Textiles and textile products - Determination of Polycyclic Aromatic Hydrocarbons (PAH), method using gas chromatography

This document specifies a method to determine the amounts of polycyclic aromatic hydrocarbons
(PAH) in components of textile products.

Textilien und textile Erzeugnisse - Kritische Stoffe, die potentiell in Bestandteilen von Materialien textiler Erzeugnisse vorhanden sind - Bestimmung von polycyclischen aromatischen Kohlenwasserstoffen (PAK), Verfahren mit chromatographischen Methoden

Dieses Dokument legt ein Verfahren zur quantitativen Bestimmung polycyclischer aromatischer Kohlenwasserstoffe (PAK) in Bestandteilen textiler Erzeugnisse fest. Dieses Verfahren wurde erarbeitet, um eine Bestimmungsgrenze von 0,1 mg/kg zu erreichen.
ANMERKUNG   Eine Liste betroffener Werkstoffe kann CEN/TR 16741 [2] entnommen werden.

Textiles et produits textiles - Détermination des hydrocarbures aromatiques polycycliques (HAP), méthode par chromatographie en phase gazeuse

Le présent document spécifie une méthode permettant de déterminer la quantité d’hydrocarbures aromatiques polycycliques (HAP) dans les composants de produits textiles. Cette méthode a été élaborée pour obtenir une limite de quantification de 0,1 mg/kg.
NOTE Une liste des matériaux pertinents est donnée dans le CEN/TR 16741 [2].

Tekstilije in tekstilni izdelki - Določevanje policikličnih aromatskih ogljikovodikov (PAH), metoda s kromatografskimi tehnikami

Ta dokument določa metodo za ugotavljanje količine policikličnih aromatskih ogljikovodikov (PAH) v delih tekstilnih izdelkov.

General Information

Status
Published
Public Enquiry End Date
01-Apr-2018
Publication Date
11-Aug-2019
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
05-Aug-2019
Due Date
10-Oct-2019
Completion Date
12-Aug-2019

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SLOVENSKI STANDARD
SIST EN 17132:2019
01-september-2019

Tekstilije in tekstilni izdelki - Določevanje policikličnih aromatskih ogljikovodikov

(PAH), metoda s kromatografskimi tehnikami

Textiles and textile products - Determination of Polycyclic Aromatic Hydrocarbons (PAH),

method using gas chromatography

Textilien und textile Erzeugnisse - Kritische Stoffe, die potentiell in Bestandteilen von

Materialien textiler Erzeugnisse vorhanden sind - Bestimmung von polycyclischen
aromatischen Kohlenwasserstoffen (PAK), Verfahren mit chromatographischen
Methoden
Textiles et produits textiles - Détermination des hydrocarbures aromatiques
polycycliques (HAP), méthode par chromatographie en phase gazeuse
Ta slovenski standard je istoveten z: EN 17132:2019
ICS:
59.080.01 Tekstilije na splošno Textiles in general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN 17132:2019 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN 17132:2019
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SIST EN 17132:2019
EN 17132
EUROPEAN STANDARD
NORME EUROPÉENNE
July 2019
EUROPÄISCHE NORM
ICS 59.080.01
English Version
Textiles and textile products - Determination of Polycyclic
Aromatic Hydrocarbons (PAH), method using gas
chromatography

Textiles et produits textiles - Détermination des Textilien und textile Erzeugnisse - Kritische Stoffe, die

hydrocarbures aromatiques polycycliques (HAP), potentiell in Bestandteilen von Materialien textiler

méthode par chromatographie en phase gazeuse Erzeugnisse vorhanden sind - Bestimmung von

polycyclischen aromatischen Kohlenwasserstoffen
(PAK), Verfahren mit chromatographischen Methoden
This European Standard was approved by CEN on 26 May 2019.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this

European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references

concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN

member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by

translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management

Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,

Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and

United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17132:2019 E

worldwide for CEN national Members.
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SIST EN 17132:2019
EN 17132:2019 (E)
Contents Page

European foreword ....................................................................................................................................................... 3

Introduction .................................................................................................................................................................... 4

1 Scope .................................................................................................................................................................... 5

2 Normative references .................................................................................................................................... 5

3 Terms and definitions ................................................................................................................................... 5

4 Principle ............................................................................................................................................................. 5

5 Reagents ............................................................................................................................................................. 6

6 Apparatus ........................................................................................................................................................... 8

7 Sample Preparation........................................................................................................................................ 8

8 Procedure........................................................................................................................................................... 9

9 Expression of results ...................................................................................................................................... 9

10 Test report ...................................................................................................................................................... 10

Bibliography ................................................................................................................................................................. 11

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SIST EN 17132:2019
EN 17132:2019 (E)
European foreword

This document (EN 17132:2019) has been prepared by Technical Committee CEN/TC 248 “Textiles and

textile products”, the secretariat of which is held by BSI.

This European Standard shall be given the status of a national standard, either by publication of an

identical text or by endorsement, at the latest by January 2020, and conflicting national standards shall

be withdrawn at the latest by January 2020.

Attention is drawn to the possibility that some of the elements of this document may be the subject of

patent rights. CEN shall not be held responsible for identifying any or all such patent rights.

This document is adapted from CEN ISO/TS 16190 [1], prepared by Technical Committee CEN/TC 309,

“Footwear”, in collaboration with ISO Technical Committee ISO/TC 216, “Footwear”, in accordance with

the Agreement on technical cooperation between ISO and CEN (Vienna Agreement). The adaptation is

based on the extension of the scope to textiles and textile products.

According to the CEN-CENELEC Internal Regulations, the national standards organisations of the

following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,

Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,

Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of

North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the

United Kingdom.
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SIST EN 17132:2019
EN 17132:2019 (E)
Introduction

In the European Union, according to Regulation (EC) No 1907/2006 (REACH), Annex XVII, Entry 50,

articles such as clothing, footwear and gloves are not to be placed on the market for supply to the

general public if any of their rubber or plastic components that come into direct, as well as prolonged or

short-term repetitive, contact with the human skin or the oral cavity, under normal or reasonably

foreseeable conditions of use, contain more than 1 mg/kg (0,000 1 % by weight of this component) of

any of the following PAHs.

Toys and childcare articles, are not to be placed on the market if any of their rubber or plastic

components that come into direct as well as prolonged or short-term repetitive contact with the human

skin or the oral cavity, under normal or reasonably foreseeable conditions of use, contain more than

0,5 mg/kg (0,000 05 % by weight of this component) of any of the following PAHs.
Further information can be found in the ECHA guideline [3].

According to Regulation (EU) 2018/1513 amending Annex XVII to Regulation (EC) No 1907/2006

(REACH) by Entry 72, (a) clothing or related accessories; (b) textiles other than clothing which, under

normal or reasonably foreseeable conditions of use, come into contact with human skin to an extent

similar to clothing; (c) footwear are not to be placed on the market after 1 November 2020, if they

contain more than 1 mg/kg (0,000 1 % by weight of this component) of any of the following PAHs.

This restriction does not apply to: (a) clothing, related accessories or footwear, or parts of clothing,

related accessories or footwear, made exclusively of natural leather, fur or hide; (b) non-textile

fasteners and non-textile decorative attachments; (c) second-hand clothing, related accessories, textiles

other than clothing or footwear; (d) wall-to-wall carpets and textile floor coverings for indoor use, rugs

and runners. It also does not apply to clothing, related accessories, textiles other than clothing, or

footwear within the scope of Regulation (EU) 2016/425 or Regulation (EU) 2017/745. The restriction

on textiles other than clothing does not apply to disposable textiles. "Disposable textiles" means textiles

that are designed to be used only once or for a limited time and are not intended for subsequent use for

the same or a similar purpose.

Regulated PAHs: Benzo[a]pyrene (BaP), Benzo[e]pyrene (BeP), Benzo[a]anthracene (BaA), Chrysen

(CHR), Benzo[b]fluoranthene (BbFA), Benzo[j]fluoranthene (BjFA), (g) Benzo[k]fluoranthene (BkFA),

Dibenzo[a,h]anthracene (DBAhA).

The PAH Benzo(g,h,i)perylene was added to the REACH Candidate List of SVHC on 27 June 2018.

In addition, the following PAHs are under consideration for addition to the REACH Regulation.

Indeno(1,2,3-cd)pyrene, Benzo(j,k)fluorene (fluoranthrene), Napthalene, Anthracene, Pyrene,

Benzo(g,h,i)perylene, Acenaphthalene, Acenaphthene

WARNING — The use of this document involves hazardous materials. It does not purport to address all

of the safety or environmental problems associated with its use. It is the responsibility of users of this

document to take appropriate measures to ensure the safety and health of personnel and the

environment prior to application of the document and fulfil statutory and regulatory requirements for

this purpose.
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SIST EN 17132:2019
EN 17132:2019 (E)
1 Scope

This document specifies a method to determine the amounts of polycyclic aromatic hydrocarbons

(PAH) in components of textile products. This method has been elaborated to achieve a limit of

quantification of 0,1 mg/kg.
NOTE A list of relevant materials can be found in CEN/TR 16741 [2].
2 Normative references

The following documents are referred to in the text in such a way that some or all of their content

constitutes requiremen
...

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