détermination du Textilien und textile Erzeugnisse - Bestimmung von

diméthylfumarate (DMFu), méthode par Dimethylfumarat (DMFu), Verfahren mittels
chromatographie en phase gazeuse Gaschromatographie
This European Standard was approved by CEN on 26 May 2019.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this

European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references

concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN

member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by

translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management

Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,

Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and

United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17130:2019 E

worldwide for CEN national Members.
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SIST EN 17130:2019
EN 17130:2019 (E)
Contents Page

European foreword ....................................................................................................................................................... 3

Introduction .................................................................................................................................................................... 4

1 Scope .................................................................................................................................................................... 5

2 Normative references .................................................................................................................................... 5

3 Terms and definitions ................................................................................................................................... 5

4 Principle ............................................................................................................................................................. 5

5 Reagents ............................................................................................................................................................. 6

6 Apparatus ........................................................................................................................................................... 6

7 Sample preparation ........................................................................................................................................ 7

8 Procedures......................................................................................................................................................... 7

9 Expression of results ...................................................................................................................................... 9

10 Test report ......................................................................................................................................................... 9

Annex A (informative) Examples ......................................................................................................................... 10

A.1 Measuring method — example 1 ............................................................................................................ 10

A.1.1 Measuring parameter ................................................................................................................................. 10

A.1.2 Calibration and calculation ...................................................................................................................... 10

A.2 Measuring method — Example 2 ............................................................................................................ 11

Annex B (informative) Reliability of the method........................................................................................... 12

Bibliography ................................................................................................................................................................. 13

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SIST EN 17130:2019
EN 17130:2019 (E)
European foreword

This document (EN 17130:2019) has been prepared by Technical Committee CEN/TC 248 “Textiles and

textile products”, the secretariat of which is held by BSI.

This European Standard shall be given the status of a national standard, either by publication of an

identical text or by endorsement, at the latest by January 2020, and conflicting national standards shall

be withdrawn at the latest by January 2020.

Attention is drawn to the possibility that some of the elements of this document may be the subject of

patent rights. CEN shall not be held responsible for identifying any or all such patent rights.

This document is adapted from CEN ISO/TS 16186 prepared by Technical Committee CEN/TC 309,

“Footwear”, in collaboration with ISO Technical Committee TC 216, “Footwear”, in accordance with the

Agreement on technical cooperation between ISO and CEN (Vienna Agreement). The adaptation is

based on the extension of the scope to textile products.

According to the CEN-CENELEC Internal Regulations, the national standards organisations of the

following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,

Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,

Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of

North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the

United Kingdom.
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SIST EN 17130:2019
EN 17130:2019 (E)
Introduction

In Europe according to Regulation (EC) No 1907/2006 (REACH), Annex XVII, Entry 61,

Dimethylfumarate is not to be used in articles, or any parts thereof, in concentrations greater than

0,1 mg/kg. Articles, or any parts thereof, containing DMFu in concentrations greater than 0,1 mg/kg are

not to be placed on the market.

WARNING — The use of this document involves hazardous materials. It does not purport to address all

of the safety or environmental problems associated with its use. It is the responsibility of users of this

document to take appropriate measures to ensure the safety and health of personnel and the

environment prior to application of the document, and fulfil statutory and regulatory requirements for

this purpose.
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SIST EN 17130:2019
EN 17130:2019 (E)
1 Scope

This document gives a test method for determining the amounts of dimethyl fumarate (DMFu) in textile

materials and textile articles. It also includes desiccant sachets that can be present.

The test method is not applicable to metal parts. The materials to which it is applicable are given in

CEN/TR 16741:2015, Tables 1 and 3.
2 Normative references

The following documents are referred to in the text in such a way that some or all of their content

constitutes requirements of this document. For dated references, only the edition cited applies. For

undated references, the latest edition of the referenced document (including any amendments) applies.

CEN/TR 16741:2015, Textiles and textile products — Guidance on health and environmental issues

related to chemical content of textile products intended for clothing, interior textiles and upholstery

EN ISO 5089, Textiles — Preparation of laboratory test samples and test specimens for chemical testing

(ISO 5089)
3 Terms and definitions
No terms and definitions are listed in this document.

ISO and IEC maintain terminological databases for use in standardization at the following addresses:

• IEC Electropedia: available at http://www.electropedia.org/
• ISO Online browsing platform: available at http://www.iso.org/obp
4 Principle

The sample is cut into small pieces and extracted with acetone in a sealed vial at a defined temperature

in an ultrasonic bath. Two different procedures are proposed to be used, depending on the material

being tested:

a) the first procedure, without purification (concentration of the extracted solution is optional), can be

used for samples giving a simple chromatograph, for example, textiles;

b) the second procedure, with purification and concentration of the extract, can be used for samples

with a complex matrix effect, such as leather.

An aliquot of the extract is analysed using a gas chromatograph with mass selective detector.

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SIST EN 17130:2019
EN 17130:2019 (E)
5 Reagents
Unless otherwise specified, analytical grade chemicals shall be used.

5.1 Dimethyl fumarate, CAS number 624-49-7, highest available defined purity standard,

5.2 Dimethyl maleate, CAS number 624-48-6, highest available defined purity standard,

5.3 Dimethyl fumarate-d2, CAS number 23057-98-9, highest available defined purity standard,

5.4 Acetone, CAS number 67-64-1,
5.5 Stock solutions and working solutions,
5.5.1 Internal standard – S
...

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